Analytical and Bioanalytical Chemistry

, Volume 397, Issue 1, pp 395–399 | Cite as

Determination of vanadium(V) in the particulate matter of emissions and working areas by sequential dissolution and solid-phase extraction

  • M. Sturini
  • F. Maraschi
  • L. Cucca
  • G. Spini
  • G. Talamini
  • A. Profumo
Technical Note

Abstract

A method based on selective sequential dissolutions is proposed to determine total vanadium(V) in particulate matter of emissions and working areas at concentrations 1,000 times lower than the threshold limit of 0.05 mg m−3. Separation and preconcentration of vanadium(V) has been achieved by solid-phase extraction on Chelex 100 resin. Possible influence of the matrix has been investigated for two standard reference materials (SRMs), NIST SRM 1648 and BCR-038, before and after spiking, with vanadium(V) recovery in the range 97–103%.

Keywords

Vanadium(V) Emissions Sequential dissolution Solid-phase extraction 

Notes

Acknowledgement

This work was principally supported by Fondi Ateneo per la Ricerca of Pavia University.

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Copyright information

© Springer-Verlag 2009

Authors and Affiliations

  • M. Sturini
    • 1
  • F. Maraschi
    • 1
  • L. Cucca
    • 1
  • G. Spini
    • 1
  • G. Talamini
    • 1
  • A. Profumo
    • 1
  1. 1.Department of General ChemistryUniversity of PaviaPaviaItaly

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