Summary
A new initiating system, azidoadamantane/CuBr, for the radical polymerisation of methylacrylate was found. Polymerisations occur as well at 50°C in toluene solution as in bulk at 70°C. A kinetic study seems to show a monomer consumption of first order in monomer concentration. However, despite a polydispersity index lower than 2, the value and the constancy of Mn during the whole polymerisation time gave an indication of a non controlled polymerisation. This is assumed to be due to the double role played by the azide function: strong complexing agent for copper ions and radical initiatior for the polymerisation, so that the presence of an additional ligand, i.e. bipyridine, is not necessary.
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Received: 15 October 2002/Revised version: 31 March 2003/ Accepted: 14 April 2003
Correspondence to Hung Anh Nguyen
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Nguyen, H., Cheradame, H. & Guérin, P. Radical Polymerisation of Methylacrylate Initiation by the Azidoadamantane / Copper Bromide System. Polymer Bulletin 50, 265–269 (2003). https://doi.org/10.1007/s00289-003-0168-6
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DOI: https://doi.org/10.1007/s00289-003-0168-6