Skip to main content
SpringerLink
Log in

Synthesis of UHMW-PE by a Highly Active Homogeneous System: η5-(C5H5)2Ti(η1-OC(O)C6H5)2/MAO

  • Original Article
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The complex η5-(C5H5)2Ti (η1-OC(O)C6H5)2 was synthesized and activated with MA0 for ethylene polymerization. The resultant polymer is UHMW-PE with a viscosimetric molecular weight of Mv = 6.8 x 106 to 0.7 x 106 g/mol dependent on the temperature of the reaction. The effects of the Al/Ti molar ratio and temperature of the reaction on the catalytic activity and polymer properties were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Author information

Authors and Affiliations

  1. Laboratorio de Polímeros, Departamento de Química, Facultad de Ciencias, La Universidad del Zulia, Maracaibo, 4001, Venezuela

    Juan Chirinos, Jose Arévalo, Tamara Rajmankina, Angel Morillo, Darmenia Ibarra & Alvaro Parada

  2. Departamento de Química, Facultad de Ciencias, Universidad de 10s Andes, La Hechicera, Mérida, 5251, Venezuela

    Ali Bahsas

Authors
  1. Juan Chirinos
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jose Arévalo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Tamara Rajmankina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Angel Morillo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Darmenia Ibarra
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ali Bahsas
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Alvaro Parada
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Alvaro Parada.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chirinos, J., Arévalo, J., Rajmankina, T. et al. Synthesis of UHMW-PE by a Highly Active Homogeneous System: η5-(C5H5)2Ti(η1-OC(O)C6H5)2/MAO. Polymer Bulletin 51, 381–387 (2004). https://doi.org/10.1007/s00289-004-0237-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-004-0237-5

Keywords

Search

Navigation