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Sampling of organophosphorus pesticides at trace levels in the atmosphere using XAD-2 adsorbent and analysis by gas chromatography coupled with nitrogen–phosphorus and ion-trap mass spectrometry detectors

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Abstract

This paper shows an analytical methodology based on solid-phase extraction by XAD-2 adsorbent and gas chromatography (GC) coupled with nitrogen–phosphorus (NPD) and ion-trap mass spectrometry detectors (ITMS) in negative chemical ionization (NCI) mode analyses for investigating organophosphorus pesticides (OPs) at trace levels (in nanograms per cubic meter) in the atmosphere: in particular, we set up a procedure for analyzing 38 OPs. For the analytical methodology linearity responses have been obtained in GC-NPD (r > 0.9982) and GC-NCI/ITMS (r > 0.9974) in a large linearity range (0.10–500 pg μL−1 in both cases) whereas the limits of detection range between 0.01 and 0.03 pg μL−1 in both the techniques with a relative standard deviation (RSD) below 9.0 in both cases. Particular attention has been devoted to investigate the effect of different solvents (n-hexane, benzene, chloroform, carbon disulfide, acetonitrile) on the OP recovery as well the breakthrough volumes have been evaluated (100 % recovery up to 4,286 L g−1). The study has also investigated the OP recoveries at different sampling flow rates (1.5 and 2.0 L min−1) for determining the optimal conditions for sample collection. Finally, the whole approach has been successfully applied to real samples collected in four different areas in the Molise region (Central Italy) during different seasons: the results show that parathion-ethyl, dimethoate, omethoate, and malathion are present in all periods at low levels (ranging between 70 and 10 ng m−3): their levels in such periods can be correlated with spraying as well atmospheric conditions favoring the dispersion/accumulation of these pollutants

Sampling system of organophosphorus pesticides in atmosphere and relative GC-NPD chromatogram

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Authors and Affiliations

  1. Facoltà di Agraria (DISTAAM), Università degli Studi del Molise, via De Sanctis, 86100, Campobasso, Italy

    Mario Vincenzo Russo, Giuseppe Cinelli & Ivan Notardonato

  2. DIPIA, INAIL ex-ISPESL, via Urbana 167, 00184, Rome, Italy

    Pasquale Avino

Authors
  1. Mario Vincenzo Russo
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  2. Pasquale Avino
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  3. Giuseppe Cinelli
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  4. Ivan Notardonato
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Correspondence to Mario Vincenzo Russo.

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Russo, M.V., Avino, P., Cinelli, G. et al. Sampling of organophosphorus pesticides at trace levels in the atmosphere using XAD-2 adsorbent and analysis by gas chromatography coupled with nitrogen–phosphorus and ion-trap mass spectrometry detectors. Anal Bioanal Chem 404, 1517–1527 (2012). https://doi.org/10.1007/s00216-012-6205-2

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  • DOI: https://doi.org/10.1007/s00216-012-6205-2

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