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European Food Research and Technology

, Volume 232, Issue 1, pp 175–182 | Cite as

Migration of mineral oil from printed paperboard into dry foods: survey of the German market

  • Antje Vollmer
  • Maurus Biedermann
  • Florian Grundböck
  • Jan-Erik Ingenhoff
  • Sandra Biedermann-Brem
  • Werner Altkofer
  • Koni Grob
Original paper

Abstract

From the German market, 119 samples of dry food were analyzed for the migration of mineral oil. The products selected were packed in paperboard boxes and intended for storage for extended periods of time at ambient temperature. The 0.6 mg/kg limit for mineral oil saturated hydrocarbons (MOSH) derived from the WHO/JECFA evaluation was frequently exceeded by a factor of 10–100. Typically, 10–20% of the migrating mineral oil consisted of aromatic hydrocarbons (MOAH). Most samples were merely 2–3 months old and far from the end of their shelf life (usually 1–3 years). From the assumption that about 70% of the MOSH and MOAH which are eluted from GC up to the C24 n-alkane (<C24) end up in the food (potential of migration), it was estimated that migration might almost triple before the products reach the end of their shelf life, reaching 31 mg/kg on average, with several samples exceeding 100 mg/kg. At the time of the analysis, products without an internal bag and with a bag of paper or polyethylene reached up to about 80% of the potential of migration (average, 30–50%). Bags of polypropylene, acrylate-coated polypropylene, PET or with an aluminum layer seemed to block migration (with one possible exception), but it was premature to reach conclusions on long-term functional barrier properties. From the comparison with <C24 MOSH concentrations in unprinted recycled paperboards, it was estimated than on average about a quarter of the migrating mineral oil was from printing ink used for decorating the box.

Keywords

Paperboard boxes Mineral oil Recycled board Printing inks Mineral oil saturated hydrocarbons (MOSH) Shelf life 

Notes

Acknowledgments

The study was financed by the Federal Ministry of Food, Agriculture and Consumer Protection (BMELV) via the Federal Agency of Agriculture and Nutrition (BLE), Germany. Gregor McCombie characterized the plastic bags by FT-IR.

References

  1. 1.
    German Federal Institute for Risk Assessment (BfR). Übergänge von Mineralöl aus Verpackungsmaterialien auf Lebensmittel. Stellungnahme Nr. 008/2010 des BfR vom 09. Dezember 2009, http://www.bfr.bund.de/cm/216/uebergaenge_von_mineraloel_aus_verpackungsmaterialien_auf_lebensmittel.pdf
  2. 2.
    BfR (2010) Questions and answers on the migration of mineral oil from packaging materials to foodstuffs BfR FAQ, 10 March 2010, http://www.bfr.bund.de/cd/50677
  3. 3.
    Biedermann M, Grob K (2010) Eur Food Res Technol 230:785–796CrossRefGoogle Scholar
  4. 4.
    Joint FAO/WHO Expert Committee on Food Additives (JECFA; 2002) 59th report, 11-20; WHO Technical Report Series 913, http://whqlibdoc.who.int/trs/WHO_TRS_913.pdf
  5. 5.
    Scientific Committee for Food (SCF), Opinion on Mineral and Synthetic Hydrocarbons, 22 September 1995Google Scholar
  6. 6.
    Kantonales Labor Zürich, Jahresbericht 2009, http://www.klzh.ch/downloads/jb_2009_klzh.pdf
  7. 7.
    Biedermann M, Uematsu Y, Grob K (2010) Packaging Technol Sci [Epub ahead of print]Google Scholar
  8. 8.
    Droz C, Grob K (1997) Z Lebensm Unters Forsch 205:239–241CrossRefGoogle Scholar
  9. 9.
    Swiss regulation SR 817.023.21 Verordnung des EDI über Bedarfsgegenstände vom 23. November 2005 (Stand 1. April 2010), http://www.admin.ch/ch/d/sr/817_023_21/index.html
  10. 10.
    Lorenzini R, Fiselier K, Biedermann M, Barbanera M, Braschi I, Grob K (2010) Food Addit Contam (accepted)Google Scholar
  11. 11.
    Triantafyllou VI, Akrida-Demertzi K, Demertzis PG (2005) J Chrom A 1077:74–79CrossRefGoogle Scholar
  12. 12.
    Triantafyllou VI, Akrida-Demertzi K, Demertzis PG (2007) Food Chem 101:1759–1768CrossRefGoogle Scholar
  13. 13.
    Biedermann M, Grob K (2009) J Agric Food Chem 57:8711–8721CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 2010

Authors and Affiliations

  • Antje Vollmer
    • 1
  • Maurus Biedermann
    • 2
  • Florian Grundböck
    • 2
  • Jan-Erik Ingenhoff
    • 2
  • Sandra Biedermann-Brem
    • 2
  • Werner Altkofer
    • 1
  • Koni Grob
    • 2
  1. 1.Chemisches und Veterinäruntersuchungsamt StuttgartFellbachGermany
  2. 2.Official Food Control Authority of the Canton of ZürichZurichSwitzerland

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