Abstract
Presence of young groundwater (post-1950) in the Goose River basin is demonstrated with 3H and 85Kr analyses. A total of 96 wells and four springs were sampled quarterly from 1999 to 2001 to determine the extent of any recent recharge and to what depth hydraulic continuity existed in the groundwatershed (33.3 km2). Recharge groundwater is less than 50 years in about 31% (3H) to 37% (85Kr) of sampled wells and 75% of sampled springs. Young groundwater ages are recorded in wells up to 320 m in depth within fractured- and arsenic-bearing crystalline bedrock. Total arsenic ≥10 μg L−1 occurs significantly in drinking water with young groundwater flowing through the pumping well intervals. Astotal occurs in 89% (85Kr) to 93% (3H) of all wells with post-1950 groundwater ages. Young groundwater recharge and elevated geogenic arsenic were discovered only in the anatectic granitoids and migmatized country rock of the southwestern part of the Goose River basin.
Similar content being viewed by others
References
Barton M, Sidle WC (1994) Petrologic and geochemical evidence for granitoid formation: the Waldoboro pluton complex, Maine. J Petrol 35:1241–1274
Caswell WB (1987) Ground water handbook for the State of Maine. Maine Geologic Survey, Augusta
Chapra SC, Canale RP (1988) Numerical methods for engineers. McGraw Hill, New York
Florkowski T (1992) Low-level tritium assay in water samples by electrolytic enrichment and liquid-scintillation counting in the IAEA laboratory. International Atomic Energy Agency, Vienna, SM-252/63, pp 335–351
Friedlander G, Kennedy JW, Macias ES, Miller JM (1981) Nuclear and radiochemistry. Wiley, New York
Held J, Schuhbeck S, Rauert W (1992) A simplified method of 85Kr measurement for dating young groundwater. Appl Rad Iso 43:939–942
IAEA (International Atomic Energy Agency) (1999) International Atomic Energy Agency Tritium Database. http://www.iaea.org/programs/gnipinfo.htm
Lange T, Hebert D (2001) A new site for 85Kr measurements on groundwater samples. Rad Phys Chem 61:679–680
Morgenstern U, Hebert D, Stolz W (1992) Electrolytic tritium enrichment of natural water samples for tritium analysis. In: Noakes JE, Schönhofer F, Polach HA (eds) Liquid scintillation spectrometry. pp 335–360
Rozanski K (1979) Krypton-85 in the atmosphere 1950–1977: a data review. Environ Int 2:139–143
Rozanski K, Florkowski T (1979) Krypton-85 dating of groundwater. In: Isotope hydrology. International Atomic Energy Agency, Vienna, vol II, pp 949–961
Seiler KP, Lindner W (1995) Near-surface and deep groundwater. J Hydrol 165:33–44
Shanklin DE, Sidle WC, Ferguson ME (1995) Micro-purge low-flow sampling of uranium-contaminated ground water at the Fernald Environmental Management project. Ground Water Mon Rev Summer:168–176
Sidle WC (1989) Bedrock geology of the Waldoboro East 7.5 minute quadrangle. Maine Geologic Survey Map, 2 plates
Sidle WC (2002) 18OSO4 and 18OH2O as prospective indicators of elevated arsenic in the Goose River ground-watershed, Maine. Environ Geol 42:350–359
Sidle WC (2003) Estimating discharge zones of arsenic in the Goose River basin, Maine: application of water balance modeling and oxygen isotope analyses. J Am Water Resour Assoc (in press)
Sidle WC, Barton M (1992) Field relationships, petrology, structure, and intrusion history of the Waldoboro pluton granitoid complex, Maine, U.S.A. Maine Geologic Survey OF-Report 92-64
Sidle WC, Lee PY (1995) Estimating local ground-water flow conditions in a granitoid: preliminary assessments in the Waldoboro pluton complex, Maine. Ground Water 33:291–303
Sidle WC, Wotten B, Murphy E (2001) Provenance of geogenic arsenic in the Goose River basin, Maine, USA. Environ Geol 41:62–73
Smethie WM, Mathieu G (1986) Measurement of krypton-85 in the ocean. Marine Chem 18:17–33
Smethie WM, Solomon DK, Schiff SL, Mathieu GG (1992) Tracing groundwater flow in the Borden aquifer using krypton-85. J Hydrol 130:279–297
Solomon DK, Cook PG (2000) 3H and 3He. In: Cook PG, Herczeg AL (eds) Environmental tracers in subsurface hydrology. Kluwer, Boston, pp 397–424
USEPA (2000) United States Environmental Protection Agency Standard Methods. http://www.epa.gov/Standards.html
Weiss RF, Kyser TK (1978) Solubility of krypton in water and seawater. J Chem Eng Data 23:69–72
Zimmerman PH, Feichter J, Rath HK, Crutzen PJ, Weiss W (1992) A global three-dimensional source–receptor model investigation using 85Kr. Atm Environ 23:25–35
Acknowledgements
This research is funded in part by internal USEPA agency program development of watershed studies. The cooperation of the Maine Geological Survey and Maine Public Health is greatly appreciated. In particular, the author thanks M. Corbin at the Maine Health Engineering Laboratory for access to the drinking water well analytical database for the study area, and R. Voyer at USDA NRCS (Bangor) for soil database assistance. Also, we wish to thank L. Smith of Waldoboro, Maine, for access to homeowner wells. Thanks to P. Barndt at Oak Ridge National Laboratory; K. Kelty and J. Doerger at USEPA WS&WRD, (Cincinnati); staff at the USEPA Isotope Hydrology Laboratory (Cincinnati); and R. Smith and M. Barton, respectively, at the Departments of Chemistry and Geological Sciences at Ohio State University (Columbus).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sidle, W.C., Fischer, R.A. Detection of 3H and 85Kr in groundwater from arsenic-bearing crystalline bedrock of the Goose River basin, Maine. Env Geol 44, 781–789 (2003). https://doi.org/10.1007/s00254-003-0826-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00254-003-0826-x