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Mineralogical description and hypothesis on the formation of menilites from Galera, Granada (Spain)

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Abstract

Menilites, intriguing botryoidal rocks found in Galera, Granada, Spain, have been examined through a multidisciplinary approach integrating mineralogical analysis and advanced imaging techniques. Characterized as opal and dolomite-bearing rocks, their complex morphologies and diverse internal structures prompted an investigation into their origin. Employing microfocus X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray spectroscopy and X-ray computed tomography, we present a detailed study of the menilites, revealing opal-A, opal-CT, dolomite and quartz as primary constituents. Notably, the internal homogeneity contrasts with the diverse external shapes. The proposed hypothesis suggests a seismic influence in menilite formation. Seismic events in porous environments above the water table may induce fluidization, resulting in the distinctive menilite structures. Osmotic pressure differences between nodules and the surrounding rock, coupled with fluidization during seismic events, could explain the observed morphologies. Validation of the proposed hypothesis requires further fieldwork and analogue experimentation. This study contributes valuable insights into the mineralogical composition, internal structures and potential formation mechanisms of menilites, laying the groundwork for future research in the field of sedimentary geology and mineralogy.

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The data that support the findings of this study are available from the corresponding author, C.P., upon request.

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Acknowledgements

Microfocus X-ray diffraction, scanning electron microscopy and X-ray computed tomography analysis and observations were carried out at the Centro de Instrumentación Científica (CIC) of the University of Granada. C.P. acknowledges funding from Juan de la Cierva-Formación (grant FJC2018-035820-I) from the Spanish Ministry of Science. J.H.E.C. and C.I.S.D. acknowledge the financial support of the Spanish MINCINN projects FIS2016-77692-C2-2-P and PCIN-2017-098. A.G.C. was funded by project PID2020116660GB-I00 (Spanish Ministerio de Ciencia e Innovación-FEDER, MCIN/AEI/https://doi.org/10.13039/501100011033). The authors would also like to thank mindat.org and its contributors for the information freely available on the web, which made it possible to locate the Galera menilite site.

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Conceptualization: CP and JHEC; formal analysis: CP and CGA; investigation: CP, AGC, CISD and JHEC; funding acquisition: CP, AGC, CISD and JHEC; writing––original draft preparation: CP and JHEC; writing––review and editing: CP, CGA, AGC, CISD and JHEC.

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Correspondence to Carlos Pimentel.

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Pimentel, C., Gutiérrez-Ariza, C., Checa, A.G. et al. Mineralogical description and hypothesis on the formation of menilites from Galera, Granada (Spain). Phys Chem Minerals 51, 7 (2024). https://doi.org/10.1007/s00269-023-01267-0

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