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Synthetic and Thermal Studies of Bisphenol-C containing Poly(aryletherketone)s

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Summary

Poly(aryletherketone)s containing 1,1-dichloro-2,2-bis(4-hydroxyphenyl)ethene (BPC) were synthesized by the cesium fluoride initiated polymerization of 1,1-dichloro-2,2-bis(4-t-butyldimethylsiloxyhenyl)ethane with 4,4'-difluorobenzophenone (BP-F). These polymers exhibit high char yields by thermogravimetric analysis (TGA), and low heat release capacities were measured by pyrolysis combustion flow calorimetry (PCFC). Poly(aryletherketone)s were prepared from BP-F and various ratios of BPC and bisphenol-A (BPA), and their thermal properties characterized by TGA and PCFC.

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Received: 23 January 2003 /Revised version: 7 April 2003 / Accepted: 7 April 2003

Correspondence to Todd Emrick

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Ellzey, K., Farris, R. & Emrick, T. Synthetic and Thermal Studies of Bisphenol-C containing Poly(aryletherketone)s. Polymer Bulletin 50, 235–242 (2003). https://doi.org/10.1007/s00289-003-0162-z

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  • DOI: https://doi.org/10.1007/s00289-003-0162-z

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