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Geochemical data as indicators of environmental change and human impact in sediments derived from downstream marshes of an ephemeral river, Northeast China

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Environmental Geology

Abstract

Recent sedimentary history of natural environmental change and anthropogenic influence in an ephemeral river catchment has been reconstructed using selected major and trace elements, element ratios, and their different geochemical phases (Tessier sequential extraction methods), pollen, and grain size combined with 210Pb- and 137Cs-dating method in marsh sedimentary cores. Attempts were made to use selected element ratios with different geochemical phases—residual phase of Ti, Al, V, Cr, Ni, Rb, K, Sr, and Ba; mobile Sr and Ba—combined with 210Pb- and 137Cs-chronology to interpret certain time information of environmental changes saved within the marsh sediments. Results indicate that there were two marked humid periods during 1850–1860 ad and 1890–1920 ad, and sand storm activities prevailed during 1920–1930 ad. After about 1900 ad, soil erosion has increased with the extensive agricultural activities in the Huolin River catchments, and further intensified after 1950s. After 1980, soil erosion has become even more intense, which is consistent with the reinforcement of human activities, the drastic loss of vegetation cover in the upstream lands, especially, the exploitation of the open cast coalmine in the upstream of Huolin River at that time. Influenced by the inundation of the Huolin River, the heavy metal pollution historical trends in Xianghai marsh wetland could be roughly divided into three periods by analysis of sediment enrichment factor (KSEF) and the index of geoaccumulation (I geo):1760–1880 ad, 1880–1980 ad, and 1980–now. Human activities accelerate the inputs of heavy metal, which leads to degradation of the marsh. This study also investigated on source of marsh sediments (by Ti/Al), redox condition [by V/Cr and V/(V + Ni)], and salinization indicators (by Sr/Ba and Rb/K). The results demonstrate that sources of sediments and redox conditions were partly similar for both riparian and depressional marshes. Besides, some differences in degree of salinization between two types of marsh were also identified, especially after 1880.

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References

  • Appleby PG, Oldfield F (1978) The calculation of lead-210 dates assuming a constant rate of supply of unsupported 210 Pb to the sediment. Catena 5:1–8

    Article  Google Scholar 

  • Brenner M, Schelske CL, Keenan LW (2001) Historical rates of sediment and nutrient accumulation in marshes of the Upper St. Johns River Basin, Florida, USA. J Paleolimnol 26:241–257

    Article  Google Scholar 

  • Davis C, Pratt L, Silter W, Mompart L, Murat B (1999) Factors influencing organic carbon and trace metal accumulation in the Upper Cretaceous La Luna Formation of the western Maracaibo Basin, Venezuela. Special Paper 332 of Geol Soc Am, pp 203–230

  • DeLaune RD, Patrick WHJ, Buresh RJ (1978) Sedimentation rates determined by 137Cs dating in a rapidly accreting salt marsh. Nature 275:532–533

    Article  Google Scholar 

  • Editorial Committee of local chronicles of Jilin province (ECLC of Jilin Province) (1996) Climate history. In: Annals of Jilin Province (in Chinese). Jilin people’s press, Changchun, vol 35

  • El-Moslinmany A (1990) The ecological significance of common non-arboreal pollen: Example from dry land of the Middle East. Rev Palaeobot Palynol 64:343–350

    Article  Google Scholar 

  • Faegri K, Iversen J (1989) Textbook of pollen analysis, 4th edn. Wiley, New York, pp 328

    Google Scholar 

  • Forstner U, Wittmann G (1979) Metal pollution in the aquatic environment. Springer, Berlin

    Google Scholar 

  • Forstner U, Ahlf W, Calmano W (1993) Sediment quality objectives and criteria development in Germany. Water Sci Technol 28:307–314

    Google Scholar 

  • Fox WM, Johnsona MS, Jones SR, Leah RT, Copplestone D (1999) The use of sediment cores from stable and developing salt marshes to reconstruct historical contamination profiles in the Mersey Estuary, UK. Mar Environ Res 47:311–329

    Article  Google Scholar 

  • Fritz SC (1996) Paleolimnological records of climatic change in North America. Limnol Oceanogr 41(5):882–889

    Article  Google Scholar 

  • Goff JR, Chague-Goff C (1999) A late Holocene record of environmental changes from coastal wetlands: Abel Tasman National Park, New Zealand. Quat Int 56:39–51

    Article  Google Scholar 

  • Green-Ruiz C, Paez-Osuna F (2001) Heavy metal anomalies in lagoon sediments related to intensive agriculture in Altata-Ensenada del Pabellon coastal system (SE Gulf of California). Environ Int 26(4):265–273

    Article  Google Scholar 

  • Herzschuh U, Tarasov P, Wunnemann B, Hartmann K (2004) Holocene vegetation and climate of the Alashan Plateau, NW China, reconstructed from pollen data. Palaeogeogr Palaeoclimatol Palaeoecol 211:1–17

    Article  Google Scholar 

  • Jordan MM, Navarro-Pedreno J, Garcia-Sanchez E, Mateu J, Juan P (2004) Spatial dynamics of soil salinity under arid and semi-arid conditions: geological and environmental implications. Environ Geol 45(4):448–456

    Article  Google Scholar 

  • Keddy PA (2000) Wetland ecology principles and conservation. Cambridge University Press, London

    Google Scholar 

  • Kim JG, Rejmankova E (2001) The paleoecological record of human disturbance in wetlands of the Lake Tahoe Basin. J Paleolimnol 25:437–454

    Article  Google Scholar 

  • Kim JG, Rejmankova E, Spanglet HJ (2001) Implications of a sediment-chemistry study on subalpine marsh conservation in the Lake Tahoe Basin, USA. Wetlands 21(3):379–394

    Article  Google Scholar 

  • Kim JG, Rejmankova E (2002) Recent history of sediment deposition in marl- and sand-based marshes of Belize, Central America. Catena 48:267–291

    Article  Google Scholar 

  • Last WM, Smol JP (2001) An introduction to physical and geochemical methods used in paleolimnology. In: Last WM, Smol JP (eds) Tracking environmental change using lake sediments: physical and geochemical methods. Kluwer, Dordrecht, vol 2, pp 1–5

  • Li X, Wai OWH, Li YS, Coles BJ, Ramsey MH, Thornton I (2000) Heavy metal distribution in sediment profiles of the Pearl River estuary, South China. Appl Geochem 15:567–581

    Article  Google Scholar 

  • Lin N, Tang J (2002) Geological environment and causes for desertification in arid-semiarid regions in China. Environ Geol 41(7):806–815

    Article  Google Scholar 

  • Liu X (2001) Management on degraded land and agricultural development in the Songnen Plain (in Chinese with English abstract). Science Press, Beijing

    Google Scholar 

  • Liu L, Chen J, Chen Y, Ji J (2002) Sequential extraction procedure of loess and paleosol and implications of Rb/Sr ratios (in Chinese with English abstract). Acta Pedologica Sinica 39(1):65–70

    Google Scholar 

  • Lopez-Buendya AM, Bastida J, Querol X, Whateley MKG (1999) Geochemical data as indicators of palaeosalinity in coastal organic-rich sediments. Chem Geol 157:235–254

    Article  Google Scholar 

  • Mitchell AC, Brown GH, Fuge R (2006) Minor and trace elements as indicators of solute provenance and flow routing in a subglacial hydrological system. Hydrol Process 20(4):877–897

    Article  Google Scholar 

  • Nakamura F, Kameyama S, Mizugaki S (2004) Rapid shrinkage of Kushiro Mire, the largest mire in Japan, due to increased sedimentation associated with land-use development in the catchment. Catena 55(2):213–229

    Article  Google Scholar 

  • Neubauer SC, Anderson IC, Constantine JA, Kuehl SA (2002) Sediment deposition and accretion in a mid-atlantic (USA) tidal freshwater marsh. Estuar Coast Shelf Sci 54:713–727

    Article  Google Scholar 

  • Nriagu JO (1990) Human influence on the global cycling of trace metals. Palaeogeogr Palaeoclimatol Palaeoecol (Global Planet Change Section) 82:113–120

    Google Scholar 

  • Owens PN, Walling DE, Leeks GJL (1999) Use of floodplain sediment cores to investigate recent historical changes in overbank sedimentation rates and sediment sources in the catchments of the River Ouse, Yorkshire, UK. Catena 36(1–2):21–47

    Article  Google Scholar 

  • Qiu Sh (1990) Formation and evolution of natural environment of quaternary in Northeast Plain of China (in Chinese with English abstract). Harbin map publishing house, Harbin

  • Sanchez-Carrillo, Salvador, Miguel Alvarez-Cobelas, David G Angeler (2001) Sedimentation in the semi-arid freshwater wetland Las Tablas De Daimiel (Spain). Wetlands 21(1):112–124

    Article  Google Scholar 

  • Schaller T, Moor HC, Wehrli B (1997) Sedimentary profiles of Fe, Mn, V, Cr, As and Mo as indicators of benthic redox condition in Baldeggersee. Aquat Sci 59(4):345–361

    Article  Google Scholar 

  • Shaw DM (1968) A review of K-Rb fractionation trends by covariance analysis. Geochim Cosmochim Acta 32:573–601

    Article  Google Scholar 

  • Soto-Jimenez M, Paez-Osuna F, Ruiz-Fernandez AC (2003) Geochemical evidences of the anthropogenic alteration of trace metal composition of the sediments of Chiricahueto marsh (SE Gulf of California). Environ Pollut 125(3):423–432

    Article  Google Scholar 

  • Sun T, Jiang F (1996) Environmental impact and ecological engineering for exploit coalmine in the prairies (in Chinese). Science Press, Beijing

    Google Scholar 

  • Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844–851

    Article  Google Scholar 

  • Wang A (1996) Discriminant effect of sedimentary environment by the Sr/Ba ratio of different existing forms (in Chinese with English abstract). Acta Sedimentologica Sinica 14(4):168–173

    Google Scholar 

  • Wang G, Liu J, Tang J (2004) Historical variation of heavy metals with respect to different geochemical phases in recent sediments from Xianghai Wetlands, Northeast China. Wetlands 24(3):608–619

    Article  Google Scholar 

  • Williams TP, Bubb JM, Lester JN (1994) Metal accumulation within salt marsh environments: A review. Mar Pollut Bull 28(5):277–290

    Article  Google Scholar 

  • Yan J, Zhang H (1996) Paleo-oxygenation facies: A new research field in sedimentology (in Chinese with English abstract). Geol Sci Technol Inf 15(3):7–13

    Google Scholar 

  • Yan M, Chi Q (1997) Abundance of elements in crust and rocks in Eastern China (in Chinese). Science Press, Beijing

    Google Scholar 

  • Zhang D, Wang Sh (2001) Mechanism of freeze-thaw action in the process of soil salinization in northeast China. Environ Geol 41(1–2):96–100

    Article  Google Scholar 

  • Zheng X, Lu Y (1995) Formation and evolution environment of Dabusu alkaline lake (in Chinese with English abstract). J Salt Lake Sci 3(4):10–17

    Google Scholar 

  • Zwolsman JJG, Berger GW, Van Eck GTM (1993) Sediment accumulation rates, historical input, postdepositional mobility and retention of major elements and trace metals in salt marsh sediments of the Scheldt estuary, SW Netherlands. Mar Chem 44:73–94

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to thank the reviewers for their helpful and constructive reviews of this paper. We also gratefully acknowledge Dr. Bai Junhong for valuable help with the sampling, Zhang Yuxia and Xia Weilan for samples analyses, and The National Natural Science Foundation of China (No. 40471136) and the Discovery Research Project of Chinese Academy of Sciences (No. KZCX2-YW-309) for financial support. Key Laboratory of Ecological Recovering and Ecosystem Management of Jilin Province (Project number: DS2004–01) partly funded this research.

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Correspondence to Guo-Ping Wang.

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Wang, GP., Zhai, ZL. Geochemical data as indicators of environmental change and human impact in sediments derived from downstream marshes of an ephemeral river, Northeast China. Environ Geol 53, 1261–1270 (2008). https://doi.org/10.1007/s00254-007-0714-x

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