Abstract
The main goal of the ageing process of tequila is to improve its organoleptic properties. This process is mainly performed in white oak barrels from trees of the Quercus species, whose wood confers a wide variety of aromas, flavors, and colors to the beverage, providing the desirable organoleptic character to this beverage. In this work, the effects of tequila maturation in recycled and regenerated oak barrels were evaluated by determining minor volatile compounds (VOCs) obtained by microdistillation of the liquid–liquid extraction of tequila samples. GC–MS analysis shows that in silver, aged, and extra-aged tequila types, ~62 VOCs were identified. The principal component analysis of VOC content for each type of tequila showed that they could be classified as four patterns (α, β, γ, and δ groups), proposed to establish their VOC content associated with the maturation process in recycled and regenerated oak barrels from Quercus alba. The α group, constituted by 21 VOCs, did not show significant differences in the concentration of compounds between the silver, aged, and extra-aged types of tequila, β group, constituted by 16 VOCs, which decreased or went missing by maturation process of silver tequila, the γ and δ groups, constituted by 15 and 10 VOCs, correlate with aged and extra-aged tequila, respectively. Findings indicate that the γ and δ groups are associated with the maturation process of tequila, suggesting that recycled and regenerated oak barrels of Q. alba is a procedure suitable for ageing of tequila, providing important VOC content to the beverage.
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References
Acosta Navarrete MS, López Pérez M, Miranda López R (2007) El tequila, su aroma y su sabor. Ciencias 87:50–53
Campos García J, Sosa Agurre CR, Reyes de la Cruz H, López Álvarez JA (2007) Levadura fermentadora para la elaboración de bebidas alcoholicas destiladas. MEXICO Patent, MX/a/2007/014445; No. Pat. 271316
López-Alvarez A, Díaz-Pérez AL, Sosa-Aguirre C, Macías-Rodríguez L, Campos-García J (2012) Ethanol yield and volatile compound content in fermentation of agave must by Kluyveromyces marxianus UMPe-1 comparing with Saccharomyces cerevisiae baker’s yeast used in tequila production. J Biosci Bioeng 113(5):614–618. doi:10.1016/j.jbiosc.2011.12.015
López MG (1999) Tequila aroma. In: Shahidi F, Ho C-T (eds) Flavor chemistry of ethnic foods. Springer US, Boston, pp 211–217. doi:10.1007/978-1-4615-4783-9_20
Ceballos-Magaña SG, de Pablos F, Jurado JM, Martín MJ, Alcázar Á, Muñiz-Valencia R, Gonzalo-Lumbreras R, Izquierdo-Hornillos R (2013) Characterisation of tequila according to their major volatile composition using multilayer perceptron neural networks. Food Chem 136(3–4):1309–1315. doi:10.1016/j.foodchem.2012.09.048
Benn SM, Peppard TL (1996) Characterization of tequila flavor by instrumental and sensory analysis. J Agric Food Chem 44(2):557–566. doi:10.1021/jf9504172
López MG (2006) Authenticity: the case of tequila. In: Authentication of food and wine. ACS Symposium Series, vol 952. pp 273–287. doi:10.1021/bk-2007-0952.ch018
Oberholster A, Elmendorf BL, Lerno LA, King ES, Heymann H, Brenneman CE, Boulton RB (2015) Barrel maturation, oak alternatives and micro-oxygenation: Influence on red wine aging and quality. Food Chem 173:1250–1258. doi:10.1016/j.foodchem.2014.10.043
Michel J, Jourdes M, Le Floch A, Giordanengo T, Mourey N, Teissedre P-L (2013) Influence of wood barrels classified by NIRS on the ellagitannin content/composition and on the organoleptic properties of wine. J Agric Food Chem 61(46):11109–11118. doi:10.1021/jf403192y
Cerdán TG, Ancín-Azpilicueta C (2006) Effect of oak barrel type on the volatile composition of wine: storage time optimization. LWT Food Sci Technol 39(3):199–205. doi:10.1016/j.lwt.2005.01.009
Conner J (2014) Chapter 11—maturation. In: Stewart IR (ed) Whisky (Second edition). Academic Press, San Diego, pp 199–220. doi:http://dx.doi.org/10.1016/B978-0-12-401735-1.00011-8
Gómez-Plaza E, Cano-López M (2011) A review on micro-oxygenation of red wines: claims, benefits and the underlying chemistry. Food Chem 125(4):1131–1140. doi:10.1016/j.foodchem.2010.10.034
Khennouf S, Benabdallah H, Gharzouli K, Amira S, Ito H, Kim T-H, Yoshida T, Gharzouli A (2003) Effect of tannins from quercus suber and quercus coccifera leaves on ethanol-induced gastric lesions in mice. J Agric Food Chem 51(5):1469–1473. doi:10.1021/jf020808y
Martínez García J, Barúa González M, Gutiérrez Viguera AR (2006) Influencia del origen del roble en la modificación de la composición aromática de los vinos durante la crianza. Paper presented at the Federación Española de Asociaciones de Enólogos, http://dialnet.unirioja.es/servlet/oaiart?codigo=4005342
Gougeon RD, Lucio M, Frommberger M, Peyron D, Chassagne D, Alexandre H, Feuillat F, Voilley A, Cayot P, Gebefügi I, Hertkorn N, Schmitt-Kopplin P (2009) The chemodiversity of wines can reveal a metabologeography expression of cooperage oak wood. Proc Natl Acad Sci USA 106(23):9174–9179. doi:10.1073/pnas.0901100106
Vivas N (2005) Manual de tonelería: destinado a usuarios de toneles. Ediciones Mundi-Prensa, Libros, Madrid
Kanakaki E, Siderakou D, Kallithraka S, Kotseridis Y, Makris D (2015) Effect of the degree of toasting on the extraction pattern and profile of antioxidant polyphenols leached from oak chips in model wine systems. Eur Food Res Technol 240(5):1065–1074. doi:10.1007/s00217-014-2410-x
Vivas N, Vivas de Gaulejac N, Vitry C, Mouche C, Kahn N, Nonier-Bourden MF, Absalon C (2013) Impact of ethanol content on the scavenging activities of oak wood C-glycosidic ellagitannins. Application to the evaluation of the nutritional status of spirits. J Inst Brew 119(3):116–125. doi:10.1002/jib.70
Cedeño MC (1995) Tequila production. Crit Rev Biotechnol 15(1):1–11. doi:10.3109/07388559509150529
Vallejo-Cordoba B, González-Córdova AF, del Carmen Estrada-Montoya M (2004) Tequila volatile characterization and ethyl ester determination by solid phase microextraction gas chromatography/mass spectrometry analysis. J Agric Food Chem 52(18):5567–5571. doi:10.1021/jf0499119
Pedro AV-L, Miriam GR-O (2012) Tequila processing and flavor. In: Flavor chemistry of wine and other alcoholic beverages. ACS Symposium Series, vol 1104. American Chemical Society, pp 237–276. doi:10.1021/bk-2012-1104.ch015
Mercedes GL, Jean Pierre D (2001) Tequilas: charm analysis of blanco, reposado, and anejo tequilas. In: Gas chromatography-olfactometry. ACS Symposium Series, vol 782. American Chemical Society, pp 62–72. doi:10.1021/bk-2001-0782.ch006
Jacob L, Keith C (2012) Streamlined analysis of potent odorants in distilled alcoholic beverages: the case of tequila. In: flavor chemistry of wine and other alcoholic beverages. ACS Symposium Series, vol 1104. American Chemical Society, pp 37–53. doi:10.1021/bk-2012-1104.ch003
De León-Rodríguez A, Escalante-Minakata P, Jiménez-García MI, Ordoñez-Acevedo LG, Flores Flores JL, Barba de la Rosa AP (2008) Characterization of volatile compounds from ethnic agave alcoholic beverages by gas chromatography-mass spectrometry. Food Technol Biotechnol 46(4):448–455
De León-Rodríguez A, González-Hernández L, Barba de la Rosa AP, Escalante-Minakata P, López MG (2006) Characterization of volatile compounds of mezcal, an ethnic alcoholic beverage obtained from agave salmiana. J Agric Food Chem 54(4):1337–1341. doi:10.1021/jf052154+
Du M, Ahn DU (2001) Volatile substances of chinese traditional jinhua ham and cantonese sausage. J Food Sci 66(6):827–831. doi:10.1111/j.1365-2621.2001.tb15181.x
Xiao ZB, Zhu JC, Feng T, Tian HX, Yu HY, Niu YW, Zhang XM (2010) Comparison of volatile components in Chinese traditional pickled peppers using HS–SPME–GC–MS, GC–O and multivariate analysis. Nat Prod Res 24(20):1939–1953. doi:10.1080/14786419.2010.506875
Acknowledgements
This study was funded by the Consejo Nacional de Ciencia y Tecnología (CONACYT) of México (Grant Number 256119), Universidad Michoacana de San Nicolás de Hidalgo/C.I.C.2.14 grant. To the tequila factory, Altos Ciénega Unidos SPR de RL for the facilities afforded.
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Aguilar-Méndez, O., López-Álvarez, J.A., Díaz-Pérez, A.L. et al. Volatile compound profile conferred to tequila beverage by maturation in recycled and regenerated white oak barrels from Quercus alba . Eur Food Res Technol 243, 2073–2082 (2017). https://doi.org/10.1007/s00217-017-2901-7
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DOI: https://doi.org/10.1007/s00217-017-2901-7