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Organosilicon sulfides as co-initiators in photoinduced free radical polymerization

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Summary

Three sulfur-containing silanes (organosilicon sulfides) were investigated as electron donors in photoinduced free radical polymerization, in conjunction with xanthene dye (5,7-diiodo-3-butoxy-6-fluorone, DIBF) as sensitizer. The results were compared with the nonsulfur-containing silane, N-((trimethylsilyl)methyl)aniline (K1) and thiophenoxyacetic acid (TPAA). The kinetic studies clearly showed that the DIBF-organosilicon sulfides exhibit a significant increase in the efficiency of free radical polymerization of TMPTA compared to nonsulfur-containing silane and that the efficiency of all tested electron donors is only slightly dependent on the structure of the sulfur-containing co-initiators.

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Authors and Affiliations

  1. Faculty of Chemical Technology and Engineering, University of Technology and Agriculture, Seminaryjna 3, 85-326, Bydgoszcz, Poland

    Adam Leniec, Beata Jędrzejewska & Jerzy Pączkowski

Authors
  1. Adam Leniec
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  2. Beata Jędrzejewska
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  3. Jerzy Pączkowski
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Correspondence to Beata Jędrzejewska.

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Leniec, A., Jędrzejewska, B. & Pączkowski, J. Organosilicon sulfides as co-initiators in photoinduced free radical polymerization. Polym. Bull. 56, 119–128 (2006). https://doi.org/10.1007/s00289-005-0477-z

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  • DOI: https://doi.org/10.1007/s00289-005-0477-z

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