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Neutron diffraction characterization of Japanese artworks of Tokugawa age

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Abstract

Neutron time-of-flight diffraction technique has been used to characterize some Japanese historical artifacts. With this method, metal samples can be analyzed in their bulk properties without need of sampling. Results shown here were obtained at the Italian Neutron Experimental Station (INES@ISIS) located at the pulsed neutron source ISIS (UK). The parallel use of a scanning electron microscope equipped with an energy-dispersive X-ray fluorescence device (SEM-EDX) permitted a full quantitative characterization of the investigated samples, namely four hand-guards (Tsubas) of Japanese swords attributed to the Tokugawa age. In particular, we were able to obtain, in a totally non-invasive non-destructive way, a full quantitative phase characterization of the samples, a detailed Bragg peak broadening analysis, and a quantitative texture determination. These results, complemented with those obtained via the traditional analysis method of SEM-EDX, allowed a full characterization of both the bulk and the surface of the artifacts.

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Acknowledgments

The authors acknowledge fruitful discussions with W. A. Kockelmann and E. Godfrey (ISIS, UK) and the cooperative attitude of staff at the Centro di Microscopia Elettronica, CNR-Firenze. The Cooperation Agreement No. 06/20018 between CNR and STFC, concerning collaboration in scientific research at the spallation neutron source ISIS (UK), is gratefully acknowledged.

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Authors and Affiliations

  1. Istituto dei Sistemi Complessi, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019, Sesto Fiorentino, FI, Italy

    F. Grazzi, L. Bartoli & M. Zoppi

  2. Istituto di Fisica Applicata “Nello Carrara”, Consiglio Nazionale delle Ricerche, Via Madonna del Piano 10, 50019, Sesto Fiorentino, FI, Italy

    L. Bartoli

  3. Sezione Giapponese, Museo Stibbert, Via F. Stibbert 26, 50122, Florence, Italy

    F. Civita

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  1. F. Grazzi
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  2. L. Bartoli
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  3. F. Civita
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  4. M. Zoppi
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Correspondence to F. Grazzi.

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Grazzi, F., Bartoli, L., Civita, F. et al. Neutron diffraction characterization of Japanese artworks of Tokugawa age. Anal Bioanal Chem 395, 1961–1968 (2009). https://doi.org/10.1007/s00216-009-3048-6

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  • DOI: https://doi.org/10.1007/s00216-009-3048-6

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