Skip to main content

Interfacial behavior of sulforhodamine 101 at the polarized water/1,2-dichloroethane interface studied by spectroelectrochemical techniques

Analytical and Bioanalytical Chemistry volume 386, pages 633–638 (2006)Cite this article

Abstract

The transfer mechanism of an amphoteric rhodamine, sulforhodamine 101 (SR101), across the polarized water/1,2-dichloroethane (DCE) interface was investigated using cyclic voltammetry, differential voltfluorometry and potential-modulated fluorescence (PMF) spectroscopy. The voltammetric response for the ion transfer of SR101 monoanion from water to DCE was observed as the diffusion-controlled transfer process. An unusual voltammetric response was found at 0.15 V more negative than the formal transfer potential of SR101− \({\left( {\Delta ^{{\text{W}}}_{{\text{O}}} \phi ^\circ \prime } \right)}\) in the cyclic voltammogram and voltfluorogram. The frequency dependence of the PMF responses confirmed the presence of the adsorption processes at negative potentials. In addition, a further transient adsorption step was uncovered at \(\Delta ^{{\text{W}}}_{{\text{O}}} \phi ^\circ \prime .\)The interfacial mechanism of SR101 is discussed by comparing the results obtained from each technique.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

43,34 €

Price includes VAT (Finland)
Tax calculation will be finalised during checkout.

Fig. 1
Fig. 2
Fig. 3a, b
Fig. 4
Fig. 5
Fig. 6

References

  1. Watarai H, Teramae N, Sawada S (eds) (2005) Interfacial nanochemistry. Kluwer Academic/Plenum, New York

    Google Scholar 

  2. Volkov AG, (ed) (2003) Interfacial catalysis. Marcel Dekker, New York

    Google Scholar 

  3. Corn RM, Higgins DA (1994) Chem Rev 94:107

    Article  CAS  Google Scholar 

  4. Conboy JC, Richmond GL (1995) Electrochim Acta 40:2881

    Article  CAS  Google Scholar 

  5. Piron A, Brevet P-F, Girault HH (2000) J Electroanal Chem 483:29

    Article  CAS  Google Scholar 

  6. Nagatani H, Piron A, Brevet P-F, Fermín DJ, Girault HH (2002) Langmuir 18:6647

    Article  CAS  Google Scholar 

  7. Fermín DJ, Ding Z, Brevet PF, Girault HH (1998) J Electroanal Chem 447:125

    Article  Google Scholar 

  8. Nagatani H, Iglesias RA, Fermín DJ, Brevet PF, Girault HH (2000) J Phys Chem B 104:6869

    Article  CAS  Google Scholar 

  9. Nishi N, Izawa K, Yamamoto M, Kakiuchi T (2001) J Phys Chem B 105:8162

    Article  CAS  Google Scholar 

  10. Nakatani K, Nagatani H, Fermín DJ, Girault HH (2002) J Electroanal Chem 518:1

    Article  CAS  Google Scholar 

  11. Nagatani H, Fermín DJ, Girault HH (2001) J Phys Chem B 105:9463

    Article  CAS  Google Scholar 

  12. Nagatani H, Ozeki T, Osakai T (2006) J Electroanal Chem 588:99

    Article  CAS  Google Scholar 

  13. Watarai H, Funaki F (1996) Langmuir 12:6717

    Article  CAS  Google Scholar 

  14. Uchida T, Yamaguchi A, Ina T, Teramae N (2000) J Phys Chem B 104:12091

    Article  CAS  Google Scholar 

  15. Ishizaka S, Kitamura N (2001) Bull Chem Soc Jpn 74:1983

    Article  CAS  Google Scholar 

  16. Tsukahara S, Yamada Y, Watarai H (2000) Langmuir 16:6787

    Article  CAS  Google Scholar 

  17. Ishizaka S, Habuchi S, Kim HB, Kitamura N (1999) Anal Chem 71:3382

    Article  CAS  Google Scholar 

  18. Ishizaka S, Nakatani K, Habuchi S, Kitamura N (1999) Anal Chem 71:419

    Article  CAS  Google Scholar 

  19. Ishizaka S, Kim HB, Kitamura N (2001) Anal Chem 73:2421

    Article  CAS  Google Scholar 

  20. Sun Z, Wang E (1989) Chin Sci Bull 34:651

    CAS  Google Scholar 

  21. Sun Z, Wang E (1988) Electrochim Acta 33:603

    Article  CAS  Google Scholar 

  22. Kakiuchi T, Teranishi Y (2001) Electrochem Commun 3:168

    Article  CAS  Google Scholar 

  23. Girault HH, Schiffrin DJ (1989) In: Bard AJ (ed) Electroanalytical chemistry, vol 15. Marcel Dekker, New York, pp. 1–141

    Google Scholar 

  24. Kakiuchi T, Takasu Y (1994) Anal Chem 66:1853

    Article  CAS  Google Scholar 

  25. Ding ZF, Wellington RG, Brevet PF, Girault HH (1997) J Electroanal Chem 420:35

    Article  CAS  Google Scholar 

  26. Bard AJ, Faulkner LR (2001) Electrochemical methods. Wiley, New York

    Google Scholar 

  27. Ghasemi J, Niazi A, Kubista M (2005) Spectrochim Acta Part A 62:649

    Article  Google Scholar 

  28. Ilich P, Mishra PK, Macura S, Burghardt TP (1996) Spectrochim Acta Part A 52:1323

    Article  Google Scholar 

  29. Lopez Arbeloa I, Ruiz Ojeda P (1982) Chem Phys Lett 87:556

    Article  CAS  Google Scholar 

  30. Nagatani H, Samec Z, Brevet P-F, Fermín DJ, Girault HH (2003) J Phys Chem B 107:786

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was partly supported by a Grant-in-Aid for Scientific Research of Priority Areas (No. 13129202) from the Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT). H.N. gratefully acknowledges a Grant-in-Aid for Young Scientists (B) (No. 17750070) from MEXT. The authors are also indebted to Dr. Toshiyuki Osakai of Kobe University for valuable discussions.

Author information

Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, Bunkyo, Nagasaki, 852-8521, Japan

    Hirohisa Nagatani

  2. Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, 305-8571, Japan

    Shingo Suzuki & Kiyoharu Nakatani

  3. Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, 3012, Bern, Switzerland

    David J. Fermín

  4. Laboratoire d’Electrochimie Physique et Analytique, Institut de Chimie Molécularie et Bioligique, Ecole Polytechnique Fédérale de Lausanne, 1015, Lausanne, Switzerland

    Hubert H. Girault

Authors
  1. Hirohisa Nagatani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shingo Suzuki
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. David J. Fermín
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hubert H. Girault
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Kiyoharu Nakatani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Hirohisa Nagatani or Kiyoharu Nakatani.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Nagatani, H., Suzuki, S., Fermín, D.J. et al. Interfacial behavior of sulforhodamine 101 at the polarized water/1,2-dichloroethane interface studied by spectroelectrochemical techniques. Anal Bioanal Chem 386, 633–638 (2006). https://doi.org/10.1007/s00216-006-0497-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00216-006-0497-z

Keywords

  • Sulforhodamine 101
  • Adsorption
  • Liquid/liquid interface
  • Potential modulated fluorescence