Abstract
We present a Raman spectroscopic study of the structural modifications of several olivines at high pressures and ambient temperature. At high pressures, the following modifications in the Raman spectra are observed:
1) in Mn2GeO4, between 6.7 and 8.6 GPa the appearance of weak bands at 560 and 860 cm−1; between 10.6 and 23 GPa, the progressive replacement of the olivine spectrum by the spectrum of a crystalline high pressure phase; upon decompression, the inverse sequence of transformations is observed with some hysteresis in the transformation pressures; this sequence may be interpreted as the progressive transformation of the olivine to a spinelloid where Ge tetrahedra are polymerized, and then to a partially inverse spinel;
2) in Ca2SiO4, the olivine transforms to larnite between 1.9 and 2.1 GPa; larnite is observed up to the maximum pressure of 24 GPa and it can partially back-transform to olivine during decompression;
3) in Ca2GeO4, the olivine transforms to a new structure between 6.8 and 8 GPa; the vibrational frequencies of the new phase suggest that the phase transition involves an increase of the Ca coordination number and that Ge tetrahedra are isolated; this high pressure phase is observed up to the maximum pressure of 11 GPa; during decompression, it transforms to a disordered phase below 5 GPa;
4) in CaMgGeO4, no significant modification of the olivine spectrum is observed up to 15 GPa; between 16 and 26 GPa, broadening of some peaks and the appearance of a weak broad feature at 700–900 cm−1 suggests a progressive amorphization of the structure; near 27 GPa, amorphization is complete and an amorphous phase is quenched down to ambient pressure; this unique behaviour is interpreted as the result of the incompatibilities in the high pressure behaviour of the Ca and Mg sublattices in the olivine structure.
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Received June 30, 1995/Revised, accepted May 31, 1996
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Reynard, B., Remy, C. & Takir, F. High-pressure Raman spectroscopic study of Mn2GeO4, Ca2GeO4, Ca2SiO4, and CaMgGeO4 olivines. Phys Chem Min 24, 77–84 (1997). https://doi.org/10.1007/s002690050019
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DOI: https://doi.org/10.1007/s002690050019