Skip to main content
Log in

Use of near-infrared spectroscopy for prediction of biomass and polypropylene in wood plastic composites

  • Original
  • Published:
Wood Science and Technology Aims and scope Submit manuscript

Abstract

The ratio of biomass to plastic in wood plastic composites (WPCs) is very important for the development of WPCs. This paper investigates the feasibility of predicting the biomass and polypropylene (PP) contents in three WPC species (Chinese fir/PP, poplar/PP and bamboo/PP) using near-infrared (NIR) spectroscopy combined with partial least squares regression (PLS). Several spectra pretreatments were applied to improve the models. Compared to other methods, baseline correction data processing gave the optimal model. The results of external validation showed that the coefficient of determination (R 2), root mean square error of prediction (RMSEP) and the ratio of the standard deviation in the validation set to the RMSEP (RPD) were 0.930, 1.944 and 3.578 for biomass and 0.930, 1.958 and 3.587 for PP, respectively. It is concluded that NIR in combination with PLS is capable of reliable quantification of biomass and PP in a diversity of PP-based WPCs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  • Ahmad Fuad MY, Zaini MJ, Jamaludin M, Mohd Ishak ZA, Mohd Omar AK (1994) Determination of filler content in rice husk ash and wood-based composites by thermogravimetric analysis. J Appl Polym Sci 51(11):1875–1882

    Article  Google Scholar 

  • Ashori A (2008) Wood-plastic composites as promising green-composites for automotive industries. Bioresour Technol 99(11):4661–4667

    Article  CAS  PubMed  Google Scholar 

  • Balasuriya PW, Ye L, Mai YW (2001) Mechanical properties of wood flake-polyethylene composites. Part I: effects of processing methods and matrix melt flow behavior. Compos A 32(5):619–629

    Article  Google Scholar 

  • Dányádi L, Renner K, Móczó J, Pukánszky B (2007) Wood flour filled polypropylene composites: interfacial adhesion and micromechanical deformations. Polym Eng Sci 47(8):1246–1255

    Article  Google Scholar 

  • Doublet J, Boulanger A, Ponthieux A, Laroche C, Poitrenaud M, Cacho Rivero JA (2013) Predicting the biochemical methane potential of wide range of organic substrates by near infrared spectroscopy. Bioresour Technol 128:252–258

    Article  CAS  PubMed  Google Scholar 

  • Hayes DJM (2012) Development of near infrared spectroscopy models for the quantitative prediction of the lignocellulosic components of wet Miscanthus samples. Bioresour Technol 119:393–405

    Article  CAS  PubMed  Google Scholar 

  • He W, Hu H (2013) Prediction of hot-water-soluble extractive, pentosan and cellulose content of various wood species using FT-NIR spectroscopy. Bioresour Technol 140:299–305

    Article  CAS  PubMed  Google Scholar 

  • He C, Chen L, Yang Z, Huang G, Liao N, Han L (2012) A rapid and accurate method for on-line measurement of straw–coal blends using near infrared spectroscopy. Bioresour Technol 110:314–320

    Article  CAS  PubMed  Google Scholar 

  • Jeske H, Schirp A, Cornelius F (2012) Development of a thermogravimetric analysis (TGA) method for quantitative analysis of wood flour and polypropylene in wood plastic composites (WPC). Thermochim Acta 543:165–171

    Article  CAS  Google Scholar 

  • Kiguchi M, Kataoka Y, Matsunaga H, Yamamoto K, Evans PD (2007) Surface deterioration of wood-flour polypropylene composites by weathering trials. J Wood Sci 53(3):234–238

    Article  CAS  Google Scholar 

  • Labbé N, Lee SH, Cho HW, Jeong MK, André N (2008) Enhanced discrimination and calibration of biomass NIR spectral data using non-linear kernel methods. Bioresour Technol 99(17):8445–8452

    Article  PubMed  Google Scholar 

  • Lao W, Li G, Zhou Q, Qin T (2014) Quantitative analysis of biomass in three types of wood-plastic composites by FTIR spectroscopy. BioResources 9(4):6073–6086

    Article  CAS  Google Scholar 

  • Li G, Lao W, Qin T, Huang L (2014) Rapid determination of biomass and polypropylene in three types of wood plastic composites (WPCs) using FTIR spectroscopy and partial least squares regression (PLSR). Holzforschung 69(4):399–404

    Google Scholar 

  • Lin Q, Zhou X, Dai G (2002) Effect of hydrothermal environment on moisture absorption and mechanical properties of wood flour-filled polypropylene composites. J Appl Polym Sci 85(14):2824–2832

    Article  CAS  Google Scholar 

  • Mankowski M, Morrell JJ (2000) Patterns of fungal attack in wood-plastic composites following exposure in soil block test. Wood Fiber Sci 32(3):340–345

    CAS  Google Scholar 

  • Nuñez AJ, Sturm PC, Kenny JM, Aranguren MI, Marcovich NE, Reboredo MM (2003) Mechanical characterization of polypropylene-wood flour composites. J Appl Polym Sci 88(6):1420–1428

    Article  Google Scholar 

  • Peng X, Chen H (2008) Rapid estimation of single cell oil content of solid-state fermented mass using near-infrared spectroscopy. Bioresour Technol 99(18):8869–8872

    Article  CAS  PubMed  Google Scholar 

  • Pohl F, Senn T (2011) A Rapid and sensitive method for the evaluation of cereal grains in bioethanol production using near infrared reflectance spectroscopy. Bioresour Technol 102(3):2834–2841

    Article  CAS  PubMed  Google Scholar 

  • Renneckar S, Zink-Sharp AG, Ward TC, Glasser WG (2004) Compositional analysis of thermoplastic wood composites. J Appl Polym Sci 93(3):1484–1492

    Article  CAS  Google Scholar 

  • Rimdusit S, Wongsongyot S, Jittarom S, Suwanmala P, Tiptipakorn S (2011) Effects of gamma irradiation with and without compatibilizer on the mechanical properties of polypropylene/wood flour composites. J Polym Res 18(4):801–809

    Article  CAS  Google Scholar 

  • Schwanninger M, Rodrigues JC, Fackler K (2011) A Review of Band Assignments in Near Infrared Spectra of Wood and Wood Components. J Near Infrared Spectrosc 19(5):287–308

    Article  CAS  Google Scholar 

  • Sombatsompop N, Chaochanchaikul K, Phromchirasulk C, Thongsang S (2003) Effect of wood sawdust content on rheological and structural changes, and thermo-mechanical properties of PVC/sawdust composites. Polym Int 52(12):1847–1855

    Article  CAS  Google Scholar 

  • Urbano-Cuadrado M, Luque de Castro MD, Pérez-Juan PM, García-Olmoc J, Gómez-Nietod MA (2004) Near infrared reflectance spectroscopy and multivariate analysis in enology: determination or screening of fifteen parameters in different types of wines. Anal Chim Acta 527(1):81–88

    Article  CAS  Google Scholar 

  • Watari M, Ozaki Y (2004) Prediction of ethylene content in melt-state random and block polypropylene by near-infrared spectroscopy and chemometrics: comparison of a new calibration transfer method with a slope/bias correction method. Appl Spectrosc 58(10):1210–1218

    Article  CAS  PubMed  Google Scholar 

  • Windt M, Meier D, Lehnen R (2011) Quantification of polypropylene (PP) in wood plastic composites (WPCs) by analytical pyrolysis (Py) and differential scanning calorimetry (DSC). Holzforschung 65(2):199–207

    Article  CAS  Google Scholar 

  • Xu F, Wang D (2013) Rapid determination of sugar content in corn stover hydrolysates using near infrared spectroscopy. Bioresour Technol 147:293–298

    Article  CAS  PubMed  Google Scholar 

  • Ye XP, Liu L, Hayes D, Womac A, Hong K, Sokhansanj S (2008) Fast classification and compositional analysis of cornstover fractions using Fourier transform near-infrared techniques. Bioresour Technol 99(15):7323–7332

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by Special Fund for Forest Scientific Research in the Public Welfare (201204802-2) from State Forestry Administration of the People’s Republic of China.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Gaiyun Li.

Additional information

Gaiyun Li and Wanli Lao have contributed equally to this work and should be regarded as co-first authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, G., Lao, W., Zou, X. et al. Use of near-infrared spectroscopy for prediction of biomass and polypropylene in wood plastic composites. Wood Sci Technol 50, 705–714 (2016). https://doi.org/10.1007/s00226-016-0799-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00226-016-0799-z

Keywords

Navigation