Abstract
The biomass carbon ratios of biochemicals related to biomass have been reviewed. Commercial products from biomass were explained. The biomass carbon ratios of biochemical compounds were measured by accelerator mass spectrometry (AMS) based on the 14C concentration of carbons in the compounds. This measuring method uses the mechanism that biomass carbons include a very low level of 14C and petroleum carbons do not include 14C similar to the carbon dating measuring method. It was confirmed that there were some biochemicals synthesized from petroleum-based carbons. This AMS method has a high accuracy with a small standard deviation and can be applied to plastic products.


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Akiyama M, Tsuge T, Doi Y (2003) Environmental life cycle comparison of polyhydroxyalkanoates produced from renewable carbon resources by bacterial fermentation. Polym Degrad Stab 80:183–194
Currie LA, Klinedinst DB, Burch R, Feltham N, Dorsch R (2000) Authentication and dating of biomass components of industrial materials; links to sustainable technology. Nucl Instrum Meth Phys Res B 172:281–287
Erwin TH, Vink ETH, Rábago KR, Glassner DA, Gruber PR (2003) Applications of life cycle assessment to NatureWorks™ polylactide (PLA) production. Polym Degrad Stab 80:403–419
Funabashi M, Ninomiya F, Kunioka M, Ohara K (2009) Biomass carbon ratio of biomass chemicals measured by accelerator mass spectrometry. Bull Chem Soc Jpn 82:1538–1547
Hämäläinen KM, Jungner H, Antson O, Räsänen J, Tormonen K, Roine J (2007) Measurement of biocarbon in flue gases using 14C. Radiocarbon 45:325–330
Kim S, Dale BE (2008) Energy and greenhouse gas profiles of polyhydroxybutyrates derived from corn grain: a life cycle perspective. Environ Sci Technol 42:7690–7695
Kunioka M, Ninomiya F, Funabashi M (2007) Biobased contents of organic fillers and polycaprolactone composites with cellulose fillers measured by accelerator mass spectrometry based on ASTM D6866. J Polym Environ 15:281–287
Linsyarini A, Kunioka M, Funabashi M (2008) Biodegradable poly(butylenes succinate) blended with biorenewable derivatives from polysaccharides. Trans Mater Res Soc Jpn 33:1159–1164
Lunt J (1998) Large-scale production, properties and commercial applications of polylactic acid polymers. Polym Degrad Stab 59:145–152
Morschbacker A (2009) Bio-ethanol based ethylene. J Macromol Sci, Part C: Polym Review 49:79–84
Narayan R (2005) Biobased and biodegradable polymer materials. ACS Polymer Preprints, USA, pp 319–320
Onishi T, Ninomiya F, Kunioka M, Funabashi M, Ohara K (2010) Biomass carbon ratio of polymer composites included biomass or petroleum origin resources. Polym Degrad Stab (in press)
Saito M (2009) Radiocarbon measurement of purified bio diesel fuel by a liquid scintillation counter. Radioisotopes 58:455–460
Song H, Lee SY (2006) Production of succinic acid by bacterial fermentation. Enzyme Microbiol Biotechnol 39:352–361
Tachibana Y, Giang NTT, Ninomiya F, Funabashi M, Kunioka M (2010). Cellulose acetate butyrate as multifunctional additive for poly(butylene succinate) by melt blending: Mechanical properties, biomass carbon ratio, and control of biodegradability. Polym Degrad Stab (in press)
Yunoki S, Saito M (2009) A simple method to determine bioethanol content in gasoline using two-step extraction and liquid scintillation counting. Bioresour Technol 100:6125–6128
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Kunioka, M. Possible incorporation of petroleum-based carbons in biochemicals produced by bioprocess. Appl Microbiol Biotechnol 87, 491–497 (2010). https://doi.org/10.1007/s00253-010-2630-3
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DOI: https://doi.org/10.1007/s00253-010-2630-3