Skip to main content
Log in

Characterization of surface water and groundwater in the Damascus Ghotta basin: hydrochemical and environmental isotopes approaches

  • Original Article
  • Published:
Environmental Geology

Abstract

The hydrochemistry of major ions and environmental isotope compositions (18O, 2H and tritium) of water samples have been used to investigate the characteristics of rainfalls, surface water and groundwater in the Damascus Ghotta basin. The groundwater salinity in the Damascus Ghotta basin gradually increases, as the groundwater moves from western to south-eastern and north-eastern parts of the basin. A strong relationship exists between the Barada river and the surrounded groundwaters, mainly in terms of recharge by infiltration of surface waters. The groundwater quality in the Adra region has clearly become less saline as a result of establishment of the sewage-water-treatment station in this area since 1997. The uncommon depleted stable isotope concentrations in the vicinity of Al-Ateibeh Lake and Adra valley could be interpreted as a result of sub-flow recharge from the Cenomanian–Turonian aquifer, mostly prolonged along the Damascus Fault, which forms direct contact between this complex and the Quaternary alluvium aquifers. The extensive exploitation of water from the Cenomanian–Turonian aquifer for drinking water supply would shortly be reflected by a gradual decline of the groundwater table in the Damascus Ghotta basin. Amelioration of water quality in the Damascus basin still requires further management strategies and efforts to be taken within the forthcoming years.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18
Fig. 19
Fig. 20
Fig. 21
Fig. 22
Fig. 23

Similar content being viewed by others

References

  • Billen G, De Becker E, Lancelot C, Mathot S, Servais P, Stainier E (1985) Etude des processus de transfert, d’immobilisation et de transformation de l’azote dans son cheminement depuis les sols agricoles jusqu’a la mer. Rapport C.E.E., contrat n Env-522-B (RS)

  • Carmi I, Gat JR (1973) Tritium in precipitation and freshwater sources in Israel. Isr J Earth Sci 22:71–92

    Google Scholar 

  • Clark ID, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publishers, Boca Raton

    Google Scholar 

  • Craig H (1961) Isotopic variations in meteoric waters. Science 133:1702

    Article  Google Scholar 

  • Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16:436–468

    Article  Google Scholar 

  • Dermine B (1985) Bilans des charges en nutriments charriés au long du cours de la Meuse Belge. Thèse doct., Facultés Universitaires de Namur

  • Dincer I, Payne BR (1971) An environmental isotope study of the south-western karst region of Turkey. J Hydrol 14:233–258

    Article  Google Scholar 

  • Dubertret L (1932) L’Hydrologie et aperçu sur l’Hydrographie de la Syrie et du Liban dans leurs relations avec la géologie. Rev Géogr Phys Géol Dynamique, TVI fas. 4

  • Eriksson E (1983) Stable isotopes and tritium in precipitation. In: Guidebook on nuclear techniques in hydrology. Technical reports series no. 91, IAEA, Vienna

  • Fontes JC (1983a) Dating of groundwater. In: Guidebook on nuclear techniques in hydrology. Technical reports series no. 91, IAEA, Vienna

  • Fontes JC (1983b) Groundwater in fractured rocks. In: Guidebook on nuclear techniques in hydrology. Technical reports series no. 91, IAEA, Vienna

  • Fontes JC, Olivry JC (1976) Gradient isotopique entre 0 et 4000 m dans les précipitations du Mont Cameroun. Résume, CR Reun Ann Sci Terre, Paris, Soc. Géolo. Français, pp 1–171

  • Friedman I, Smith GI, Gleason JD, Warden A, Harris JM (1992) Stable isotope composition of waters in southeastern California I. Modern precipitation. J Geophys Res 97(D5):5795–5812

    Google Scholar 

  • Fritz P (1981) River waters. In: Stable isotope hydrology, deuterium and oxygen-18 in the water cycle. Technical reports series no. 210, IAEA, Vienna

  • Fritz P, Fontes JC (1980) Handbook of environmental isotope geochemistry. Elsevier Scientific Publication Co., Amsterdam, The Netherlands

    Google Scholar 

  • Gasparini A, Custudio E, Fontes JC, Jimenez J, Nunez JA (1990) Exemple d’étude gèochimique et isotopique de circulations aquifères en terrain volcanique sous climat semi-aride (Amurga, Gran Canaria, Iles Canaries). J Hydrol 114:61–91

    Article  Google Scholar 

  • Gat JR (1974) Local variability of the isotopic composition of groundwater. In: Proceedings of a symposium on isotope techniques in groundwater hydrology, IAEA, Vienna

  • Gat JR (1980) The isotopes of hydrogen and oxygen in precipitation. In: Fritz P, Fontes JC (eds) Handbook of environmental isotope geochemistry. Elsevier, New York

    Google Scholar 

  • Gat JR (1996) Oxygen and hydrogen isotopes in the hydrologic cycle. Ann Rev Earth Planet Sci 24:225–262

    Article  Google Scholar 

  • Gat JR, Carmi I (1970) Evolution of the isotopic composition of atmospheric water in the Mediterranean Sea Area. J Geophys Res 75:3039–3048

    Google Scholar 

  • Gat JR, Dansgaard W (1972) Stable isotope survey of the fresh water occurrence in Israel and the northern Jordan rift valley. J Hydrol 16:177–212

    Article  Google Scholar 

  • Gat JR, Matsui E (1991) Atmospheric water balance in the Amazon Basin. An isotopic evapo-transpiration model. J Geophys Res 96:13179–13188

    Google Scholar 

  • Gat JR, Tzur Y (1967) Modification of the isotopic composition of rain water by processes which occur before groundwater recharge. In: Proceedings of a symposium on isotope hydrology, IAEA, Vienna

  • Gonfiantini R, Gallo G, Payne BR, Taylor CB (1976) Environmental isotopes and hydrochemistry in groundwater of Gran Canaria. In: Proceedings of a group meeting on interpretation of environmental isotope and hydrochemical data in groundwater hydrology, IAEA, Vienna

  • Gonfiantini R, Roche MA, Olivry JC, Fontes JC, Zuppi GM (2001) The altitude effect on the isotopic composition of tropical rains. Chem Geol 181:147–167

    Article  Google Scholar 

  • Hadid B (1989) The strategy to develop water resources, assertion on long-term planning. Ministry of Irrigation, Syrian Arab Republic, Damascus (in Arabic)

  • Hem JD (1992) Study and interpretation of the chemical characteristics of natural waters. US Geological Survey water-supply paper 2254. US Geological Survey, Reston

  • Hsu KJ (1963) Solubility of dolomite and composition of Florida groundwaters. J Hydrol 1:288–310

    Article  Google Scholar 

  • IAEA (1980a) Arid zone hydrology, investigations with isotope techniques. In: Proceedings of an advisory group meeting, IAEA, Vienna

  • IAEA (1980b) Nuclear techniques in groundwater pollution research. In: Proceedings of an advisory group meeting, IAEA, Vienna

  • IAEA (1981) Statistical treatment of environmental isotope data in precipitation. Technical reports series no. 206. IAEA, Vienna

  • IAEA (1983a) Guidebook on nuclear techniques in hydrology. Technical reports series no. 91, IAEA, Vienna

  • IAEA (1983b) Palaeoclimates and palaeowaters, a collection of environmental isotope studies. In: Proceedings of an advisory group meeting, IAEA, Vienna

  • IAEA (1987) Isotope techniques in water resources development. In: Proceedings of a symposium, IAEA, Vienna

  • IAEA (1991) Isotope techniques in water resources development. In: Proceedings of a symposium, IAEA, Vienna

  • IAEA (1992) Statistical treatment of data on environmental isotopes in precipitation. Technical reports series no. 331, IAEA, Vienna

  • IAEA (1995) Isotopes in water resources management. In: Proceedings of a symposium, vol. 1–2, IAEA, Vienna

  • IAEA (1998) Application of isotope techniques to investigate groundwater pollution. IAEA-TECDOC-1046, IAEA, Vienna

  • JICA (2001) The study of water resources development in the western and central basins in Syrian Arab Republic, phase I (in Arabic), Ministry of Irrigation (Unpublished report)

  • Kattan Z (1995) Chemical and environmental isotope study of the fissured basaltic aquifer systems of the Yarmouk Basin (Syrian Arab Republic). In: Proceedings of international symposium on isotopes in water resources management, IAEA-SM-336/28, vol. 2, Vienna

  • Kattan Z (1997a) Chemical and environmental isotope study of precipitation in Syria. J Arid Environ 35:601–615

    Article  Google Scholar 

  • Kattan Z (1997b) Environmental isotope study of the major karst springs in Damascus limestone aquifer systems: case of the Figeh and Barada springs. J Hydrol 193:161–182

    Article  Google Scholar 

  • Kattan Z (2001a) Use of hydrochemistry and environmental isotopes for evaluation of groundwater in the Paleogene limestone aquifer of the Ras Al-Ain area (Syrian Jezireh). Environ Geol 41:128–144

    Article  Google Scholar 

  • Kattan Z (2001b) Use of environmental isotopes in studying surface and groundwaters in the Upper Orontes Basin: a case study of modeling elements and pollutants transport using the code PHREEQM. Final report on scientific research, AECS–G\FRSR 236, Damascus (in Arabic)

  • Kattan Z (2002a) Effects of sulphate reduction and geogenic CO2 incorporation on the determination of 14C groundwater ages—a case study of the Paleogene groundwater system in north-eastern Syria. Hydrogeol J 10:495–508

    Article  Google Scholar 

  • Kattan Z (2002b) Use of tritium for estimation of groundwater mean residence time, a case study of the Ain Al-Tanour and Ain Al-Samak karst springs (Central Syria). Sixth Arab conference on the peaceful uses of atomic energy, Cairo, Egypt (in Arabic)

  • Kattan Z (2004a) Use of environmental isotope techniques in studying surface and groundwaters in the Damascus basin (Al-Ghotta): a case study of geochemical modeling of elements and pollutants transport. Final report on scientific research, AECS–G\FRSR 313, Damascus (in Arabic)

  • Kattan Z (2004b) Use of 15N/14N ratio to evaluate the sources of nitrate pollution in surface and groundwaters in the Upper Orontes Basin (Central Syria). Seventh Arab conference on the peaceful uses of atomic energy, Yemen, Sana’a (in Arabic)

  • Kattan Z, Najjar H (2005) Groundwater salinity in the Khabour-Euphrates down-streams valleys. In: Groundwater and saline intrusion. Hidrogeología y Aguas Subterráneas, vol. 15. Instituto Geológico y Minero de España, Spain, pp. 565–583

  • Kempe S (1984) Sinks of the anthropogenically enhanced carbon cycle in surface fresh water. J Geophys Res 89(D3):4657–4676

    Article  Google Scholar 

  • Kendall C, Coplen TB (2001) Distribution of oxygen-18 and deuterium in river waters across the United States. Hydrol Process 15:1363–1393

    Article  Google Scholar 

  • Kendall C, Mc Donnell JJ (eds) (1998) Isotope tracers in catchment hydrology. Elsevier Science Publisher, Amsterdam

    Google Scholar 

  • La-Moreaux PE, Hughes TH, Memon BA, Lineback N (1989) Hydrogeologic assessment—Figeh Spring, Damascus, Syria. Environ Geol Water Sci 13(2):73–127

    Article  Google Scholar 

  • Livingstone DA (1963) Data of geochemistry, 6th edn. US Geological Survey professional paper 440-G, pp G1–G64

  • Merlivat L, Jouzel J (1979) Global climatic interpretation of deuterium–oxygen 18 relationship for precipitation. J Geophys Res 84:5029–5033

    Google Scholar 

  • Meybeck M (1979) Concentration des eaux fluviales en éléments majeurs et apports en solution aux océans. Rev Géol Dyn Géogr Phys 21(fasc 3):215–246

    Google Scholar 

  • Meybeck M (1983) Atmospheric inputs and river transport of dissolved substances. In: Proceedings of an IAHS symposium on dissolved loads of river and surface water quantity and quality relationships. IAHS Publication 141, Germany, Hamburg

  • Meybeck M (1986) Composition chimique des ruisseaux non pollues en France. Sci Géol Bull 39(1):3–77

    Google Scholar 

  • Nir A (1967) Development of isotope methods applied to groundwater hydrology. In: Proceedings of a symposium on isotope techniques in the hydrological cycle, Am Geophys Union Monogr Series, no 11, pp 1–109

  • Payne BR (1983) Introduction. In: Guidebook on nuclear techniques in hydrology. Technical reports series no. 91, IAEA, Vienna

  • Payne BR, Yurtsever Y (1974) Environmental isotopes as a hydrogeological tool in Nicaragua. In: Proceedings of a symposium on isotope techniques in groundwater hydrology, vol. 1, IAEA, Vienna

  • Plummer LN, Jones BF, Truesdell AH (1976) WATEQF—a FORTRAN IV version of WATEQ. US Geological Survey Water Resources Investigation, no. 13

  • Plummer LN, Prestemon EC, Parkhurst DL (1991) An interactive code (NETPATH) for modeling net geochemical reactions along a flow path. US Geol Survey Water Resources Investigations Report no. 91-4078

  • Ponikarov VO (1967) The geology of Syria, explanatory notes on the map of Syria, Scale 1:500,000. Part II. Mineral deposits and underground water resources, Technoexport, Moscow

  • Prizgonov V, Nitashov V, Steriocovitch PV (1988) Determination of recharge zone of Damascus basin by the use of oxygen-18 in groundwater. Nawca (edn in Russian), USSR Academy of Science, Moscow, pp. 169–174

  • Rasoul-Agha W (1999) Deep non-renewable groundwater in Syria and future strategic options for the management of water resources. In: International conference on regional aquifer systems in arid zones-managing non-renewable resources, Libya, Tripoli (in Arabic)

  • Rosanski K (1985) Deuterium and oxygen-18 in European groundwaters; links to atmospheric circulation in the past. Chem Geol 52:349–363

    Google Scholar 

  • Rosanski K, Araguas-Araguas L, Gonfiantini R (1992) Relation between long-term trends of oxygen-18 isotope composition of precipitation and climate. Science 258:981–985

    Article  Google Scholar 

  • Rosanski K, Araguas-Araguas L, Gonfiantini R (1993) Isotopic patterns in modern global precipitation. In: Swart PK, Lohmann KC, McKenzie J, Savin S (eds) Climate change in continental isotopic records. Am Geophys Union Monogr Series, no. 78, Am Geophys Union, Washington, pp. 1–36

  • Rosenthal E (1987) Chemical composition of rainfall and groundwater in recharge areas of Bet Shean-Harod multiple aquifer system, Israel. J Hydrol 89:329–352

    Article  Google Scholar 

  • Saad Z, Slim K, Ghaddar A, Nasreddine M, Kattan Z (2000) Chemical composition of rain water in Lebanon. J Européen d’Hydrologie, tome 31(fasc 2):223–238

    Google Scholar 

  • Safadi MC (1974) Hydraulic resources in the Syrian Arab Republic. Fourteenth scientific week, Damascus University, Damascus

  • Schoeller H (1956) Géochimie des eaux souterraines, Application aux eaux des gisements de pétrole, Soci. des Editions, Technip, Paris

  • Schoeller H (1977) Geochemistry of groundwaters (Chapter 15). In: Groundwater studies—an international guide for research and practice. UNESCO, Paris, pp 1–18

  • Selkhozpromexport (1986) Water resources use in Barada and Auvage basins for irrigation of crops, Syrian Arab Republic, feasibility study, stage I, vol. II. Natural conditions, Book 2, Hydrogeology. USSR, Ministry of Land Reclamation and Water Management, Moscow

  • Stumm W, Morgan JJ (1981) Aquatic chemistry; an introduction emphasizing chemical equilibria in natural waters. Wiley, New York

    Google Scholar 

  • United Nations (1982) Groundwater in Eastern Mediterranean and Western Asia; natural resources. Water series no. 9, United Nations, New York

  • Verhagen BT, Geyh MA, Frohlich K, Wirth K (1991) Isotope hydrological methods for the quantitative evaluation of ground water resources in arid and semi-arid areas, development of methodology. Research report of the Federal Ministry for Economic Cooperation, Federal Republic of Germany, Hanover

  • Wagner W, Geyh MA (1999) Application of environmental isotope methods for groundwater studies in the ESCWA region (Economic and Social Commission for Western Asia). Geologisches Jahrbuch, Reihe C, Heft 67, Hanover

  • White DE, Hem JD, Waring GA (1963) Chemical composition of subsurface waters. In: Data of geochemistry, 6th edn. US Geological Survey, professional paper 440-F, pp. F1–F67

  • Yurtsever Y (1983) Models for tracer data analysis. In: Guidebook on nuclear techniques in hydrology. Technical reports series no. 91, IAEA, Vienna

  • Yurtsever Y, Gat JR (1981) Atmospheric waters. In: Stable isotope hydrology, deuterium and oxygen-18 in the water cycle. Technical reports series no. 210. IAEA, Vienna

  • Zuber A (1994) On calibration and validation of mathematical models for the interpretation of environmental tracer data in aquifers. In: Proceedings of a final research co-ordination meeting, IAEA-TECDOC-777, IAEA, Vienna

Download references

Acknowledgments

The author would particularly acknowledge Prof. I. Othman, Director General of AECS, for his support and encouragement. He is also grateful to Drs W. Rasoul-Agha, C. Safadi and S. Rammah for the supervising and useful discussions. The IAEA Organization, Isotope Hydrology Lab of the Jordanian Water Authority in Amman, and the AECS Labs are deeply acknowledged for the isotopic and chemical analyses of water samples. Finally, the author is indebted to Dr R. Nasser, Head of the Geology Department at the AECS, and his technical staff who contributed to this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zuhair Kattan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kattan, Z. Characterization of surface water and groundwater in the Damascus Ghotta basin: hydrochemical and environmental isotopes approaches. Environ Geol 51, 173–201 (2006). https://doi.org/10.1007/s00254-006-0316-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00254-006-0316-z

Keywords

Navigation