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Voltammetry of lead cations on a new type of silver composite electrode in the presence of other cations

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Abstract

A new type of silver composite electrode was examined, prepared from silver, graphite powder, and methacrylate resin. The effects of the presence of various cations (cadmium, copper, bismuth, thallium), anions (chlorides), surface-active substances (Triton X-100), and oxygen on the anodic-stripping voltammetric determination of lead were studied. It was found that the effect of underpotential deposition at the composite electrode differs from that produced at a metallic silver electrode, mainly at low concentrations of the deposited metal. The use of this type of silver composite electrode in differential pulse anodic-stripping voltammetry enables direct determination of lead in natural water samples without elimination of surface-active substances (LOD about 3 μg L−1).

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References

  1. Tallman DE, Petersen SL (1990) Electroanalysis 2:499–510

    CAS  Google Scholar 

  2. Petersen SL, Tallman DE (1988) Anal Chem 60:82–86

    CAS  Google Scholar 

  3. Kolb DM (1978) In: Gerischer H, Tobias CW (eds) Advances in electrochemistry and electrochemical engineering, vol 11. Wiley, New York, pp 125–271

  4. Navrátil T, Kopanica M (2002) Chem Listy 96:111–116

    Google Scholar 

  5. Navrátil T, Kopanica M (2002) Crit Rev Anal Chem 32:153–166

    Google Scholar 

  6. Navrátil T, Kopanica M, Krista J (2003) Chem Anal (Warsaw) 48:265–272

    Google Scholar 

  7. Kopanica M, Navrátil T (2001) In: Barek J, Drašar P (eds) Abstracts of the US-CZ workshop on electrochemical sensors, Prague, 19–22 June 2001. Czech Chemical Society, Prague, p 32

  8. Brand M, Ashkenazi I, Kirowa-Eisner E (1997) Anal Chem 69:4660–4664

    Article  CAS  Google Scholar 

  9. Bonfil Y, Brand M, Kirowa-Eisner E (2000) J Heyrovský memorial symposium on advances in polarography and related methods. J Heyrovský Institute of Physical Chemistry and Czech Chemical Society, Prague, p 25

  10. Ishiyama T, Tanaka T (1996) Anal Chem 68:3789–3792

    Article  CAS  Google Scholar 

  11. Miva T, Nishimura Y, Mizuike A (1982) Anal Chim Acta 140:59–64

    Article  Google Scholar 

  12. Shain I, Perone SP (1961) Anal Chem 33:325–329

    CAS  Google Scholar 

  13. Yosypchuk B, Novotný L (2002) Electroanalysis 14:1733–1738

    Article  CAS  Google Scholar 

  14. Novotný L, Yosypchuk B (2000) Chem Listy 94:1118–1120

    Google Scholar 

  15. Shen H, Mark JE, Seliskar CJ, Mark HB Jr, Heineman WR (1997) J Solid State Electrochem 1:241–247

    Article  CAS  Google Scholar 

  16. Kolb DM, Przasnyski M, Grischer H (1974) J Electroanal Chem 54:25–38

    CAS  Google Scholar 

  17. Zeng X, Bruckenstein S (1999) J Electroanal Chem 461:131–142

    Article  CAS  Google Scholar 

  18. Zeng X, Bruckenstein S (1999) J Electroanal Chem 461:143–153

    Article  CAS  Google Scholar 

  19. Zeng X, Bruckenstein S (1999) J Electrochem Soc 146:2549–2554

    Article  CAS  Google Scholar 

  20. Zeng X, Bruckenstein S (1999) J Electrochem Soc 146:2555–2561

    Article  CAS  Google Scholar 

  21. Šebková S, Navrátil T, Kopanica M (2003) Anal Lett 36:2767–2782

    Article  Google Scholar 

  22. Šebková S (2003) Chem Listy 97:201–205

    Google Scholar 

  23. Šebková S, Navrátil T, Kopanica M (2004) Anal Lett 37:613–635

    Google Scholar 

  24. Perone SP (1963) Anal Chem 35:2091–2094

    CAS  Google Scholar 

  25. Brainina K , Zakharchuk NF, Synkova DP and Yudelevich IG (1972) J Electroanal Chem 35:165–176

    Article  CAS  Google Scholar 

  26. Morcos I (1975) J Electroanal Chem 66:250–257

    Article  CAS  Google Scholar 

  27. Vassos BH, Mark HB Jr (1967) J Electroanal Chem 13:1–9

    Article  CAS  Google Scholar 

  28. Schmidt E, Gygax HR, Böhlen P (1966) Helv Chim Acta 49:733

    CAS  Google Scholar 

  29. Bonfil Y, Kirowa-Eisner E (2002) Anal Chim Acta 457:285–296

    Article  CAS  Google Scholar 

  30. Meloun M, Militký J, Forina M (1992) Chemometrics for analytical chemistry, vol 1: PC-aided statistical data analysis, vol 2: PC-aided regression and related methods. Ellis Horwood, Chichester, pp 1–175

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Acknowledgements

The sponsorship by the contract No. 101/02/U111/CZ is gratefully acknowledged.

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Authors and Affiliations

  1. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23, Prague, Czech Republic

    Tomáš Navrátil & Světlana Šebková

  2. Department of Analytical Chemistry, Faculty of Science, UNESCO Trace Element Satellite Center at Charles University in Prague, Albertov 2030, 128 43, Prague, Czech Republic

    Miloslav Kopanica

Authors
  1. Tomáš Navrátil
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  2. Světlana Šebková
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  3. Miloslav Kopanica
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Correspondence to Tomáš Navrátil.

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Navrátil, T., Šebková, S. & Kopanica, M. Voltammetry of lead cations on a new type of silver composite electrode in the presence of other cations. Anal Bioanal Chem 379, 294–301 (2004). https://doi.org/10.1007/s00216-004-2517-1

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  • DOI: https://doi.org/10.1007/s00216-004-2517-1

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