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Correction to: Analytical and Bioanalytical Chemistry (2023) 415: 841–854
The authors regret that the sign convention in the description of the extended Kalman filter in the original publication was flawed. The state vectors \(\hat{x}_1\) and \(\hat{x}_2\) should have been defined as \(\hat{x}_1=E(-\Delta x)\) and \(\hat{x}_2=E(\frac{\kappa F}{V}\Delta t)\), respectively. Note that the sign of both state variables was changed. Consequently, a minus sign is missing in the exponential function of the transfer function for the first state estimate (Eq. 6 in the original publication), i.e.
Two minor notation errors shall furthermore be disclosed: \(\textbf{H}_k\) should be a row vector (defined as a column vector) and \(R_k = \sigma ^2_w\) is a scalar. All other equations are correctly documented and not impacted by the disclosed errors.
As an immediate consequence of the errors coming to our awareness, we reviewed the code developed for this project. We conclude that the errors were limited to the mathematical description in the paper. The code is not affected and was correctly implemented from the beginning. Therefore, all visualizations and conclusions drawn in the paper remain valid.
For simplifying the understanding of the implemented extended Kalman filter for future readers, we are publishing a Python-based version of the code along this correction.
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15 March 2024
Springer Nature’s version of this paper was updated: Supplementary Material note has been inserted.
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Rolinger, L., Hubbuch, J. & Rüdt, M. Correction to: Monitoring of ultra- and diafiltration processes by Kalman-filtered Raman measurements. Anal Bioanal Chem 416, 1775 (2024). https://doi.org/10.1007/s00216-024-05168-1
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DOI: https://doi.org/10.1007/s00216-024-05168-1