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Analytical and Bioanalytical Chemistry

, Volume 405, Issue 9, pp 2987–2994 | Cite as

Isotope ratio measurements with a fully simultaneous Mattauch–Herzog ICP-MS

  • Dirk ArdeltEmail author
  • Aleksandra Polatajko
  • Oliver Primm
  • Maurice Reijnen
Technical Note

Abstract

A fully simultaneous ICP-MS, based on a compact Mattauch–Herzog geometry with a permanent magnet and a large, spatially resolving semiconductor ion detector covering the complete inorganic relevant mass range from 6Li to 238U in a single measurement, has been used to determine isotope ratios and assess achievable isotope ratio precisions. Measurements of the 235/238U isotopic ratio, chosen as example for an isotopic system with a disparate isotope ratio, yielded a precision of 0.05 % relative. To evaluate the expected multi-isotope ratio measurement capabilities of the system used, several isotope ratios spanning a wide range (6/7Li, 84/86Sr, 87/86Sr, 88/86Sr, 204/207Pb, 206/207Pb and 208/207Pb) were measured simultaneously, using a synthetic multi-element standard as sample. Very satisfying isotope ratio precisions, between 0.5 and 0.04 % relative, depending on the isotope ratio in question were found during the simultaneous multi-isotope ratio measurements. Together with a brief description of the system and measurement procedures employed for this technical note, the results achieved are assessed in view of other existing ICP-MS-based isotope ratio techniques.

Figure

Fully simultaneous Mattauch-Herzog geometry MS with a spatially resolving semiconductor ion detector (schematic)

Keywords

IR-ICP-MS Fully simultaneous ICP-MS Mattauch–Herzog geometry Spatially resolving semiconductor ion detector Simultaneous multi-element IR-ICP-MS 

References

  1. 1.
    Becker JS (2002) J Anal At Spectrom 17:1172–1185CrossRefGoogle Scholar
  2. 2.
    Willie S, Mester Z, Sturgeon RE (2005) J Anal At Spectrom 20:1358–1364CrossRefGoogle Scholar
  3. 3.
    Resano M, Marzo MP, Alloza R, Saenz C, Vanhaecke F, Yang L, Willie S, Sturgeon RE (2010) Anal Chim Acta 677:55–63CrossRefGoogle Scholar
  4. 4.
    Rowland A, Holcombe JA (2009) Spectrochim Acta Part B 64:35–41CrossRefGoogle Scholar
  5. 5.
    Vanhaecke F, Degryse P (eds) (2012) Isotopic analysis: fundamentals and applications using ICP-MS, First edn. WILEY-VCH, WeinheimGoogle Scholar
  6. 6.
    Woodhead JD (2010) Geostand Geoanal Res 34:395–406CrossRefGoogle Scholar
  7. 7.
    Yang L (2009) Mass Spectrom Rev 28:990–1011CrossRefGoogle Scholar
  8. 8.
    Heumann KG, Vanhaecke F (eds.) (2008) Anal. Bioanal. Chem. Issue entitled “Isotope Ratios in Analytical Chemistry”, Anal Bioanal Chem 390Google Scholar
  9. 9.
    Becker JS (2005) J Anal At Spectrom 20:1173–1184CrossRefGoogle Scholar
  10. 10.
    Albaréde F, Beard B (2004) Rev Mineral Geochem 55:113–152CrossRefGoogle Scholar
  11. 11.
    Cromwell EF, Arrowsmith P (1995) ‘ICP-MS with a Mattauch–Herzog/array detector instrument: the simultaneous advantage’, FACSS XXII Conference, 016, 1995, Cincinnati, OHGoogle Scholar
  12. 12.
    Cromwell EF, Arrowsmith P (1996) J Am Soc Mass Spectrom 7:458–466CrossRefGoogle Scholar
  13. 13.
    Burgoyne TW, Hieftje GM, Hites RA (1997) J Am Soc Mass Spectrom 8:307–318CrossRefGoogle Scholar
  14. 14.
    Denton MB (1998) ‘Spectroscopic instrumentation in the 21st century: excitement on the horizon’, Winter Conference on Plasma Spectrochemistry, PL1, 1998, Scottsdale, AZGoogle Scholar
  15. 15.
    Mattauch J, Herzog R (1934) Z F Phys A 89:786–795CrossRefGoogle Scholar
  16. 16.
    Burgoyne TW, Hieftje GM (1996) Mass Spectrom Rev 15:241–259CrossRefGoogle Scholar
  17. 17.
    Barnes JH IV, Schilling GD, Sperline RP, Denton MB, Young ET, Barinaga CJ, Koppenaal DW, Hieftje GM (2004) Anal Chem 76:2531–2536CrossRefGoogle Scholar
  18. 18.
    Schilling GD, Andrade FJ, Barnes JH IV, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2006) Anal Chem 78:4319–4325CrossRefGoogle Scholar
  19. 19.
    Schilling GD, Ray SJ, Rubinshtein AA, Felton JA, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2009) Anal Chem 81:5467–5473CrossRefGoogle Scholar
  20. 20.
    Schilling GD, Ray SJ, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2010) J Anal At Spectrom 25:322–327CrossRefGoogle Scholar
  21. 21.
    Felton JA, Schilling GD, Ray SJ, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2001) J Anal At Spectrom 26:300–304CrossRefGoogle Scholar
  22. 22.
    Peschel BU, Andrade FJ, Wetzel WC, Schilling GD, Hieftje GM, Broekaert JAC, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW (2006) Spectrochim Acta Part B 61:42–49CrossRefGoogle Scholar
  23. 23.
    Schilling GD, Andrade FJ, Barnes JH IV, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM (2007) Anal Chem 79:7662–7668CrossRefGoogle Scholar
  24. 24.
  25. 25.
    Resano M, McIntosh KS, Vanhaecke F (2012) J Anal At Spectrom 27:165–173CrossRefGoogle Scholar
  26. 26.
  27. 27.
    Nishiguchi M, Toyoda M, Ishihara M, Ohtake M, Sugihara T, Katakuse I (2006) J Mass Spectrom Soc Jpn 54:1–9CrossRefGoogle Scholar
  28. 28.
    Solyom DA, Burgoyne TW, Hieftje GM (1999) J Anal At Spectrom 14:1101–1110CrossRefGoogle Scholar
  29. 29.
    NIST Standard Reference Materials Program, Gaithersburg (MD), USAGoogle Scholar
  30. 30.
    Richter S, Alonso A, Wellum R, Taylor PDP (1999) J Anal At Spectrom 14:889–891CrossRefGoogle Scholar
  31. 31.
    Kmetov V (2002) PLASMACHEM-L Archives March 2002: Item# 007782 “Uranium ratio in Merck standard?”, 2002-03-05 13:23h, https://listserv.syr.edu/scripts/wa.exe?A1=ind0203&L=PLASMACHEM-L#62, last accessed 27. August, 2012
  32. 32.
    Heumann KG, Gallus SM, Rädlinger G, Vogl J (1998) J Anal At Spectrom 13:1001–1008CrossRefGoogle Scholar
  33. 33.
    Vogl J, Pritzkow W (2010) MAPAN-J Metrol Soc Ind 25:135–164CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  • Dirk Ardelt
    • 1
    Email author
  • Aleksandra Polatajko
    • 1
  • Oliver Primm
    • 1
  • Maurice Reijnen
    • 1
  1. 1.SPECTRO Analytical Instruments GmbHKleveGermany

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