Abstract
Two specimens of alluaudite-group minerals, badalovite NaNaMg(Mg,Fe3+)2(AsO4)3 and calciojohillerite NaCaMgMg2(AsO4)3, were taken on the Second scoria cone of the Great fissure Tolbachik eruption, Kamchatka Peninsula, Russia. The crystal structures of these monoclinic minerals have been refined by single-crystal X-ray diffraction. The thermal expansion of badalovite and calciojohillerite has been studied by high-temperature powder X-ray diffraction. The electrical conductivity was evaluated by impedance spectroscopy. The thermal expansion of these minerals is similar: maximum expansion is close to the longer diagonal of the parallelogram ac, minimum expansion is close to the shorter diagonal of the parallelogram ac. Thermal deformation of the ac plane is described in terms of the theory of shear deformation of monoclinic crystals. The results of shear deformations calculation and its consideration with thermal expansion are given. The shear deformations were calculated using bisectors of the ac parallelogram at different temperatures. The axes of shear deformation are located in the directions of the mutually perpendicular bisectors of ac parallelogram. The electrical conductivity of badalovite is ~ 3–4 times greater than for calciojohillerite in the studied temperature range (350–600 °C).
Similar content being viewed by others
References
Auernhammer M, Effenberger H, Hentschel G, Reinecke Th, Tillmanns E (1993) Nickenichite, a new arsenate from the Eifel, Germany. Mineral Petrol 48:153–166
Baur WH (1974) The geometry of polyhedral distortions. Predictive relationships for the phosphate group. Acta Crystallogr B 30:1195–1215
Daidouh A, Durio C, Pico C, Veiga ML, Chouaibi N, Ouassini A (2002) Structural and electrical study of the alluaudites (Ag1-xNax)2FeMn2(PO4)3 (x = 0, 0.5 and 1). Solid State Sci 4:541–548
Dridi W, Zid MF (2016) Synthesis, crystal structure and charge-distribution validation of β-Na4Cu(MoO4)3 adopting the alluadite structure-type. Acta Crystallogr E 72:1103–1107
Durio C, Daidouh A, Chouaibi N, Pico C, Veiga ML (2002) Electrical behavior of new orthophosphates Na2M3(PO4)3 (M3 = GaMn2, GaCd2, InMn2 and FeMnCd) with the alluaudite-like structure. J Solid State Chem 168:208–216
Ennajeh I, Georges S, Ben Smida Y, Guesmi A, Zid MF, Boughazala H (2015) Synthesis, crystal structure, sintering and electrical properties of a new alluaudite-like triple molybdate K0.13Na3.87MgMo3O12. RSC Adv 5:38918–38925
Essehli R, Belharouak I, Ben Yahia H, Maher K, Abouimrane A, Orayech B, Calder S, Zhou XL, Zhou Z, Sun YK (2015) Alluaudite Na2Co2Fe(PO4)3 as an electroactive material for sodium ion batteries. Dalt Trans 44:7881–7886
Filatov SK (1982) Negative thermal expansion of crystals. Zapiski VMO 116(4):417–431 ((in Russian))
Filatov SK (2008) Negative linear thermal expansion of oblique-angle (monoclinic and triclinic) crystals as a common case. Phys Stat Solid 245(11):2490–2496
Filatov SK, Andrianova LV, Bubnova RS (1984) Regularities of thermal deformations in monoclinic crystals. Cryst Res Tech 19(4):563–569
Filatov SK, Vergasova LP, Gorskaya MG, Krivovichev SV, Burns PC, Ananiev VV (2001) Bradaczekite, NaCu4(AsO4)3, a new mineral species from the Tolbachik volcano, Kamchatka Peninsula, Russia. Can Mineral 39:1115–1119
Filatov SK, Rybin DS, Krivovichev SV, Vergasova LP (2009) Thermal expansion of new arsenate minerals, bradaczekite, NaCu4(AsO4)3, and urusovite, Cu(AsAlO5). Geol Ore Dep 54(8):827–832 ((translated from: Zapiski RMO, 2009, 138(1):136–143))
Firsova VA, Bubnova RS, Volkov SN, Filatov SK (2018) RietveldToTensor: program for processing powder X-ray diffraction data under variable conditions. Glass Phys Chem 44:33–40
Glavatskikh SF, Bykova EY (1998) First find of exhalation johillerite (Kamchatka). Dokl RAN 361(6):795–798 ((in Russian))
Hatert F (2019) A new nomenclature scheme for the alluaudite supergroup. Eur J Mineral 31(4):807–822
Hatert F, Keller P, Lissner F, Antenucci D, Fransolet AM (2000) First experimental evidence of alluaudite-like phosphates with high Li-content: the (Na1-xLix)MnFe2(PO4)3 series (x = 0 to 1). Eur J Mineral 12:847–857
Keller P, Hess H, Dunn PJ (1982) Johillerit, Na(Mg, Zn)3Cu(AsO4)3, ein neues Mineral aus Tsumeb, Namibia. Tscherm Mineral Petrograph Mitt 29:169–175
Krivovichev SV, Vergasova LP, Filatov SK, Rybin DS, Britvin SN, Ananiev VV (2013) Hatertite, Na2(Ca, Na)(Fe3+, Cu)2(AsO4)3, a new alluaudite-group mineral from Tolbachik fumaroles, Kamchatka peninsula. Russia Eur J Mineral 25(4):683–691
Naqash S, Gerhards M, Tietz F, Guillon O (2018) Coefficients of thermal expansion of Al- and Y-substituted NaSICON solid solution Na3+2xAlxYxZr2–2xSi2PO12. Batteries 4(3):33
Pekov IV, Koshlyakova NN, Agakhanov AA, Zubkova NV, Belakovskiy DI, Vigasina MF, Turchkova AG, Sidorov EG, Pushcharovsky DYu New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XV. Calciojohillerite, NaCaMgMg2(AsO4)3, a member of the alluaudite group. Miner Mag, submitted
Pekov IV, Lykova IS, Koshlyakova NN, Belakovskiy DI, Vigasina MF, Agakhanov AA, Britvin SN, Turchkova AG, Sidorov EG, Giester G (2016) Magnesiohatertite, IMA 2016-078. CNMNC Newsletter No. 34, December 2016, page 1319; Mineral Mag 80(7):1315–1321
Pekov IV, Koshlyakova NN, Belakovskiy DI, Vigasina MF, Zubkova NV, Agakhanov AA, Britvin SN, Sidorov EG, Pushcharovsky DY (2018) Khrenovite, IMA 2017-105. CNMNC Newsletter No. 42, April 2018, page 448; Mineral Mag 82(2):445–451
Pekov IV, Koshlyakova NN, Zubkova NV, Lykova IS, Britvin SN, Yapaskurt VO, Agakhanov AA, Shchipalkina NV, Turchova AG, Sidorov EG (2018) Fumarolic arsenates—a special type of arsenic mineralization. Eur J Mineral 30(2):305–322
Pekov IV, Koshlyakova NN, Belakovskiy DI, Vigasina MF, Zubkova NV, Agakhanov AA, Britvin SN, Sidorov EG, Pushcharovsky DY (2018) Paraberzeliite, IMA 2018-001. CNMNC Newsletter No 43, June 2018, page 780; Mineral Mag 82(3):779–785
Pekov IV, Zubkova NV, Agakhanov AA, Yapaskurt VO, Chukanov NV, Belakovskiy DI, Sidorov EG, Pushcharovsky DY (2018a) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia VIII Arsenowagnerite, Mg2(AsO4)F. Mineral Mag 82(4):877–888
Pekov IV, Zubkova NV, Agakhanov AA, Ksenofontov DA, Pautov LA, Sidorov EG, Britvin SN, Vigasina MF, Pushcharovsky DY (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)4. Mineral Mag 83(4):485–495
Pekov IV, Agakhanov AA, Zubkova NV, Koshlyakova NN, Shchipalkina NV, Sandalov FD, Yapaskurt VO, Turchkova AG, Sidorov EG (2020) Oxidizing-type fumarolic systems of the Tolbachik volcano—a mineralogical and geochemical unique. Russ Geol Geophys 61(5–6):675–688
Pekov IV, Koshlyakova NN, Agakhanov AA, Zubkova NV, Belakovskiy DI, Vigasina MF, Turchkova AG, Sidorov EG, Pushcharovsky DY (2020b) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIV. Badalovite, NaNaMg(MgFe3+)(AsO4)3, a member of the alluaudite group. Mineral Mag 84(4):616–622
Pekov IV, Lykova IS, Koshlyakova NN, Belakovskiy DI, Vigasina MF, Turchkova AG, Britvin SN, Sidorov EG, Scheidl KS (2020c) A new mineral species zincobradaczekite, NaCuCuZn2(AsO4)3, and a new isomorphous series bradaczekite–zincobradaczekite in the alluaudite group. Phys Chem Miner 47(8):36
Petřiček V, Dušek M, Palatinus L (2006) Jana2006. Structure determination software programs. Institute of Physics, Praha
Shablinskii AP, Filatov SK, Vergasova LP, Avdontseva EY, Moskaleva SV (2018) Wrightite, K2Al2O(AsO4)2, a new oxo-orthoarsenate from the Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik volcano, Kamchatka peninsula. Russia Mineral Mag 82(6):1243–1251
Shablinskii AP, Filatov SK, Vergasova LP, Avdontseva EY, Moskaleva SV, Povolotskiy AV (2019) Ozerovaite, Na2KAl3(AsO4)4, new mineral species from Tolbachik volcano, Kamchatka peninsula. Russia Eur J Mineral 31(1):159–166
Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A 32:751–767
Sleight AW (1998) Compounds that contract on heating. Inorg Chem 37:2854–2860
Vergasova LP, Filatov SK (2012) New mineral species in products of fumarole activity of Great Tolbachik fissure eruption. J Volcanol Seismol 6(5):281–289
Vergasova LP, Filatov SK (2016) A study of volcanogenic exhalation mineralization. J Volcanol Seismol 10(2):71–85
Warner TE, Milius W, Maier J (1994) New copper phosphates with the NASICON or alluaudite-type structures as ionic or mixed conductors. Solid State Ionics 74:119–123
Acknowledgements
This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the scientific tasks of the Institute of Silicate chemistry (Russian Academy of Sciences) [project number 0097-2019-0013] and the Russian Foundation for Basic Research [grant number 18-29-12106]. Technical support by the SPbSU X-ray Diffraction Centre is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Shablinskii, A.P., Melnikova, N.A., Vergasova, L.P. et al. Thermal expansion, shear deformations and electrical conductivity of alluaudite-group minerals (badalovite and calciojohillerite). Phys Chem Minerals 48, 14 (2021). https://doi.org/10.1007/s00269-021-01135-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00269-021-01135-9