Summary
Thin films of hydroxypropylcellulose (HPC)/methanol (MeOH) solutions were juxtaposed against air in a diffusion couple geometry at room temperature and the solvent was allowed to diffuse away and evaporate from the solution in a controlled manner. The diffusion couple geometry produced a uniform film for optical assessment of liquid crystalline potential between crossed polarizers. After an induction period, a stable microstructure developed in which the interior of the sample remained isotropic followed by a cholesteric liquid crystalline band, with characteristic disclination defects and texture, followed by a crystalline band nearest to the external surface. The width of the total characteristic birefringent band was measured over time and provided information concerning the dynamics and trajectory of solvent transport and evaporation from the cover slip edge. The apparent solvent diffusion coefficient for the HPC/MeOH system was measured at room temperature as a function of initial concentration. Diffusion couple optical microscopy data were compared to both solution rheological characteristics as well as model diffusion data from finite difference calculations in order to validate the observed concentration dependence of diffusion.
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References
Donald AM, Windle AH (1993) Liquid Crystalline Polymers. Cambridge University Press, UK
DeGennes PG, Prost J (1993) The Physics of Liquid Crystals. 2nd Edition, Clarendon Press, Oxford, UK, pp 6 (1993)
Chandrasekhar S, Liquid Crystals.(1992) 2nd Edition, Cambridge University Press, UK, pp 12-14
Chapman D, (1971) Faraday Soc Symp 5:165
Ciferri A (1991) “Phase Behavior of Rigid and Semirigid Mesogens.” In: Liquid Crystallinity in Polymers. VCH Publishers, New York, Chapter 4, pp 209-259
Aharoni SM (1980) Polymer 21:1413
Aharoni SM (1981) J Polym Sci, Polym Lett Ed 19:495
Dayan S, Maissa P, Vellutini MJ, Sixou P (1982) J Polym Sci, Polym Lett Ed, 20:33
Martin DC (2002) Polymer 43:4421
Gray DW, J (1983) Appl Polym Sci, Appl Polym Symp 37:179
Tseng SL, Valente A, Gray DW (1981) Macromoleules 14:715
Dayan S, Fried F, Gilli JM, Sixou P (1983) J Appl Polym Sci, Appl Polym Symp 37:193
Zugenmaier P, J Appl Polym Sci, Appl Polym Symp, 37:223
Navard P, Haudin JM, Dayan S, Sixou P (1981) J Polym Sci, Polym Lett Ed 19:379
Werbowyj RS, Gray DG (1976) Mol Cryst Liq Cryst Lett, 34:97
Maeno J, (1979) US Patent 4,132,464
Chiba, R, Nishio Y (2003) Macromolecules 36(5):1706
Gray DG (1983) J Appl Polym Sci, Appl Polym Symp 37:179
Gilbert RD, Patton PA, (1983) Prog Polym Sci 9:115
Gray DG Faraday Discuss Chem Soc (1985) 79:257
Guo JX, Gray DG (1994) In: . Gilbert RD (ed) Cellulosic Polymers, Blends and Composites. Carl Hanser, Munich, Chapter 2
Fortin S, Charlet G (1989) Macromolecules 22:2286.
Godinho MH, Fonseca JG, Ribeiro AC, Melo LV, Brogueira P. (2002) Macromolecules 35(15):5932
Navard P, Haudin JM, Dayan S, Sixou, P (1983) J Appl Polym Sci, Appl Polym Symp 37:211
Aspler JS, Gray DG (1979) Macromolecules 12:562
Aspler JS, Gray DG (1981) Macromolecules 14:1546
Onogi Y, White JL, Fellers JF (1980) J Polym Sci, Polym Phys Ed 18:663
Onogi Y, White JL, Fellers JF (1980) J Non-Newtonian Fluid Mech, 7:121
Werbowyj RS, Gray DG (1980) Macromolecules, 13:69
Tsutsui T, Tanaka R (1980) Polym J 12:473
Aharoni SM, (1981) Am Chem Soc Polym Prep 22(1):116
Standard Test Methods for Hydroxypropylcellulose (2003) Test D 5400-03 American Society for Testing and Materials (ASTM), West Conshohocken, Pennsylvania
Klug ED, (1971) J Polym Sci, Polym Symp 36:49
Klug ED, “Hydroxypropylcellulose” (1971) In: Bikales NM (ed) Encyclopedia of Polymer Science and Technology. Volume 15, Wiley-Interscience, New York, pp 307-314
Standard Test Method for Methoxyl and Hydroxypropyl Substitution in Cellulose Ether Products by Gas Chromatography (2001) Test D 3876-96 American Society for Testing and Materials (ASTM), West Conshohocken, Pennsylvania
Hydroxypropyl Cellulose: Physical and Chemical Properties. (2001) Hercules Inc (Aqualon), Wilmington, Deleware, p 4
Savage AB Derivatives of Cellulose: Ethers.(1971) In: Bikales, NM, Segal L (ed) In: Cellulose and Cellulose Derivatives Part V, 2nd Edition, High Polymers (Part V), Wiley-Interscience, New York, Chapter 17c, pp 806-807
Shimamura K, White JL, Fellers JF (1981) J Appl Polym Sci 26:2165
Aronson, CL (2000) “Structure-Property Relationships for n-Alkyl Isocyanate Containing Polymers.” Ph.D. Dissertation University of Michigan, Ann Arbor
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Aronson, C., Catalogna, J. & Webster, W. The Dynamics of Solvent Evaporation from Hydroxypropylcellulose/Methanol Solutions with Lyotropic Liquid Crystalline Capability. Polym. Bull. 53, 43–52 (2004). https://doi.org/10.1007/s00289-004-0307-8
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DOI: https://doi.org/10.1007/s00289-004-0307-8