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Separation of CO2/N2 mixture by vacuum pressure swing adsorption (VPSA) using zeolite 13X type and carbon molecular sieve adsorbents

Heat and Mass Transfer volume 56, pages 1985–1994 (2020)Cite this article

Abstract

Separation of carbon dioxide in flue gases from the combustion equipment is one of the most serious concerns for industries and especially for the power plants which are the main producers of this pollutant gas. From the various separation methods, vacuum pressure swing adsorption (VPSA) process is attracted interest due to its lower energy consumption and high efficiency. A VPSA process was studied for the separation of a mixture of CO2/N2 (80% N2 and 20% CO2). Experiments were performed in an eight-step, four-bed setup using zeolite 13X and carbon molecular sieve (CMS) as adsorbents. Experimental measurements by the bench-scale system have been obtained in a pressure range of 2.7–4.7 bar, cycle times of 360–600 s, the product flow rate of 1–3 (lit/min), and temperature 30 °C. The effects of pressure, cycle time, and product flow rate were investigated. With using 560 s for a cycle time at 3.7 bar, the maximum purity of 97.6% was obtained for zeolite 13X adsorbent.

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References

  1. Divekar S, Dasgupta S, Aarti P, Gupta S, Singh AN (2019) Improved CO2 recovery from flue gas by layered bed vacuum swing adsorption. Sep Purif Technol. https://doi.org/10.1016/j.seppur.2019.05.036

    Article  Google Scholar 

  2. Susarla N, Haghpanah R, Karimi IA, Farooq S, Rajendran A, Tan LSC, Lim JST (2015) Energy and cost estimates for capturing CO2 from a dry flue gas using pressure/vacuum swing adsorption. Chem Eng Res Des 102:354–367. https://doi.org/10.1016/j.cherd.2015.06.033

    Article  Google Scholar 

  3. Canevesi RLS, Andreassen KA, Silva EA, Borba CE, Grande CA (2019) Evaluation of simplified pressure swing adsorption cycles for biomethane production. Adsorption. 1-11. https://doi.org/10.1007/s10450-019-00049-x

    Article  Google Scholar 

  4. Sayari A, Belmabkhout Y, Serna-Guerrero R (2011) Flue gas treatment via CO2 adsorption. Chem Eng J 171:760–774. https://doi.org/10.1016/j.cej.2011.02.007

    Article  Google Scholar 

  5. Zhao R, Deng S, Wang S, Zhao L, Zhang Y, Liu B, Li H, Yu Z (2018) Thermodynamic research of adsorbent materials on energy efficiency of vacuum-pressure swing adsorption cycle for CO2 capture. Appl Therm Eng 128:818–829. https://doi.org/10.1016/j.applthermaleng.2017.09.074

    Article  Google Scholar 

  6. Ling J, Xiao P, Ntiamoah A, Xu D, Webley P, Zhai Y (2016) Strategies for CO2 capture from different CO2emission sources by vacuum swing adsorption technology. Chinese J Ch E 24:460–467. https://doi.org/10.1016/j.cjche.2015.11.030

    Article  Google Scholar 

  7. Kacem M, Pellerano M, Delebarre A (2015) Pressure swing adsorption for CO2/N2 and CO2/CH4 separation: comparison between activated carbons and zeolites performances. Fuel Process Technol 138:271–283. https://doi.org/10.1016/j.fuproc.2015.04.032

    Article  Google Scholar 

  8. Dasgupta S, Biswas N, Aarti N, Gode G, Divekar S, Nanoti A, Goswami AN (2012) CO2 recovery from mixtures with nitrogen in a vacuum swing adsorber using metal organic framework adsorbent: a comparative study. Int J Greenhouse Gas Control 7:225–229. https://doi.org/10.1016/j.ijggc.2011.10.007

    Article  Google Scholar 

  9. Luberti M, Oreggioni GD, Ahn H (2017) Design of a Rapid Vacuum Pressure Swing Adsorption (RVPSA) process for post-combustion CO2 capture from a biomass-fuelled CHP plant. J Environ Chem Eng 5:3973–3982. https://doi.org/10.1016/j.jece.2017.07.029

    Article  Google Scholar 

  10. Y. Shen, W. Shi, D. Zhang, P. Na, B. Fu, (2018) The removal and capture of CO2 from biogas by vacuum pressure swing process using silica gel. J CO2 Util 27:259–271. 10.1016/j.jcou.2018.08.001

  11. Qasem NAA, Ben-Mansour R (2018) Energy and productivity efficient vacuum pressure swing adsorption process to separate CO2 from CO2/N2 mixture using mg-MOF-74: a CFD simulation. Appl Energy 209:190–202. https://doi.org/10.1016/j.apenergy.2017.10.098

    Article  Google Scholar 

  12. Ma J, Si C, Li Y, Li R (2012) CO2 adsorption on zeolite X/activated carbon composites. Adsorption 18:503–510. https://doi.org/10.1007/s10450-012-9440-0

    Article  Google Scholar 

  13. Mhaskar PR, Moharir AS (2012) Heuristics for synthesis and Design of Pressure Swing Adsorption Processes. Adsorption. 18:275–295. https://doi.org/10.1007/s10450-012-9400-8

    Article  Google Scholar 

  14. Mendes PAP, Ribeiro AM, Gleichmann K, Ferreira AFP, Rodrigues AE (2017) Separation of CO2/N2 on binderless 5A zeolite. J CO2 UTIL 20:224–233. https://doi.org/10.1016/j.jcou.2017.05.003

    Article  Google Scholar 

  15. Wang L, Liu Z, Li P, Wang J, Yu J (2012) CO2 capture from flue gas by two successive VPSA units using 13XAPG. Adsorption. 18:445–459. https://doi.org/10.1007/s10450-012-9431-1

    Article  Google Scholar 

  16. Makarem MA, Mofarahi M, Jafarian B, Lee CH (2019) Simulation and analysis of vacuum pressure swing adsorption using the differential quadrature method. Comput Chem Eng 121:483–496. https://doi.org/10.1016/j.compchemeng.2018.11.017

    Article  Google Scholar 

  17. S. Mohajerani (2010) Modeling of separation of CO2/N2 by PSA, M.Sc. thesis, Tarbiat Modares University

  18. Eghbaljahromi P, Fatemi S, Vatani A (2018) Effective design of a PVSA process to recover dilute helium from a natural gas source in a methane-rich mixture with nitrogen. Ind Eng Chem Res 57:12895–12908. https://doi.org/10.1021/acs.iecr.8b00798

    Article  Google Scholar 

  19. Maring BJ, Webley PA (2013) A new simplified pressure/vacuum swing adsorption model for rapid adsorbent screening for CO2 capture applications. Int. J. Greenhouse Gas Control. 15:16–31. https://doi.org/10.1016/j.ijggc.2013.01.009

    Article  Google Scholar 

  20. Mofarahi M, Sadrameli M, Towfighi J (2005) Four-bed vacuum pressure swing adsorption process for propylene/propane separation. Ind Eng Chem Res 44:1557–1564. https://doi.org/10.1021/ie034016k

    Article  Google Scholar 

  21. Zhang J, Webley PA, Xiao P (2008) Effect of process parameters on power requirements of vacuum swing adsorption technology for CO2 capture from flue gas. Energy Convers Manag 49:346–356. https://doi.org/10.1016/j.enconman.2007.06.007

    Article  Google Scholar 

  22. Wawrzyńczak D, Majchrzak-Kucęba I, Srokosz K, Kozak M, Nowak W, Zdeb J, Smółka W, Zajchowski A (2019) The pilot dual-reflux vacuum pressure swing adsorption unit for CO2 capture from flue gas. Sep Purif Technol 209:560–570. https://doi.org/10.1016/j.seppur.2018.07.079

    Article  Google Scholar 

  23. Tao L, Xiao P, Qader A, Webley PA (2019) CO2 capture from high concentration CO2 natural gas by pressure swing adsorption at the CO2CRC Otway site. Australia Int J Greenhouse Gas Control 83:1–10. https://doi.org/10.1016/j.ijggc.2018.12.025

    Article  Google Scholar 

  24. Cavenati S, Grande CA, Rodrigues AE (2005) Layered pressure swing adsorption for methane recovery from CH4/CO2/N2 streams. Adsorption. 11:549–554. https://doi.org/10.1007/s10450-005-5983-7

    Article  Google Scholar 

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Acknowledgements

The authors are grateful to Prof. M. Mofarahi for his valuable assistance during experimental setup commissioning. Financial help from Tarbiat Modares University is also acknowledged.

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Authors and Affiliations

  1. Chemical Engineering Department, Tarbiat Modares University, Tehran, 14115-111, Iran

    Mehdi Alibolandi, Seyed Mojtaba Sadrameli, Fatemeh Rezaee & Jafar Towfighi Darian

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  1. Mehdi Alibolandi
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  2. Seyed Mojtaba Sadrameli
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  3. Fatemeh Rezaee
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  4. Jafar Towfighi Darian
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Correspondence to Seyed Mojtaba Sadrameli.

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Highlights

• Separation of CO2/N2 mixture has been done by Vapor pressure swing adsorption process (VPSA)

• Two adsorbents namely zeolite 13X type and carbon molecular sieve have been used

• The scale of the setup is a large laboratory scale

• Experiments were performed in an eight-steps, four beds set up

• The maximum purity of 97.6% for zeolite and 76% for CMS were obtained

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Alibolandi, M., Sadrameli, S.M., Rezaee, F. et al. Separation of CO2/N2 mixture by vacuum pressure swing adsorption (VPSA) using zeolite 13X type and carbon molecular sieve adsorbents. Heat Mass Transfer 56, 1985–1994 (2020). https://doi.org/10.1007/s00231-020-02823-y

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  • DOI: https://doi.org/10.1007/s00231-020-02823-y

Keywords

  • Vacuum pressure swing adsorption
  • Carbon dioxide
  • Nitrogen
  • Zeolite 13X
  • CMS