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Synthesis and Thermal Properties of Enyne-Containing Polymers by the Polymerization of Diynes Using a Low-Valent Titanium Catalyst

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Summary

Polymers having conjugated enyne moieties in the main chain (3) were prepared by the polymerization of diynes (2) using a low-valent titanocene catalyst (1) generated from Cp*2TiCl2 and i-PrMgBr. The reactivity of the enyne-containing polymers (3) was demonstrated by the thermal cross-linking reaction at 200 °C.

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Authors and Affiliations

  1. Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Nagatsuta-cho 4259, Midori-ku, Yokohama 226-8502, JAPAN

    Masahiro Ueda & Ikuyoshi Tomita

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  1. Masahiro Ueda
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  2. Ikuyoshi Tomita
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Correspondence to Ikuyoshi Tomita.

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Ueda, M., Tomita, I. Synthesis and Thermal Properties of Enyne-Containing Polymers by the Polymerization of Diynes Using a Low-Valent Titanium Catalyst. Polymer Bulletin 51, 359–364 (2004). https://doi.org/10.1007/s00289-004-0234-8

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  • DOI: https://doi.org/10.1007/s00289-004-0234-8

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