Physics and Chemistry of Minerals

, Volume 44, Issue 2, pp 125–135 | Cite as

Thermal behavior of polyhalite: a high-temperature synchrotron XRD study

  • Hongwu XuEmail author
  • Xiaofeng Guo
  • Jianming Bai
Original Paper


As an accessory mineral in marine evaporites, polyhalite, K2MgCa2(SO4)4·2H2O, coexists with halite (NaCl) in salt formations, which have been considered as potential repositories for permanent storage of high-level nuclear wastes. However, because of the heat generated by radioactive decays in the wastes, polyhalite may dehydrate, and the released water will dissolve its neighboring salt, potentially affecting the repository integrity. Thus, studying the thermal behavior of polyhalite is important. In this work, a polyhalite sample containing a small amount of halite was collected from the Salado formation at the WIPP site in Carlsbad, New Mexico. To determine its thermal behavior, in situ high-temperature synchrotron X-ray diffraction was conducted from room temperature to 1066 K with the sample powders sealed in a silica-glass capillary. At about 506 K, polyhalite started to decompose into water vapor, anhydrite (CaSO4) and two langbeinite-type phases, K2Ca x Mg2-x (SO4)3, with different Ca/Mg ratios. XRD peaks of the minor halite disappeared, presumably due to its dissolution by water vapor. With further increasing temperature, the two langbeinite solid solution phases displayed complex variations in crystallinity, composition and their molar ratio and then were combined into the single-phase triple salt, K2CaMg(SO4)3, at ~919 K. Rietveld analyses of the XRD data allowed determination of structural parameters of polyhalite and its decomposed anhydrite and langbeinite phases as a function of temperature. From the results, the thermal expansion coefficients of these phases have been derived, and the structural mechanisms of their thermal behavior been discussed.


Polyhalite Thermal decomposition Anhydrite Langbeinite Crystal structure Thermal expansion Synchrotron X-ray diffraction Salt repository 



This work was supported by the University of California Lab Fees Research Program (Grant #237546). Use of the National Synchrotron Light Source at Brookhaven National Laboratory was supported by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, under contract no. DE-AC02-98CH10886. Los Alamos National Laboratory is operated by Los Alamos National Security LLC, under DOE Contract DE-AC52-06NA25396. We thank the two anonymous reviewers for their helpful comments.


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Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  1. 1.Earth and Environmental Sciences DivisionLos Alamos National LaboratoryLos AlamosUSA
  2. 2.National Synchrotron Light Source IIBrookhaven National LaboratoryUptonUSA

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