Abstract
An unresolved issue in the study of pressure solution in rock materials is the dependence of grain boundary structure and diffusive properties on the mutual orientation of neighbouring grain lattices. We report electrical measurements yielding the diffusivity of differently oriented halite–glass and halite–halite contacts loaded in the presence of brine. The halite–glass contact experiments show pressure solution of the halite and an effect of halite lattice orientation on grain boundary transport. Post-mortem observations show an orientation-dependent grain boundary texture controlled by the periodic bond chains in the halite structure. It is inferred that this texture determines the internal grain boundary structure and properties during pressure solution. In the halite–halite experiments neck-growth occurred, its rate depending on twist-misorientation. The results imply that deformation by pressure solution may lead to lattice-preferred orientation development, and that polymineralic rocks may deform faster at lower stresses than monomineralic rocks.
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Acknowledgments
This research and the position of RvN were funded by the The Netherlands Organisation for Scientific Research, grant number 814.01.001. The authors would like to thank Eimert de Graaff for his outstanding technical support and Peter van Krieken for his help with the SEM.
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van Noort, R., Spiers, C.J. & Peach, C.J. Effects of orientation on the diffusive properties of fluid-filled grain boundaries during pressure solution. Phys Chem Minerals 34, 95–112 (2007). https://doi.org/10.1007/s00269-006-0131-9
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DOI: https://doi.org/10.1007/s00269-006-0131-9