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Effects of land use on the spatial distribution of trace metals and volatile organic compounds in urban groundwater, Seoul, Korea

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Environmental Geology

Abstract

To investigate the urban groundwater contamination by eight trace metals and 69 volatile organic compounds (VOCs) in relation to land use in Seoul, a total of 57 groundwater samples collected from wells were examined using a non-parametric statistical analysis. Land use was classified into five categories: less-developed, residential, agricultural, traffic, and industrial. A comparison of analyzed data with US EPA and Korean standards for drinking water showed that some metals and VOCs exceeded the standards in a few localities, such as Fe (N=5), Mn (N=6), Cu (N=1), TCE (N=6), PCE (N=8), 1,2-DCA (N=1), and 1,2-dichloropropane (N=1). Among the 69 investigated VOCs, 19 compounds such as some gasoline-related compounds (e.g., toluene) and chlorinated compounds (e.g., chloroform, PCE, TCE) were detected in groundwater. Non-parametric statistical analysis showed that the concentrations of most trace metals (Fe, Mn, As, Cr, Pb, Cd) and some VOCs (especially, TCE, PCE, chloroform; toluene, carbon tetrachloride, bromodichloromethane, CFC113) are significantly higher in the industrial, residential, and traffic areas (P<0.05), indicating that anthropogenic contamination of urban groundwater by those chemicals is growing. Those chemicals can be used as effective indicators of anthropogenic contamination of groundwater in urban areas and therefore a special attention is warranted for a safe water supply in those areas. The results of this study suggest that urban groundwater quality in urban areas is closely related with land use.

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References

  • Anderson HW (1993) Effects of agricultural and residential land use on groundwater quality, Anoka Sand Plain aquifer, east central Minnesota. USGS Water Resour Invest Rep, pp 93–4074

  • APHA, AWWA, WEF (American Public Health Association, American Water Works Association, Water Environment Federation) (1992) Standard methods for the examination of water and wastewater, 18th edn. APHA Pub, Washington

    Google Scholar 

  • Barber C, Otto CJ, Bates LE (1996) Evaluation of the relationship between land-use changes and groundwater quality in a water-supply catchment, using GIS technology: the Gwelup wellfield, Western Australia. Hydrogeol J 4:6–19

    Article  Google Scholar 

  • Barrett MH, Hiscock KM, Pedley S, Lerner DN, Tellam JH, French MJ (1999) Marker species for identifying urban groundwater recharge sources: a review and case study in Nottingham, UK. Water Res 33:3083–3097

    Article  Google Scholar 

  • Barringer TD, Dunn D, Battaglin W, Vowinkel E (1990) Problems and methods involved in relating land use to groundwater quality. Water Resour Bull 26:1–9

    Google Scholar 

  • Cain D, Helsel DR, Ragone SE (1989) Preliminary evaluations of regional groundwater quality in relation to land use. Ground Water 27:230–244

    Article  Google Scholar 

  • Chae GT, Yun ST, Kim KH, Lee PK, Choi BY (2004) Atmospheric versus lithogenic contribution to the composition of first- and second-order stream waters in Seoul and its vicinity. Environ Int 30:73–85

    Article  PubMed  Google Scholar 

  • Choi BY, Yun ST, Yu SY, Lee PK, Park SS, Chae GT, Mayer B (2005) Hydrochemistry of urban groundwater in Seoul, South Korea: effects of land-use and pollutant recharge. Environ Geol (in press)

  • Eckhardt DAV, Stackelderg PE (1995) Relation of groundwater quality to land use on Long Island, New York. Ground Water 33:1019–1033

    Article  Google Scholar 

  • Eiswirth M, Hotzl H (1997) The impact of leaking sewers on urban groundwater. In: Chilton J (eds) Proceedings of the XXVII IAH congress on groundwater in the urban environment. vol 1, problems, processes and management, 21–27 September 1997. AA Balkema, Rotterdam/Brookfiled, pp 399–404

  • Helsel DR, Hirsch RM (1992) Statistical methods in water resources. Elsevier, New York

    Google Scholar 

  • Hudak PF, Blanchard S (1997) Land use and groundwater quality in the Trinity Group outcrop of north-central Texas, USA. Environ Int 23:507–517

    Article  Google Scholar 

  • Kim YY (2004) Analysis of hydrochemical processes controlling the urban groundwater system in Seoul area, Korea. Geosci J 8:313–318

    Google Scholar 

  • KMA (Korean Metrological Administration) (2002) Annual climate report [in Korean]

  • Lee KJ, Pyo HS, Park SJ, Yoo EA, Lee DW (2001) A study of purge efficiency in purge and trap analysis of VOCs in water. Bull Korean Chem Soc 22:171–178

    Google Scholar 

  • Lee PK, Park SW, Jeon CW, Shin SC (2001) Volatile organic compounds contamination in some urban runoff and groundwater samples in Seoul city [in Korean]. J Korean Soc Soil Groundwater Environ 6:73–91

    Google Scholar 

  • Lee SM, Min KD, Woo NC, Kim YJ, Ahn CH (2003) Statistical models for the assessment of nitrate contamination in urban groundwater using GIS. Environ Geol 44:210–222

    Google Scholar 

  • Lerner DN (2002) Identifying and quantifying urban recharge: a review. Hydrogeol J 10:143–152

    Article  Google Scholar 

  • Lopes TJ, Bender DA (1998) Nonpoint sources of volatile organic compounds in urban areas—relative importance of land surfaces and air. Environ Poll 101:221–230

    Article  Google Scholar 

  • MOE (Ministry of Environment of Korea) (2002) Guidelines of Korean Drinking Water Quality Management in 2002 [in Korean]. MOE, Korea (http://www.me.go.kr)

  • Niemczynowicz J (1999) Urban hydrology and water management—present and future challenges. Urban Water 1:1–14

    Article  Google Scholar 

  • Sharp JR Jr (1997) Groundwater supply issues in urban and urbanizing areas. In: Chilton J (Ed) Proceedings of the XXVII IAH congress on groundwater in the urban environment. v. 1, problems, processes and management, 21–27 September 1997. AA Balkema, Rotterdam/Brookfiled, pp 67–74

  • SDI and SMC (Seoul Development Institute and Seoul Metropolitan City) (2001) Study on the use of GIS techniques for the selection of groundwater protection area and the development of groundwater assessment scheme in Seoul [in Korean]

  • SMC (Seoul Metropolitan City) (2001a) Report of statistics for Seoul Metropolitan City [in Korean]. Seoul, Korea

  • SMC (Seoul Metropolitan City) (2001b) Biotope mapping and guideline for establishment of ecopolis in Seoul [in Korean]. Seoul Development Institute, Seoul, Korea

  • Squillace PJ, Price CV (1996) Urban land-use study plan for the national water-quality assessment program. US Geol Surv Open-File Rep, pp 96–217

  • Subbarao C, Subbarao NV, Chandu SN (1996) Characterization of groundwater contamination using factor analysis. Environ Geol 28:175–180

    Article  Google Scholar 

  • Trauth R, Xanthopoulos C (1997) Non-point pollution of groundwater in urban areas. Water Res 31:2711–2718

    Article  Google Scholar 

  • Trojan MD, Maloney JS, Stockinger JM, Eid EP, Lahtinen MJ (2003) Effects of land use on groundwater quality in the Anoka sand plain quifer of Minnesota. Ground Water 41:482–492

    Article  PubMed  Google Scholar 

  • U.S. EPA (Environmental Protection Agency) (2001) National Primary Drinking Water Standards. EPA/816/F/01/007, Office of Water, U.S. EPA, Washington DC (http://www.epa.gov/safewater)

  • Yun ST, Choi BY, Lee PK (2000) Distribution of heavy metals (Cr, Cu, Zn, Pb, Cd, As) in roadside sediments, Seoul Metropolitan City, Korea. Environ Technol 21:989–1000

    Article  Google Scholar 

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Acknowledgements

This research was supported by the Environmental Geosphere Research Lab (EGRL) of Korea University. The authors should acknowledge many graduate students of Korea University who contributed to the field work for this study. Thoughtful comments by anonymous referees and Dr. P.E. LaMoreaux (journal editor) were helpful to improve the manuscript.

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Correspondence to Soon-Oh Kim or Seong-Taek Yun.

Appendix

Appendix

  Summary of the 68 compounds of VOCs analyzed in this study

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Park, SS., Kim, SO., Yun, ST. et al. Effects of land use on the spatial distribution of trace metals and volatile organic compounds in urban groundwater, Seoul, Korea. Environ Geol 48, 1116–1131 (2005). https://doi.org/10.1007/s00254-005-0053-8

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  • DOI: https://doi.org/10.1007/s00254-005-0053-8

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