Abstract
Laser ablation is considered a promising alternative to conventional mask fabrication methods for flexible sensors. For the efficient and high-quality patterning of circuit and electrode geometries, numerous process parameters must be optimized to obtain the necessary laser fluence and pulse overlap that allow for precise, clean cuts in thin, heat-sensitive materials. This study investigates the ability to achieve target cut widths and depths during the pulsed UV laser ablation of NiCr films at various laser powers (0.2 to 1 W), laser scan speeds (0.1 to 0.6 m/s), and pulse frequencies (30 to 100 kHz). Significant variation is observed in the depth, width, and quality of ablated microchannels formed at similar laser fluence and pulse overlap, with the typical fluence-based model giving poor predictions (R2 = 0.37 to 0.57). To address this, an improved fluence-based model that incorporates the effect of a moving laser source using a physics-based approach is proposed (R2 = 0.62 to 0.82). This model is then used to select process parameters for the fabrication of electrically insulated features (> 5 µm cut depth) with the smallest channel width possible (13.7 µm). This process parameter selection approach has the ability to shorten development times and facilitate the fabrication of custom flexible sensors.
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Abbreviations
- \({P}_{avg}\) :
-
Laser average power, W
- \({P}_{peak}\) :
-
Laser peak power, W
- \(V\) :
-
Scanning speed, m/s
- \(f\) :
-
Frequency, kHz
- \(\tau\) :
-
Pulse width, ns
- \(\psi\) :
-
Pulse overlap factor, -
- Lp :
-
Distance between adjacent pulses, µm
- D 0 :
-
Laser beam diameter, µm
- \(\omega\) :
-
Laser beam radius, µm
- d :
-
Ablation depth, µm
- α :
-
Absorptivity, µm−1
- \(F\) :
-
Applied laser fluence, J/mm2
- \({F}_{th}\) :
-
Threshold laser fluence, J/mm2
- \(W\) :
-
Ablation width, µm
- \(n\) :
-
Number of passes,
References
Brown MS, Arnold CB (2010) Fundamentals of laser-material interaction and application to multiscale surface modification, Springer Series in Materials. Science 135:91–120. https://doi.org/10.1007/978-3-642-10523-4_4/COVER/
Kongsuwan P, Brandal G, Yao YL (2015) Laser induced porosity and crystallinity modification of a bioactive glass coating on titanium substrates. J Manuf Sci Eng 137(3):031004. https://doi.org/10.1115/1.4029566/376332
Esakkimuthu M, BalakrishnapillaiSuseela S, Sankararajan R, Gupta A, Rana G (2017) Laser patterning of thin film copper and ITO on flexible substrates for terahertz antenna applications. JLMN-J Laser Micro/Nanoengineering 12:313–320. https://doi.org/10.2961/jlmn.2017.03.0023
Arshak K, Morris D, Arshak A, Korostynska O (2006) Development of high sensitivity oxide based strain gauges and pressure sensors. J Mater Sci: Mater Electron 17:767–778. https://doi.org/10.1007/S10854-006-0013-4
Dankoco MD, Bènevent E, Bergeret E, Gallais L, Bendahan M (2014) Temperature sensor on flexible substrate patterned by laser ablation, Conference Proceedings - 10th International Conference on Advanced Semiconductor Devices and Microsystems. (pp. 1–4). IEEE. https://doi.org/10.1109/ASDAM.2014.6998634
Chen Q, Tong T, Longtin JP, Tankiewicz S, Sampath S, Gambino RJ (2004) Novel sensor fabrication using direct-write thermal spray and precision laser micromachining. J Manuf Sci Eng 126:830–836. https://doi.org/10.1115/1.1813481
Lin Z, Hong M (2021) Femtosecond laser precision engineering: from micron, submicron, to nanoscale. Ultrafast Sci 2021:1–22. https://doi.org/10.34133/2021/9783514
Liu Z, Wu B, Kang Z, Yang Z (2019) Microhole drilling by high-intensity focused ultrasound-assisted water-confined laser micromachining. J Manuf Sci Eng 141(9):091003. https://doi.org/10.1115/1.4043979/955954
Manzoli A, De Almeida GFB, Filho JA, Mattoso LHC, Riul A, Mendonca CR, Correa DS (2015) Femtosecond laser ablation of gold interdigitated electrodes for electronic tongues. Opt Laser Technol 69:148–153. https://doi.org/10.1016/J.OPTLASTEC.2014.12.026
Kim D, Jeong S, Moon J, Han S, Chung J (2007) Organic thin film transistors with ink-jet printed metal nanoparticle electrodes of a reduced channel length by laser ablation. Appl Phys Lett. 91:071114. https://doi.org/10.1063/1.2771059
Binh Nam V, Shin J, Yoon Y, ThiGiang T, Kwon J, Suh YD, Yeo J, Hong S, Hwan Ko S, Lee D, Nam VB, Giang TT, Lee D, Shin J, Yoon Y, Kwon J, Suh YD, Ko SH, Yeo J, Hong S (2019) Highly stable Ni-based flexible transparent conducting panels fabricated by laser digital patterning. Adv Funct Mater. 29:1806895. https://doi.org/10.1002/ADFM.201806895
Prakash S, Kumar S (2015) Fabrication of microchannels: a review. Proc Inst Mech Eng B J Eng Manuf 229:1273–1288. https://doi.org/10.1177/0954405414535581/ASSET/IMAGES/LARGE/10.1177_0954405414535581-FIG5.JPEG
Brandi F, Burdet N, Carzino R, Diaspro A (2010) Very large spot size effect in nanosecond laser drilling efficiency of silicon. Opt Express 18:23488. https://doi.org/10.1364/OE.18.023488
Simon P, Ihlemann J (1996) Machining of submicron structures on metals and semiconductors by ultrashort UV-laser pulses. Appl Phys A 63:505–508. https://doi.org/10.1007/BF01571681
Mao N, Enrique PD, Chen AIH, Zhou NY, Peng P (2022) Dynamic response and failure mechanisms of a laser-fabricated flexible thin film strain gauge. Sens Actuators A Phys. 342:113655. https://doi.org/10.1016/J.SNA.2022.113655
Zhang D, Guan L (2014) Laser Ablation. In: comprehensive materials processing, 4, Elsevier Ltd, pp. 125–169. https://doi.org/10.1016/B978-0-08-096532-1.00406-4
Garrison BJ, Itina TE, Zhigilei LV (2003) Limit of overheating and the threshold behavior in laser ablation. Phys Rev E. 68:041501. https://doi.org/10.1103/PhysRevE.68.041501
Follstaedt M, Baglin JEE, Appleton BR, Celler GK (2013) Laser and electron beam interactions with solids. MRS Bulletin 1982 7(1):4–5. https://doi.org/10.1557/S0883769400049460
Brygo F, Dutouquet C, Le Guern F, Oltra R, Semerok A, Weulersse JM (2006) Laser fluence, repetition rate and pulse duration effects on paint ablation. Appl Surf Sci 252:2131–2138. https://doi.org/10.1016/j.apsusc.2005.02.143
Zhigilei LV, Lin Z, Ivanov DS (2009) Atomistic modeling of short pulse laser ablation of metals: connections between melting, spallation, and phase explosion. J Phys Chem C 113:11892–11906. https://doi.org/10.1021/JP902294M/ASSET/IMAGES/LARGE/JP-2009-02294M_0008.JPEG
Lutey AHA (2013) An improved model for nanosecond pulsed laser ablation of metals. J Appl Phys 114(8). https://doi.org/10.1063/1.4818513
Anjum A, Shaikh AA, Tiwari N (2022) Experimental investigations of channel profile and surface roughness on PMMA substrate for microfluidic devices with mathematical modelling. Optik 261:169154. https://doi.org/10.1016/j.ijleo.2022.169154
Anjum A, Shaikh A (2023) Experimental and analytical modeling for channel profile using CO2 laser considering Gaussian beam distribution. J Eng Res 11:100035. https://doi.org/10.1016/j.jer.2023.100035
Shaikh AA, Ali A, Anjum A (2022) Acta Technica Napocensis Comparative assessment of experimental and numerical simulation of ablation depth in PMMA multipass laser cutting. Acta Technica Napocensis - Ser: Appl Math, Mech, Eng 65:1303–1310
Anjum A, Shaikh AA, Tiwari N (2023) Comparative assessment of the developed algorithm with the soft computing algorithm for the laser machined depth. Infrared Phys Technol 129:104545. https://doi.org/10.1016/j.infrared.2023.104545
Anjum A, Shaikh AA, Tiwari N (2023) Experimental investigations and modeling for multi-pass laser micro-milling by soft computing-physics informed machine learning on PMMA sheet using CO2 laser. Opt Laser Technol 158:108922. https://doi.org/10.1016/j.optlastec.2022.108922
Di Niso F, Gaudiuso C, Sibillano T, Mezzapesa FP, Ancona A, Lugarà PM (2014) Role of heat accumulation on the incubation effect in multi-shot laser ablation of stainless steel at high repetition rates. Opt Express 22:12200. https://doi.org/10.1364/oe.22.012200
Ancona A, Tünnermann A, Röser F, Limpert J, Rademaker K, Nolte S (2008) High speed laser drilling of metals using a high repetition rate, high average power ultrafast fiber CPA system. Opt Express 16:8958–8968. https://doi.org/10.1364/OE.16.008958
Byskov-Nielsen J, Savolainen JM, Christensen MS, Balling P (2010) Ultra-short pulse laser ablation of metals: threshold fluence, incubation coefficient and ablation rates. Appl Phys A 101:97–101. https://doi.org/10.1007/S00339-010-5766-1
Liu JM (1982) Simple technique for measurements of pulsed Gaussian-beam spot sizes. Optics letters 7(5):196–198. https://doi.org/10.1364/OL.7.000196
von der Heide C, Grein M, Bräuer G, Dietzel A (2020) Methodology of selective metallic thin film ablation from susceptible polymer substrate using pulsed femtosecond laser. Opt Express 28:33413. https://doi.org/10.1364/OE.391084
Anisimov SI (1996) Vaporization of metal absorbing laser radiation. In: 30 Years of The Landau Institute—Selected Papers. World Sci 14–15. https://doi.org/10.1142/9789814317344_0002
Harimkar SP, Samant AN, Dahotre NB (2007) Temporally evolved recoil pressure driven melt infiltration during laser surface modifications of porous alumina ceramic. Aip Scitation Org 101:54911. https://doi.org/10.1063/1.2710288
Brannon JH, Lankard JR, Baise AI, Burns F, Kaufman J (1998) Excimer laser etching of polyimide. J Appl Phys 58:2036. https://doi.org/10.1063/1.336012
Aguilar CA, Lu Y, Mao S, Chen S (2005) Direct micro-patterning of biodegradable polymers using ultraviolet and femtosecond lasers. Biomaterials 26:7642–7649. https://doi.org/10.1016/j.biomaterials.2005.04.053
Srinivasan R (1986) Ablation of polymers and biological tissue by ultraviolet lasers. Science 234(4776):559–565. https://doi.org/10.1126/science.3764428
Grigoropoulos CP (1997) Lasers, optics, and thermal considerations in ablation experiments. In: Experimental methods in the physical sciences. 30:173–223. Academic Press. https://doi.org/10.1016/S0076-695X(08)60396-8
Funding
This work was supported with funding from the Discovery and Alliance grants of the Natural Sciences and Engineering Research Council of Canada (NSERC), and Forcen Inc., and was performed at the Centre for Advanced Materials Joining (CAMJ) at the University of Waterloo.
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Ningyue Mao: data curation; investigation; formal analysis; writing, original draft; and software. Pablo D. Enrique: project administration; formal analysis; writing, review and editing; and software. Peng Peng: funding acquisition; resources; supervision; writing, review and editing; and project administration.
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Mao, N., Enrique, P.D. & Peng, P. Pulsed laser ablation of electrically insulated features in thin NiCr films. Int J Adv Manuf Technol 128, 5167–5177 (2023). https://doi.org/10.1007/s00170-023-12271-7
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DOI: https://doi.org/10.1007/s00170-023-12271-7