Abstract
Total suspended particles and 12 airborne metals were determined in 4 sampling sites in the industrial region of Médio Paraíba, Brazil. The geometrical means for the four sampling locals were (in units of μg/m3): 65.9 in Barra Mansa, 57.3 in Jardim Paraíba (Volta Redonda), 41.7 in Resende, and 48.9 in Volta Grande (Volta Redonda). These values are lower than levels previously determined in urban and industrial locals of the Metropolitan Area of Rio de Janeiro. For metals, the higher concentrations were obtained for Ca, Zn, Al, Fe, and Mg. Ca, Zn, and Al levels are higher than those determined in other industrial areas. These three metals are used in steel manufacturing, the main economical activity of the region. Enrichment factors for Zn, Cu, Cd, and Pb are higher than 10, suggesting an industrial input. Statistical analysis show a high correlation among Ca, Mg, Zn, Cr, Al, Mn, and Fe, all of them used as raw materials in steel manufacturing and/or accumulated as industrial blast furnace slag and steelworks slag.



Similar content being viewed by others
Explore related subjects
Discover the latest articles and news from researchers in related subjects, suggested using machine learning.References
Baldasano JM, Valera E, Jimenez P (2003). Air quality data from large cities. Sci Total Environ 307:141–165
Barra Mansa (2005) Prefeitura de Barra Mansa. Available from http://wwwportalbm.com/portal/noticias (accessed August 2005)
Beceiro-González E, Andrade-Garda JM, Serrano-Velasco E, Lópes-Mahía P (1997) Metals in airborne particulate matter in La Coruña (NW Spain). Sci Total Environ 196:131–139
Bilos C, Colombo JC, Skorupka CN, Rodrigues Presa MJ (2001) Sources, distribution and variability if airborne trace metals in La Plata City area, Argentina. Environ Pollut 111:149–158
Boss CB, Fredeen KJ (1999) Concepts, instrumentation, and techniques in inductively coupled plasma optical emission spectrometry. Perkin Elmer, Norwalk, CT
Caroli S, La Torre F, Petrucci F, Violante N (1996) Element speciation in bioinorganic chemistry. Wiley-Interscience, New York
Cheng MT, Lin YC, Chio CP, Wang CF, Kuo CY (2005) Characteristics of aerosols collected in central Taiwan during an Asian dust event in spring 2000. Chemosphere 61:1439
CONAMA (1990) Padrões Nacionais de Qualidade do Ar. Available from http://www.mma.gov.br/port/conama/res/res90/res0390.html (accessed September 2005)
CSN (Companhia Siderúrgica Nacional) (2005) Portal CSN: Relatório Anual online. Available from http://csna0004.csn.com.br/ CSNAPP/ RQQ/2004 (accessed August 2005)
EPA (Environmental Protection Agency) (1998).Guidance for sitting ambient air monitors around stationary lead sources USA. Available from http://www.ttnamti1/files/ambient/criteria/reldocs/pbgde997.pdf(accessed August 2005)
FEEMA (Fundação Estadual de Engenharia do Meio Ambiente) (2004) Inventário de fontes emissoras de poluentes atmosféricos da Região Metropolitana do Rio de Janeiro. Available from http://www.feema.gov.br (accessed August 2005)
FEEMA (Fundação Estadual de Engenharia do Meio Ambiente) (2005a) Relatório anual da qualidade do ar. Available from http://www.feema.gov.br (accessed August 2005)
FEEMA (Fundação Estadual de Engenharia do Meio Ambiente) (2005b) Internal report. Available from http://www.feema.gov.br (accessed August 2005)
Fernández AJ, Ternero M, Barragán FJ, Jiménez JC (2000) An approach to characterization of sources of urban airbone particles through heavy metal speciation. Chemph Global Change Sci 2:123–136
Harrinson RM, Smith DJT, Luhana L (1996) Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, U.K. Environ Sci Technol 30:825–832
IBGE (Instituto Brasileiro de Geografia e Estatística) (2002) População. Available from http://www.ibge.gov.br (accessed August 2005)
Lantzy RJ, Mackenzie FT (1979) Atmospheric trace metals: Global cycles and assessment of man’s impact. Geochim Cosmochim Acta 43:511–525
Merck (2006) Chemicals: Materials safety data sheets. Available from http://chemdat.merck.de/pls/pi03/web2.zoom_in?text=111355&screen=110&cid=xcsfs&pg=0&s= &lang=1 (accessed March 2006)
Method IO-3.4 (1999) Determination of metals in ambient particulate matter using inductively coupled plasma (ICP) spectroscopy. USEPA, Washington, DC (CD Rom)
Quiterio S, Arbilla G, Silva CRS, Escaleira V (2004a) Metals in airborne particulate matter in the Industrial District of Santa Cruz, Rio de Janeiro, in an annual period. Atmos Environ 38:32–331
Quiterio SL, Arbilla G, Escaleira V, Silva CRS, Maia LFPG (2004b) Metals in airborne particulate matter in downtown Rio de Janeiro (Brazil). Bull Environ Contam Toxicol 72:916–922
Quiterio SL, Arbilla G, Escaleira V, Silva CRS (2005) Evaluation of levels, sources and distribution of airborne trace metals in seven districts of the baixada fluminense, Rio de Janeiro, Brazil. Atmos Environ 39:3504–3512
Ragosta M, Caggiano R, Démilio M, Macchiato M (2002) Source origin and parameters influencing levels of heavy metals in TSP, in an industrial background area of southern Italy. Atmos Environ 36:3071–3087
Resende (2005) Prefeitura de Resende. Available from http://www.resende.rj.gov.br/site-prefeitura/meio_ambiente_monitor.php (accessed August 2005)
Rizzio E, Cucca L, Profumo A, Rolla A, Gallorini M (1998) Studio delle concentrazioni degli elementi in tracce e della loro distribuzione granulometrica nel particolato atmosferico di zone urbane e industrializzate mediante AAN. Acqua Aria (Gugno/Luglio) 6–7:75–80
Serrano E, Beceiro E, López P, Prada D (1996) Heavy metals determination in atmospheric particulate matter of La Coruña. Química Anal 15:38–44
Sweet CW, Vermette SJ, Landsberg S (1993) Sources of toxic trace elements in urban air in Illinois. Environ Sci Technol 27:2502–2510
TPAl (1999) Toxicological profile for aluminum. US Department of Disease Registry, Atlanta, GA
TPCd (1999) Toxicological profile for cadmium. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPCo (1992) Toxicological profile for cobalt. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPCr (2000) Toxicological profile for chromium. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPCu (1990)Toxicological profile for copper. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPMn (2000) Toxicological profile for manganese. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPNi (1997) Toxicological profile for nickel. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPPb (1999) Toxicological profile for lead. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
TPZn (1994) Toxicological profile for zinc. US Department of Health and Human Services, Public Health Services, Agency for Toxic Substances and Disease Registry, Atlanta, GA
Ure AM, Davidson CM (1995) Chemical speciation in the environment. Blackie Academic & Professional, London, p 408
Volta Redonda (2005) Portal Volta Redonda. Available from http://wwwportalvr.com/portal/noticias (accessed August 2005)
WHO (World Health Organization) (2000) Guidelines for air quality—Geneva. Available from http://www.who.int/environmental_ information/Air/Guidelines/aqguide7.pdf (accessed September 2005)
Acknowledgments
The authors acknowledge financial support from FAPERJ and CNPq. They also acknowledge the collaboration of FEEMA (Fundação Estadual de Engenharia do Meio Ambiente), in particular of Antônio Carlos Dias dos Santos and João Eustaquio Xavier, who participated in sampling compaigns. They also acknowledge the collaboration of ANA (Agência Nacional de Águas), INMET, and COORDEMA (Coordenadoria de Meio Ambiente da Prefeitura de Volta Redonda), in particular Leslie Calzavara Carreiro.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Loyola, J., de Almeida, P.B., Quiterio, S.L. et al. Concentration and Emission Sources of Airborne Metals in Particulate Matter in the Industrial District of Médio Paraíba, State of Rio de Janeiro, Brazil. Arch Environ Contam Toxicol 51, 485–493 (2006). https://doi.org/10.1007/s00244-005-0313-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00244-005-0313-3


