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Enzymatic Synthesis of Poly( quinolinol) and Its Fluorescent Aluminum Complex

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Summary

Horseradish peroxidaze (HRP)-catalyzed polymerization of 8-quinolinol proceeded regioselectively to give a soluble poly(quinolino1) (1). Reaction of 1 with Alq'2(Et) (q'= 2-methy-8-quinolinolato) provided a polymer-aluminum complex (2). 2 was photoluminescent both in solutions and in the solid state. Quantum yield (Φ) of the photoluminescence in the chloroform solution was 23%.

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Authors and Affiliations

  1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan, e-mail: tyamamot@res.titech.ac.jp. Fax: +81-45-924-5276, , , , , , JP

    Takakazu Yamamoto & Isao Yamaguchi

Authors
  1. Takakazu Yamamoto
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  2. Isao Yamaguchi
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Received: 27 February 2003 / Accepted: 5 March 2003

Correspondence to Takakazu Yamamoto, Isao Yamaguchi

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Yamamoto, T., Yamaguchi, I. Enzymatic Synthesis of Poly( quinolinol) and Its Fluorescent Aluminum Complex. Polymer Bulletin 50, 55–60 (2003). https://doi.org/10.1007/s00289-003-0146-z

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  • DOI: https://doi.org/10.1007/s00289-003-0146-z

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