Abstract
Cesium and Strontium concentrations were analyzed in eight pedogenetic soil profiles developed on different rocks from a semiarid mediterranean region: La Mancha (Central Spain). Concentration activities of 137Cs and 90Sr, as for some soil properties, were also measured. The results are presented in this document: Cs concentrations range between 0.4 and 18.3 mg kg−1 and Sr varies widely between 11.0 and 3,384 mg kg−1. Therefore, it is clear that there is a broad range of concentrations and there are also values significantly higher than the average values stated by several authors. Concentrations of long-life artificial radionuclides (137Cs, 90Sr) were determined in some of the same soils. The activity concentration mean values (Bq kg−1) were ranging between 0.82 and 21.76 for 137Cs and 90Sr variations range between 6.73 and 0.35. There were no significant correlations between radionuclides and stable trace elements. The data indicate that the soils do not show significant radioactivity of these elements and therefore they do not pose a danger. By the same token, no risk of contamination by this activity was detected. Finally, spatial patterns seem to be affected by the soil type and some soil properties.
Similar content being viewed by others
References
Aloway BJ (1990) Heavy metals in soils. Blackie and Son, UK
Aubert D, Probst A, Stille P (2004) Distribution and origin of major and trace elements (particularly REE, U and Th) into labile and residual phases in an acid soil profile (Vosges Mountains, France). Appl Geochem 19:899–916
Bowen JM (1979) Environmental chemistry of the elements. Academic Press, London
Collado Fernández DM, Sánchez Garrido JA, Navarro Flores A, del Moral Torres F (2000) Suelos desarrollados sobre materiales aluviales afectados por actividades mineras en El Arteal (Cuevas de Almanzora, Almería). Edafología 7–3:217–225
Conde P, Martín Rubí JA, Jiménez Ballesta R (2007) Chemical vulnerability of red soils in La Mancha (Central Spain). Sci Total Environ 378:228–232. doi:10.1016/j.scitotenv.2007.01.082
Baeza A, Del Rio M, Jiménez A, Miro C, Paniagua J (1995) Influence of geology and soil particle size on the surface area/volume activity ratio for natural radionuclides. J Radional Nucl Chem 189:289–299
Bonnett P (1990) A review of the erosional behaviour of radionuclides in selected drainage basins. J Environ Radioact 11:251–266
Bunzl A, Albers BP, Schimmack W, Belli M, Ciuffo L, Menegon S (2000) Examination of a relationship between 137Cs concentration in soils and plants from alpine pastyres. J Environ Radioact 48:145–158
Chapman SL, Horn ME (1968) Parent material uniformity and origin of silty soils in northwest Arkansas based on zirconium–titanium contents. Soil Sci Soc Am Proc 32:265–271
Cowart JB, Burnett WC (1994) The distribution or uranium and thorium decay-series radionuclides in the environment—a review. J Environ Qual 23:651–662
Evans DW, Alberts JA, Clark RA (1983) Reversible ion exchange fixation os caesium-137 leading to mobilisation from reservoir sediments. Geochim Cosmochim Acta 47:1041–1049
FAO7UNESCO (1977) Guidelines for soils profile description. FAO, Rome
FAO/UNESCO (1990) Soil map of the world. Revised legend. Soils bulletin 60. FAO, Rome
Knatko VA, Ageets VU, Shmigelskaya IV, Ivashkevich II (2000) Soil to potato transfer of 137Cs in a area of Belarus: regression analysis of the transfer factor against 137Cs deposition and soil characteristics. J Environ Radioact 48:171–181
Kilmer V, Alexander L (1949) Methods of making mechanical analysis of soils. Soil Sci 68:15–24
Kisch H (1990) Recommendations on illite crystallinity. IGCP Project 294, VIGM 1–9
Klechkovskiy VM, Fedorov EA, Archipov NP, Romanov NG, Alexakhim RM, Fevraleva LT (1973) The regularities of soil and aerial pathways of radioactive strontium uptake by farm crops. Pochvovedenie 5:38–47 (in Russian)
Krishna AK, Govil PK (2007) Soil contamination due to heavy metals from an industrial area of Surat, Gujarat, Western India. Environ Monit Assess 124:263–275
Lai S, Weng P, Lin Y, Chu T (1995) Investigation of radiocesium in the natural terrestrial environment in Taiwan. In: The 4th symposium on environmental radiation monitoring technology proceedings, Taiwan Radiation Monitoring Center. Atomic Energy Council, Kaohsiung, Taiwan pp F-4-1–F-4-10
Livens FR, Loveland P (1988) The influence of soil properties on the environmental mobility of caesium in Cumbria. Soil Use Manage 4:69–75
Manjón G, El-Daoushy F, Garc!ıa-Tenorio R (1997) 90–Sr in lake sediments. J Radioanal Nucl Chem 219:95-98
Martínez Cortizas A, García-Rodeja E, Novoa Muñoz JC, Pontevedra Pombal X, Buurman P, Terribile F (2003) Distribution of some selected major and trace elements in four Italian soils developed from the deposits of the Gauro and Vico volcanoes. Geoderma 117:215–224
Morton LS, Evans CV, Harbotle G, Estes GO (2001) Pedologic fractionation and bioavailability of uranium and thorium in naturally radiactive Spodosols. Soil Sci Soc Am J 65:1197–1203
Murad E (1978) Yttrium and zirconium as geochemical guide elements in soil and stream sediment sequences. J Soil Sci 29:219–223
Murakami T, Ohnuki T, Isobe H, Sato T (1997) Mobility of uranium during weathering. Am Mineral 82:888–899
Navas A, Soto J, Machin J (2003) Edaphic and physiographic factors affecting the distribution of natural gamma-emiting radionuclides in the soils of the Amas catchment in the central Spanish Pyrenees. Eur J Soil Sci 53:629–638
Palumbo B, Angelone M, Bellanca A, Dazzi C, Hauser S, Nery R, Wilson J (2000) Influence of inheritance and pedogenesis on heavy metals distribution in soils of Sicily, Italy. Geoderma 95:247–266
Prister BS, Perepelyatnikova LV, Ivanova TN, Vynogradskaya VD, Kalinenko LV, Grytsjuk NR, Rudenko VA, Perepelyatnikov GP, Pojarkov VA (2003) The classification of soil systems on the basis of transfer factors or radionuclides from soil to reference plants. Final report to the IAEA. The classification of Ukrainian soil systems on the basis of transfer factors of radionuclides from soils to reference plants. European Centre of Technogenic Safety, Kiev
Quindos LS, Fernandez PL, Soto J, Rodenas C, Gomez J (1994) Natural radioactivity in Spanish soils. Health Phys 66(2):194–200
Rose, et al (1979) Departamento de Minas/Área de Geología/Universidad de Atacama/Chile http://www.plata.uda.cl/minas/index.html, 21/07/05, Exploraciones Mineras, Métodos analíticos del laboratorio. Cap. 3. Método geoquímico de exploración. Susanne Griem-Klee
Sawhney BL (1972) Selective sorption and fixation of cations by clay minerals: a review. Clays Clay Miner 20:93–100
Schacklette HT, Boerngen JG (1984) Element concentration in soils and other surficial materials of the conterminous United States. US Geological Survey Prof Paper 1270
Schultz L (1964) Quantitative interpretation of mineralogical composition from X-ray and chemical data for Pierce Shale. US Geol Surv Prof Pap 391-C
Schulz RK, Overstreet R, Barsahd I (1960) On the chemistry of caesium-137. Soil Sci 89:16–27
Skarlou V, Nobeli C, Anoussis J, Haidouti C, Papanicolau E (1999) Transfer factors of 137Cs for olive and orange trees grown on different soils. J Environ Radioact 45:139–147
Smeck NE, Wilding NP (1980) Quantitative evaluation of pedon formation in calcareous glacial deposits in Ohio. Geoderma 24:1–6
Smith JT, Ellis KM (1982) Transport mechanism for Pb-220, Cs-137 and Pu fallou radionuclides through fluvial–marine systems. Geochim Cosmochim Acta 46:941–954
Smith JN, Comans RNJ (1996) Modeling the diffusive transport and remobilisation of 137Cs in sediments:the effects of sorption kinetics and reversibility. Geochim Cosmochim Acta 60:995–1004
Smith H, Wilding LP (1972) Genesis of argillic horizons in Ochraqualfs derived from fine textured till deposit of northwestern Ohio and southwestern Michigan. Soil Sci Soc Am Proc 36:808–815
Soon YK, Abboud S (1990) Trace elements in agricultural soils of north-western Alberta. Can J Soil Sci 70:277–288
Soil Conservation Service (1972) Soil survey laboratory methods and procedures for collecting soil samples. USDA SSIR 1. Washington, 72 pp
Tyler G (2004) Vertical distribution of major, minor, and rare elements in a Haplic Podzol. Geoderma 119:277–290
Tyler G, Olsson T (2001) Concentrations of 60 elements in the soil solution as related to the soil acidity. Eur J Soil Sci 52:1–15
Vaca F, Manjón G, Cuellar S, García-León M (2001a) Factor of merit and minimum detectable activity for 90-Sr determinations by gas-flow proportional counting or Cherenkov counting. Technical Note Applied Radiation Isotopes 55:849–851
Vaca F, Manjón G, García-León M (2001b) The presence of some artificial and natural radionuclides in a Eucalyptus forest in the south of Spain. J Environ Radioact 56:309–325
Walton A (1963) The distribution in soil of radioactivity from weapons tests. J Geophys Res 68:1445–1486
Walling DE, Quine TA (1995) Use of fallout radionuclide measurement in soil erosion investigations. In: Nuclear technique in soil-plant studies for sustainable agriculture and environment preservation. Proceeding of the International Symposium. International Atomic Agency, Vienna 17–21: 597–619
Walkley A, Black YA (1949) An examination of the Detjareff method for determining soil organic matter and a proposed modification on the chromic acid titration methods. Soil Sci 37:29–38
Wedepohl KH (1995) The composition of the continental crust. Geochem Cosmochim Acta 59:1217–1232
Acknowledgments
This work has been funded by a research fellowship of the Geological Survey of Spain (IGME).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Conde Bueno, P., Martín Rubí, J.A. & Jiménez Ballesta, R. Environmental evaluation of elemental cesium and strontium contents and their isotopic activity concentrations in different soils of La Mancha (Central Spain). Environ Geol 56, 327–334 (2008). https://doi.org/10.1007/s00254-007-1168-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00254-007-1168-x