To identify odorous substances of solid wood, the emission from two types of wood species, namely Phoebe neurantha (Hemsl.) Gamble and Osmanthus fragrans (Thunb.) Lour. was sampled by micro-chamber extractor, combined with the Tenax TA tube and multi-bed tube (carbopack C, carbopack B and carboxen 1000). The odor-active compounds were identified by gas chromatography-mass spectrometry/olfactometry (GC–MS/O), which combine instrumental and sensory analyses. The results showed that, for Phoebe neurantha and Osmanthus fragrans, 12 and 20 kinds of odor-active compounds were identified. The main odor contributors of Phoebe neurantha were “D-limonene, 2-hexanol, 1-heptanol and 2-hexanone”, with the dominant odor impressions of fragrant, irritant, special and fruity. The main odor contributors of Osmanthus fragrans were “camphene, heptanal and pentanal”, while the key odor impressions were spicy, fruity and fatty. VOC concentration and odorous concentration of Phoebe neurantha were higher than Osmanthus fragrans. The proportion of the odorant concentration to the TVOC concentration of Phoebe neurantha and Osmanthus fragrans was 77.39 and 58.68 percent, respectively. The multi-bed tube, which showed excellent adsorption performance for alcohols and compounds with low molecular weight in this study, is able to capture some of the key odor-active compounds that Tenax TA tube cannot collect. Identification of the composition of these two wood species will expand the solid wood odorous substance database and help to establish a method to investigate the odorants with low molecular weight from wood. Through this study, a better understanding of the characteristic odor from wooden materials used in daily life could be obtained.
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Aatamila M, Verkasalo PK, Korhonen MJ, Suominen AL, Hirvonen MR, Viluksela MK, Nevalainen A (2011) Odour annoyance and physical symptoms among residents living near waste treatment centres. Environ Res 111:164–170
Acree TE, Butts RM, Nelson PR, Lee CY (1976) Sniffer to determine the odor of gas chromatographic effluents. Anal Chem 48(12):1821–1822. https://doi.org/10.1021/ac50006a050
Acree TE, Barnard J, Cunningham DG (1984) A procedure for the sensory analysis of gas chromatographic effluents. Food Chem 14(4):273–286. https://doi.org/10.1016/0308-8146(84)90082-7
American Conference of Governmental Industrial Hygienists Documentation of the Threshold Limit Values and Biological Exposure Indices (1986) 5th ed. Cincinnati, OH: American Conference of Governmental Industrial Hygienists. p. 376
Bartsch J, Uhde E, Salthammer T (2016) Analysis of odour compounds from scented consumer products using gas chromatography–mass spectrometry and gas chromatography– olfactometry. Anal Chim Acta 904:98–106
Baxter CS, et al (2015) Alicyclic Hydrocarbons. Patty's Toxicology. 6th ed. (1999–2015). New York: Wiley, Inc. On–line Posting Date: August, 17
BSEN 13725 (2003) Air quality-determination of odour concentration by dynamic olfactometry. European Committee for Standardization, Brussels
Burdock GA et al (2010) Fenaroli’s Handbook of Flavor Ingredients, 6th edn. CRC Press p, Boca Raton, p 238
Díaz–Maroto MC, Guchu E, Castro–Vázquez L, De Torres C, Pérez–Coello MS (2008) Aroma–active compounds of American, French, Hungarian and Russian oak woods, studied by GC–MS and GC–O. Flavour Fragr J 23:93–98
Dong HJ, Wang QF, Shen J, Zeng B (2019a) Effects of temperature on volatile organic compounds and odor emissions of PVC–overlaid MDF. Wood Res 64(6):999–1010
Dong HJ, Jiang LQ, Shen J, Zhao Z, Wang QF (2019b) Shen XW Identification and analysis of odor–active substances from PVC–overlaid MDF. Environ Sci Pollut Res 26(20):20769–20779
Eggersdorfer M (2000) Terpenes Ullmann's Encyclopedia of Industrial Chemistry. 7th ed. (1999–2015). New York, NY: John Wiley & Sons. Online Posting Date: June 15.
Fuller GH, Steltenkamp R, Tisserand GA (1964) The gas chromatograph with human sensor: perfumer model. Ann NY Acad Sci 116(2):711–724. https://doi.org/10.1111/j.1749-6632.1964.tb45106.x
Furia TE (1980) CRC Handbook of Food Additives, vol 2. CRPress, Inc p, Boca Raton, p 275
Gallego E, Roca FJ, Perales JF, Guardino X (2010) Comparative study of the adsorption performance of a multi–sorbent bed (Carbotrap, Carbopack X, Carboxen 569) and a Tenax TA adsorbent tube for the analysis of volatile organic compounds (VOCs). Talanta 81(3):916–924
GB/T 29899–2013 (2013) Determination of the emission of volatile organic compounds from wood–based panels and furnishing—small chamber method. Standardization Administration of China, Beijing
Ghadiriasli R, Wagenstaller M, Buettner A (2018) Identification of odorous compounds in oak wood using odor extract dilution analysis and two–dimensional gas chromatography–mass spectrometry/olfactometry. Anal Bioanal Chem 410:6595–6607
Hoshika Y, Muto G (1982) Gas–chromatographic determination of concentrations of trace amounts of 46 odorants prepared in air in a 10–m3 stainless–steel odour test room. Analyst 107(1277):855
ISO 16000–6 (2012) Indoor air Part 6—determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA® sorbent, thermal desorption and gas chromatography using MS or MS–FID. Beuth Verlag, Berlin
Jha SK, Marina N, Liu C, Hayashi K (2015) Human body odor discrimination by GC–MS spectra data mining. Anal Methods 7(22):9549–9561
Jiang LQ, Shen J, Zhao Z, Dong HJ, Li YB (2019) Study on film properties and VOCs of nano– TiO2 and ZnO modified waterborne paints. J For Eng 4(04):148–155
Jones AP (1999) Indoor air quality and health. Atmos Environ 33(28):4535–4564
Kesen S, Amanpour A, Tsouli SS et al (2018) Characterization of aroma-active compounds in seed extract of black cumin (Nigella sativa L.) by aroma extract dilution analysis. Foods 7(7):98
Lewis RJ Sr (2007) Hawley’s condensed chemical dictionary, 15th edn. Wiley Inc., New York, NY p, p 639
Lewis RJ Sr (2012) Sax’s dangerous properties of industrial materials, 12th edn. Wiley-Interscience Wiley Inc., Hoboken, p 42741
Li ZJ, Shen J, Jiang LQ (2018) Analysis of odor release from melamine impregnated paper veneer. J Beijing For Univ 40(12):117–123
Liu WJ, Shen J, Wang QF (2017) Design of DL–SW micro–cabin for rapid detection and analysis of VOCs from wood–based panels. J For Eng 4:40–45
Liu R, Huang AM, Wang C, Lv B (2018a) Review of odor source and controlling technology for furniture. J Wood Ind 32(03):34–38
Liu R, Wang C, Huang AM, Lv B (2018b) Identification of odorous constituents of southern yellow pine and China fir wood: the effects of extractive removal. Anal Methods 10(18):2115–2122. https://doi.org/10.1039/C7AY02885G
Lu ZG, Wang QF, Xia KY, Hou JJ (2020) Development of a simulated indoor environment release cabin equipment. J For Eng 5(03):130–137
Lv B, Yang JK, Yang Z et al (2017) Discussion on the smell and environmental performance of wooden furniture. Chin Wood Based Panels 24(03):4–6
Ministry of the Environment Law No. 91 of 1971 (1971) Offensive odor control law. Government of Japan, Tokyo
NIOSH (2005) Pocket Guide to Chemical Hazards and Other Databases CD–ROM. Department of Health and Human Services, Centers for Disease Prevention and Control. National Institute for Occupational Safety & Health. DHHS (NIOSH) Publication No. 2005–151.
Polster J, Schieberle P (2015) Structure-odor correlations in homologous series of alkanethiols and attempts to predict odor thresholds by 3D-QSAR studies. J Agric Food Chem 63:1419–1432. https://doi.org/10.1021/jf506135c
Scheffler L, Sharapa C, Amar T, Buettner A (2018) Identification and Quantification of Volatile Ramson-Derived Metabolites in Humans. Frontiers in Chemistry 6:1–15
Schreiner L, Loos HM, Buettner A (2017) Identification of odorants in wood of Calocedrus decurrens (Torr.) Florin by aroma extract dilution analysis and two–dimensional gas chromatography–mass spectrometry/olfactometry. Anal Bioanal Chem 409:3719–3729
Schreiner L, Bauer P, Buettner A (2018) Resolving the smell of wood Identification of odour–active compounds in Scots pine (Pinus sylvestris L.). Sci Rep 8:1–9
Shen J, Jiang LQ (2018) A review of research on VOCs release from wood–based panels. J For Eng 3(06):1–10
Fenaroli's Handbook of Flavor Ingredients (1975) Volume 2. Edited, translated, and revised by T.E. Furia and N. Bellanca. 2nd ed. Cleveland: The Chemical Rubber Co 1975. p. 238
Ullrich F, Grosch W (1987) Identification of the most intense odor compounds formed during autoxidation of linoleic acid. Z Lebensm Unters For 184(4):277–282. https://doi.org/10.1007/BF01027663
Van den Dool H, Kratz PD (1963) A generalization of the retention index system including linear temperature programmed gas–liquid partition chromatography. J Chromatogr 11:463–470. https://doi.org/10.1016/s0021-9673(01)80947-x
Wang QF, Shen J, Du JH, Cao TY, Shen XW (2018) Characterization of odorants in particleboard coated with nitrocellulose lacquer under different environment conditions. For Prod J 68(3):272–280
Wang QF, Shen J, Shao YL, Dong HJ, Li ZJ, Shen XW (2019) Volatile organic compounds and odor emissions from veneered particleboards coated with water–based lacquer detected by gas chromatography–mass spectrometry/olfactometry. Eur J Wood Prod 77(5):771–781
Xie LS (2001) Interior environment and odor of wood. Furnit Inter Des 3:13–15
This research was supported by the “Project of National Natural Science Foundation of China” (Grant No. 31971582) and “The Fundamental Research Funds for the Central Universities” (No. 2572019AB04).
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Wang, Q., Shen, J., Wang, H. et al. Determination of odor-active compounds from Phoebe neurantha (Hemsl.) Gamble and Osmanthus fragrans (Thunb.) Lour. by GC–MS/O and micro-chamber combined with Tenax TA and multi-bed tubes. Wood Sci Technol 55, 1135–1151 (2021). https://doi.org/10.1007/s00226-021-01268-8