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Migration of plasticizers from the gaskets of lids into oily food in glass jars: a European enforcement campaign

European Food Research and Technology volume 235, pages 129–137 (2012)Cite this article

Abstract

The results of a joint European enforcement campaign are described. The two governmental food control laboratories in Stuttgart/Germany and Zürich/Switzerland analyzed the migration of the plasticizers from the gaskets of lids into food in glass jars for 411 products collected by the authorities of 21 European countries. Of these products, 308 contained free edible oil in contact with the gasket and were considered relevant for further evaluation. In 74 of the relevant products (24 %), either non-authorized plasticizers had been used or the migration exceeded the legal limits, in some cases for several parameters and by up to more than a factor of 10. Most of the products were 1–4 years from the end of their shelf life. Taking into account that migration proceeds throughout storage, sometimes even accelerates, limits are likely to be exceeded for many more products by the end of the shelf life. Polyadipate showed the lowest migration. Promising gaskets are either plasticized exclusively with a polyadipate or with combinations of substances. Joint enforcement is cost-effective, particularly when chemical analysis is demanding; accumulation of experience facilitates the evaluation of results, and joint measures are promising to be more effective.

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References

  1. Hammarling L, Gustavsson H, Svensson K, Karlsson S, Oskarsson A (1998) Food Addit Contam 15:203–208

    Article  CAS  Google Scholar 

  2. Scientific Committee on Food (SCF) (1999) Compilations of the evaluations of the SCF on certain monomers and additives used in the manufacture of plastic materials intended to come into contact with foodstuffs until 21 March 1997. Reports of the Scientific Committee for Food (42nd series). European Commission, Luxembourg

  3. MAFF (1999) Food surveillance information sheet no. 196. http://www.foodstandards.gov.uk/maff/archive/food/infsheet/1999/no186/186esbo.htm

  4. Fantoni L, Simoneau C (2003) Food Addit Contam 20:1087–1096

    Article  CAS  Google Scholar 

  5. Fankhauser-Noti A, Fiselier K, Biedermann S, Biedermann M, Grob K, Armellini F, Rieger K, Skjevrak I (2005) Eur Food Res Technol 221:416–422

    Article  CAS  Google Scholar 

  6. Biedermann-Brem S, Grob K, Biedermann M (2001) Mitt Lebensm Unters Hyg 92:515–534

    CAS  Google Scholar 

  7. Biedermann-Brem S, Biedermann M, Grob K (2004) Mitt Lebensm Unters Hyg 95:261–280

    CAS  Google Scholar 

  8. Suman M, De Dominicis E, Commissati I (2010) J Mass Spectrom 45:996–2002

    Article  CAS  Google Scholar 

  9. European Food Safety Authority (EFSA) (2004) http://www.efsa.eu.int/press_room/questions_and_answers/44_en.html

  10. Elss S, Grünewald L, Richling E, Schreier P (2004) Food Addit Contam 21:811–814

    Article  CAS  Google Scholar 

  11. Fankhauser-Noti A, Biedermann-Brem S, Grob K (2006) Eur Food Res Technol 223:447–453

    Article  CAS  Google Scholar 

  12. European Commission, SANCO (2006) Rapid alert system for foods and feeds (Rasff) news 06-314 from Aug 18

  13. Bundesamt für Gesundheit (2004) Weisung 3, ESBO in Lebensmitteln. Bern, Nov 5, 2004. http://www.bag.admin.ch/themen/lebensmittel/04861/04912/index.html?lang=de

  14. Biedermann M, Fiselier K, Marmiroli G, Avanzini G, Rutschmann E, Pfenninger S, Grob K (2008) Eur Food Res Technol 226:1399–1407

    Article  CAS  Google Scholar 

  15. European Food Safety Authority (EFSA) (2006) Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC). EFSA J 395–401, 1–21

  16. Biedermann M, Fiselier K, Grob K (2008) Trends Food Sci Techn 19:145–155

    Article  CAS  Google Scholar 

  17. Biedermann-Brem S, Biedermann M, Fiselier K, Grob K (2005) Food Addit Contam 22:1274–1284

    Article  CAS  Google Scholar 

  18. Fankhauser-Noti A, Fiselier K, Biedermann-Brem S, Grob K (2005) J Chromatogr A 1082:214–219

    Article  CAS  Google Scholar 

  19. Fankhauser-Noti A, Grob K (2006) J Sep Sci 29:2365–2374

    Article  CAS  Google Scholar 

  20. Biedermann M, Grob K (2006) Chromatographia 64:543–552

    Article  CAS  Google Scholar 

  21. Biedermann M, Grob K (2006) Packag Techn Sci 19:159–178

    Article  CAS  Google Scholar 

  22. Simoneau C (2010) Activity report 2009 of the EURL for food contact materials. http://publications.jrc.ec.europa.eu/repository/bitstream/111111111/14490/1/reqno_jrc59503_annual_report_2009_eurl-fcm_final_07_15.pdf%5B1%5D.pdf

  23. Graubardt N, Biedermann M, Fiselier K, Bolzoni L, Pedrelli T, Cavalieri C, Simoneau C, Grob K (2009) Food Addit Contam 26:1113–1122

    Article  CAS  Google Scholar 

  24. Graubardt N, Biedermann M, Fiselier K, Bolzoni L, Cavalieri C, Grob K (2009) Food Addit Contam 26:1217–1225

    Article  CAS  Google Scholar 

  25. European Food Safety Authority (EFSA) (2009) Panel on food contact materials, enzymes, flavourings and processing aids (CEF). EFSA J 7(12):1398

    Google Scholar 

  26. Fankhauser-Noti A, Grob K (2006) Trends Food Sci Techn 17:105–112

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Official Food Control Authority of the Canton of Zürich, P.O. Box 1471, 8032, Zurich, Switzerland

    Gregor McCombie, Maurus Biedermann, Sandra Biedermann-Brem, Michael Zurfluh, Gaby Sutter, Matthias Landis & Koni Grob

  2. Chemisches und Veterinäruntersuchungsamt Stuttgart, Schaflandstr. 3/2, 70736, Fellbach, Germany

    Antje Harling-Vollmer, Maria Morandini, Gabriele Schmäschke, Sylvia Pechstein & Werner Altkofer

Authors
  1. Gregor McCombie
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  2. Antje Harling-Vollmer
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  3. Maria Morandini
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  4. Gabriele Schmäschke
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  5. Sylvia Pechstein
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  6. Werner Altkofer
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  7. Maurus Biedermann
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  8. Sandra Biedermann-Brem
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  9. Michael Zurfluh
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  10. Gaby Sutter
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  11. Matthias Landis
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  12. Koni Grob
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Corresponding author

Correspondence to Koni Grob.

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McCombie, G., Harling-Vollmer, A., Morandini, M. et al. Migration of plasticizers from the gaskets of lids into oily food in glass jars: a European enforcement campaign. Eur Food Res Technol 235, 129–137 (2012). https://doi.org/10.1007/s00217-012-1739-2

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  • DOI: https://doi.org/10.1007/s00217-012-1739-2

Keywords

  • Plasticized PVC
  • Preserves in glass jars
  • Epoxidized soybean oil (ESBO)
  • Polyadipates
  • Migration into oil food