A short range interaction model applied to illite/smectite mixed-layer minerals

Abstract 

We present a solid solution model, able to take into account short-range interactions up to the third nearest neighbor. This model has been applied to illite/smectite mixed-layer clay minerals and tests the relative thermodynamic stability of each illite/smectite stacking sequence. The non-ideal energy terms have been calculated, showing a strong decrease of the interaction energy as the distance between elements grows. From ΔG _m calculations the model predicts the following succession in I/S stacking sequences as X _i tends to 1:R1, R2 and then R3. This succession agrees well with some mineralogical observations in natural series.