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Controlled radical polymerization of N,N-dimethylaminoethyl methacrylate using triazolinyl as counter radical

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Summary

The role of the triazolinyl radical as additive for controlled radical polymerisation is investigated for N,N-dimethylaminoethyl methacrylate (DMAEMA) as polar monomer. A linear increase of the molecular weight with conversion and first-order kinetics are observed proving the controlled behaviour of the polymerization. The end-functionalisation of the obtained polymers was proven by both GPC und UV-spectroscopy. Furthermore, various amphiphilic block copolymers were obtained by chain extension with styrene, methyl methacrylate and ethyl methacrylate. In all cases monomodal GPC curves were obtained indicating an almost quantitative reinitiation.

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Authors and Affiliations

  1. Max-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128, Mainz, Germany

    Nawel S. Khelfallah, Maxim Peretolchin, Markus Klapper & Klaus Müllen

Authors
  1. Nawel S. Khelfallah
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  2. Maxim Peretolchin
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  3. Markus Klapper
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  4. Klaus Müllen
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Correspondence to Markus Klapper.

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Khelfallah, N., Peretolchin, M., Klapper, M. et al. Controlled radical polymerization of N,N-dimethylaminoethyl methacrylate using triazolinyl as counter radical. Polym. Bull. 53, 295–304 (2005). https://doi.org/10.1007/s00289-005-0352-y

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  • DOI: https://doi.org/10.1007/s00289-005-0352-y

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