Skip to main content
Log in

The Indian drawings of the poet Cesare Pascarella: non-destructive analyses and conservation treatments

  • Original Paper
  • Published:
Analytical and Bioanalytical Chemistry Aims and scope Submit manuscript

Abstract

The Italian dialect poet Cesare Pascarella travelled all around the world, noting down in notebooks his keen and caustic observations, and drawing sketches that are a visual reportage of his journeys. The sketches were mounted as a random collage over acidic cardboards that were exposed to direct sunlight in his studio. Their poor state of conservation is related to the use of modern paper: chemical instability of raw materials caused acidification and strong oxidation of the support, with intense yellowing of the surfaces and brittleness of the paper. To ensure future preservation of the drawings, chemical stabilisation with simultaneous alcoholic treatment by deacidification (calcium propionate) and reduction (borane tert-butylamine complex) appeared necessary. To verify its applicability, it was indispensible to characterise the support and identify the nature of all the graphic media. The use of Raman, Infrared, X-ray fluorescence spectroscopies and scanning electron microscopy coupled with X-ray microanalysis allowed us to clear the problems related to the different penetration depth of each analytical technique and the different responses of pigments/dyes to each spectroscopy. The palette, how it varied along the journeys, the different supports used and preparations were completely identified showing a choice of colours compatible with the reduction treatment.

Top: Drawing A12. Left: before chemical stabilisation and conservation treatment. Right: after chemical deacidification/reduction and the final conservation intervention. Bottom Left: SEM image of the paper composition of drawing A19. Bottom right: Raman spectra of the paper support of drawing B6 before and after the reduction treatment. On the top, the spectra without baseline correction; on the bottom, the spectrum after reduction is compared with a standard spectrum of pure cellulose paper that shows a perfect recovery of the original structure of the paper after the chemical treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. Bioletti S, Leahy R, Fields J, Meehan B, Blau W (2009) The examination of the Book of Kells using micro-Raman spectroscopy. J Raman Spectrosc 40:1043–1049

    CAS  Google Scholar 

  2. Bicchieri M, Monti M, Piantanida G, Sodo A (2008) All that is iron ink is not always iron-gall. J Raman Spectrosc 39:1074–1078

    CAS  Google Scholar 

  3. Bicchieri M, Sodo A, Piantanida G, Coluzza C (2006) Analysis of degraded papers by non-destructive spectroscopic techniques. J Raman Spectrosc 37:1186–1192

    CAS  Google Scholar 

  4. Mansoa M, Carvalho ML (2009) Application of spectroscopic techniques for the study of paper documents: A survey. Spectrochim Acta B 64:482–490

    Google Scholar 

  5. Workman JJ Jr (2001) Infrared and Raman spectroscopy in paper and pulp analysis. Appl Spectrosc Rev 36:139–168

    CAS  Google Scholar 

  6. Hochleitner B, Desnica V, Mantler M, Schreiner M (2003) Historical pigments: a collection analyzed with X-ray diffraction analysis and X-ray fluorescence analysis in order to create a database*1. Spectrochim Acta B 58:641–649

    Google Scholar 

  7. Ferrero JL, Roldán C, Navarro E, Ardid M, Marzal M, Almirante J, Ineba P, Vergara J, Mata C (1999) Applications of the X-ray fluorescence analysis to the cultural patrimony of the Comunidad Valenciana (Spain): Painting, metal and paper. J Radioanal Nucl Ch 240:523–528

    CAS  Google Scholar 

  8. Roux S, Feugeas F, Bach M, Fagon M, Bettinger C, Mourad S, Cornet A (2008) Determination of paper filler Z-distribution by low-vacuum SEM and EDX. J Microsc 229:44–59

    CAS  Google Scholar 

  9. Goldstein J, Newbury D, Joy D, Lyman C, Echlin P, Lifshin E, Sawyer L, Michael E (2003) Scanning Electron Microscopy and X-ray Microanalysis 3 rd edn. Kluver, New York

    Google Scholar 

  10. Richards GN (1971) In: Bikales NM, Segal L (eds) Cellulose and cellulose derivatives Part V, 2nd edn. New York, Wiley

    Google Scholar 

  11. Van Loon LR, Glaus MA (1997) Review of the kinetics of alkaline degradation of cellulose in view of its relevance for safety assessment of radioactive waste repositories. J Polym Environ 5(2):97–109

    Google Scholar 

  12. Walker ERH (1976) The functional group selectivity of complex hydride reducing agents. Chem Soc Rev 5(1):23–50

    CAS  Google Scholar 

  13. Block I, Kim HK (1986) In: Needles H, Zeronian SH (eds) Historic Textile and Paper Materials. Washington DC, ACS

    Google Scholar 

  14. Andrews GC (1980) Chemoselectivity in the reduction of aldehydes and ketones with amine boranes. Tetrahedron Lett 21:679–700

    Google Scholar 

  15. Raber DJ, Guida WC, Shoenberger DC (1981) Reduction of aldehydes and ketones with tetraalkylammonium borohydrides. Tetrahedron Lett 22:5107–5110

    CAS  Google Scholar 

  16. Tang LC (1986) In: Needles H, Zeronian SH (eds) Historic Textile and Paper Materials. Washington DC, ACS

    Google Scholar 

  17. Burgess HD (1990) The stabilization of cellulosic fibres by borohydride derivatives. ICOM Committe For Conservation 2:447–452

    Google Scholar 

  18. Bicchieri M, Brusa P (1997) The bleaching of paper by reduction with borane tert-butylamine complex. Restaurator 18(1):1–11

    CAS  Google Scholar 

  19. Bicchieri M, Bella M, Sementilli F (1999) A quantitative measure of borane tert–butylamine complex effectiveness in carbonyl reduction of aged papers. Restaurator 20(1):22–29

    CAS  Google Scholar 

  20. Bicchieri M, Curini R, D’Ascenzo G, Orrù MA (2000) Characterization of oxidized and reduced papers by thermogravimetric analysis—effectiveness of reducing treatments. Qvinio 2:93–101

    Google Scholar 

  21. Capitani D, Segre AL, Pentimalli M, Bicchieri M, Munafò PF (2000) Ancient deteriorated paper: washing and restoring processes as studied by 13 C CP-MAS NMR spectroscopy. Qvinio 2:37–43

    Google Scholar 

  22. Pedneault C, Robert S, Pellerin C (1997) Bleaching with new reductive chemicals: replacement of hydrosulfite. Pulp Pap Can 98(3):51–55

    CAS  Google Scholar 

  23. Bicchieri M, Sementilli FM, Sodo A (2000) Application of seven borane complexes in paper conservation. Restaurator 21(4):213–228

    CAS  Google Scholar 

  24. Sanna C, Sodo A, Laguzzi G, Mancini G, Bicchieri M (2009) Tert-butyl amine borane complex: an unusual application of a reducing agent on model molecules of cellulose based materials. J Cult Herit 10(3):356–361

    Google Scholar 

  25. Plossi Zappalà M (1994) Il propionato di calcio nella deacidificazione e stabilizzazione della carta. Cellulosa e Carta 45:53–60

    Google Scholar 

  26. Bicchieri M, Monti M, Antonelli ML (2001) In: J. Apuente (ed) Proceedings of the 3 rd International Conference on Science and Technology for the safeguard of cultural heritage in the mediterranean basin Vol. I. Universitad de Alcalà, Alcalà

  27. Coluzza C, Bicchieri M, Monti M, Piantanida G, Sodo A (2008) Atomic force microscopy application for degradation diagnostics in library heritage. Surf Interface Anal 40(9):1248–1253

    CAS  Google Scholar 

  28. http://www.icpal.beniculturali.it/allegati/Capitolato_Speciale_Tecnico_Tipo.pdf

  29. Pace G (1999) In: Fiorani F, Di Noia R (eds) De Nittis incisore. Roma, Artemide

    Google Scholar 

  30. Bicchieri M, Storace MS (2004) In: Lo stato dell’arte 2: Conservazione e restauro, confronto di esperienze. Atti del II Congresso Nazionale dell’IGIIC, Il Prato, Saonara

    Google Scholar 

  31. Iannuccelli S, Sotgiu S, Missori M (2004) In: Lo stato dell’arte 2: Conservazione e restauro, confronto di esperienze. Atti del II Congresso Nazionale dell’IGIIC, Il Prato, Saonara

    Google Scholar 

  32. Iannuccelli S, Storace MS (2005) The conservation of Matthaeus Greuter’s Ancient Map of Italy. Beitrage zur Erhaltung von Kunst und Kulturgut Heft 1:36–42

    Google Scholar 

  33. Sotgiu S, Iannuccelli S (2006) In: Carrarini R, Casetti Brach C (ed) Libri e Carte. Restauro e analisi diagnostiche, Gangemi, Roma

    Google Scholar 

  34. Sotgiu S, Iannuccelli S (2010) In: XXI Secolo-L’universo fisico. Istituto della Enciclopedia Italiana Treccani, Roma

    Google Scholar 

  35. Pinzari F, Zotti M, De Mico A, Calvini P (2010) Biodegradation of inorganic components in paper documents: formation of calcium oxalate crystals as a consequence of Aspergillus terreus Thom growth. Int Biodeter Biodegr 64:499–505

    CAS  Google Scholar 

  36. McNamara CJ, Konkol N, Mitchell R (2010) In: Mitchell R, Gu J-D (eds) Environmental Microbiology, 2nd edn. Wiley, Hoboken, NJ

    Google Scholar 

  37. Reich S, Thomsen C (2004) Raman spectroscopy of graphite. Phil Trans R Soc Lond A 362:2271–2288

    CAS  Google Scholar 

  38. Iannuccelli S, Sotgiu S (2010) A new methodology for wet conservation treatments of graphic art on paper with a rigid polysaccharide gel of Gellan gum. Book and Paper Group Annual 29:25–39

    Google Scholar 

Download references

Acknowledgements

We would like to acknowledge Dr. Marco Guardo, Director of the Biblioteca Corsiniana, Accademia Nazionale dei Lincei, Rome, for cooperation and for allowing us to present the images of Pascarella’s sketches.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Marina Bicchieri.

Additional information

Published in the special issue Analytical Techniques in Art, Archaeology and Conservation Science with guest editor Oliver Hahn.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bicchieri, M., Monti, M., Piantanida, G. et al. The Indian drawings of the poet Cesare Pascarella: non-destructive analyses and conservation treatments. Anal Bioanal Chem 402, 1517–1528 (2012). https://doi.org/10.1007/s00216-011-5229-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00216-011-5229-3

Keywords

Navigation