Abstract
In recent years, nanocomposite coatings have become relevant in different metal-mechanical processes related to the increase of the tribomechanical properties. Therefore, this research is focused on improving mechanical behavior and wear resistance of TiSiCN nanocomposite coating with different power applied on the silicon nitride (Si3N4) target by means of magnetron sputtering r.f. technique and synthesized on HSS (high-speed steel) and oriented silicon (100) substrates. The response of the nanocomposite coatings to power variation was analyzed by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), and instrumented nanoindentation. Ball-on-disc and scratch tests were used for tribological characterization. The XRD study determined an FCC structure with a peak of maximum intensity in the plane (200). XPS analysis showed chemical energies in the bonds and stoichiometry. By means of the AFM technique, the tendency to decrease the roughness and grain size was detected, with the increase of the power for the coatings obtained at 500 W. From the nanoindentation test, it was possible to stablish increases in mechanical properties as the applied power increases; the best performance was obtained for coating with a 500-W power, where the hardness and elastic modulus were 32 GPa and 301 GPa, respectively. The friction coefficient in dry environment decreased with increasing applied power (500 W, 0.31), and the critical load produced by adhesive wear was determined for the TiSiCN nanocomposite coatings for the different applied powers, showing the highest critical load in the coating with 500 W (62.42 N). Finally, the cutting tests with AISI 1020 steel (workpiece) to assess wear as a function of the applied power. A comparison of the tribological properties revealed a decrease of flank wear (approximately 37%) for ASSAB 17 steel burins coated with TiSiCN nanocomposite coatings with 550 W, when compared to uncoated ASSAB 17 steel burins. These results open a great industrial potential in anti-wear applications.
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References
Martin PM (2009) Handbook of deposition technologies for films and coatings: science, applications and technology, 3rd edn. https://public.ebookcentral.proquest.com/choice/publicfullrecord.aspx?p=566654
Baptista A, Silva FJG, Porteiro J, Míguez JL, Pinto G, Fernandes L (2018) On the physical vapour deposition (PVD): evolution of magnetron sputtering processes for industrial applications. Procedia Manuf 17:746–757. https://doi.org/10.1016/j.promfg.2018.10.125
Caicedo JC, Cabrer G, Aperador W, Caicedo HH, Mejia A (2012) Determination of the best behavior among AISI D3 steel, 304 stainless steel and CrN/AlN coatings under erosive-corrosive effect. Vacuum 86:1886–1894
Bobzin K (2017) High-performance coatings for cutting tools. CIRP J Manuf Sci Technol 18:1–9. https://doi.org/10.1016/j.cirpj.2016.11.004
Caicedo JC, Guerrero A, Aperador W (2017) Physical properties evolution on ternary and quaternary carbonitride coatings. Vacuum. 143:217–224
Vepřek S, Reiprich S (1995) A concept for the design of novel superhard coatings. Thin Solid Films 268:64–71. https://doi.org/10.1016/0040-6090(95)06695-0
Patscheider J (2003) Nanocomposite hard coatings for wear protection. MRS Bull 28:180–183. https://doi.org/10.1557/mrs2003.59
Vepřek S (1999) The search for novel, superhard materials. J Vac Sci Technol 17:2401–2420. https://doi.org/10.1116/1.581977
Voevodin AA, Zabinski JS (2005) Nanocomposite and nanostructured tribological materials for space applications. Compos Sci Technol 65:741–748. https://doi.org/10.1016/j.compscitech.2004.10.008
Rafaja D, Poklad A, Klemm V, Schreiber G, Heger D, Šíma M, Dopita M (2006) Some consequences of the partial crystallographic coherence between nanocrystalline domains in Ti–Al–N and Ti–Al–Si–N coatings. Thin Solid Films 514:240–249. https://doi.org/10.1016/j.tsf.2006.02.092
Oláh N, Fogarassy Z, Sulyok A, Szívós J, Csanádi T, Balázsi K (2016) Ceramic TiC/a:C protective nanocomposite coatings: structure and composition versus mechanical properties and tribology. Ceram Int 42:12215–12220. https://doi.org/10.1016/j.ceramint.2016.04.164
Marchin N, Ashrafizadeh F (2021) Effect of carbon addition on tribological performance of TiSiN coatings produced by cathodic arc physical vapour deposition. Surf Coat Technol 407:126781. https://doi.org/10.1016/j.surfcoat.2020.126781
Johnson LJS, Rogström L, Johansson MP, Odén M, Hultman L (2010) Microstructure evolution and age hardening in (Ti,Si)(C,N) thin films deposited by cathodic arc evaporation. Thin Solid Films 519:1397–1403. https://doi.org/10.1016/j.tsf.2010.08.150
Lin J, Wei R, Bitsis DC, Lee PM (2016) Development and evaluation of low friction TiSiCN nanocomposite coatings for piston ring applications. Surf Coat Technol 298:121–131. https://doi.org/10.1016/j.surfcoat.2016.04.061
Thangavel E, Lee S, Nam K-S, Kim J-K, Kim D-G (2013) Synthesis and characterization of Ti–Si–C–N nanocomposite coatings prepared by a filtered vacuum arc method. Appl Surf Sci 265:60–65. https://doi.org/10.1016/j.apsusc.2012.10.107
Greczynski G, Hultman L (2020) X-ray photoelectron spectroscopy: towards reliable binding energy referencing. Prog Mater Sci 107:100591
ASTM (2015) E1523-15. Standard guide to charge control and charge referencing techniques in X-ray photoelectron spectroscopy. West Conshohocken (PA), ASTM International www.astm.org
ISO 19318:2004. Surface chemical analysis – reporting of methods used for charge control and charge correction
ISO 15472:2010. Surface chemical analysis – X-ray photoelectron spectrometers – Calibration of energy scales (ISO, Geneva, 2010)
Seah MP (2001) Summary of ISO/TC 201 Standard: VII ISO 15472: 2001—surface chemical analysis—X-ray photoelectron spectrometers—calibration of energy scales. Surf Interface Anal 31:721–723
ISO 16243:2011s Surface chemical analysis — recording and reporting data in X-ray photoelectron spectroscopy (XPS)
ISO 18516:2019 Surface chemical analysis Determination of lateral resolution and sharpness in beam-based methods with a range from nanometres to micrometres and its implementation for imaging laboratory X-ray photoelectron spectrometers (XPS)
Greczynski G, Hultman L (2021) The same chemical state of carbon gives rise to two peaks in X-ray photoelectron spectroscopy. Sci Rep 11:11195
Evans S (1973) Work function measurements by X-Pe spectroscopy, and their relevance to the calibration of X-Pe spectra. Chem Phys Lett 23:134–138
ASTM International (2017) Standard Test method for wear testing with a pin-on-disk apparatus G99-17. Annu B ASTM Stand 05:1–6. https://doi.org/10.1520/G0099-17.Copyright
Method ST (2003) Scratch hardness of materials using a diamond stylus. Current. 14:1–7. https://doi.org/10.1520/G0171-03R17.2
Nledengvist P, Hogmark S (1997) Experiences from scratch testing of tribological PVD coatings. Tribol Int 30:507–516
Lin Y-C, Hsu S-Y, Song R-W, Lo W-L, Lai Y-T, Tsai S-Y, Duh J-G (2020) Improving the hardness of high entropy nitride (Cr0.35Al0.25Nb0.12Si0.08V0.20) N coatings via tuning substrate temperature and bias for anti-wear applications. Surf Coat Technol 403:126417. https://doi.org/10.1016/j.surfcoat.2020.126417
Anandh Jesuraj S, Kuppusami P, Ajith Kumar S, Panda P, Udaiyappan S (2019) Investigation on the effect of deposition temperature on structural and nanomechanical properties of electron beam evaporated lanthanum zirconate coatings. Mater Chem Phys 236:121789. https://doi.org/10.1016/j.matchemphys.2019.121789
Arunkumar P, Ramaseshan R, Dash S, Basu J, Ravindran TR, Balakumar S, Babu KS (2014) Texturing of pure and doped CeO2 thin films by EBPVD through target engineering. RSC Adv 4:33338–33346. https://doi.org/10.1039/c4ra04353g
Ortiz CH, Aperador W, Caicedo JC (2022) Physical properties evolution of β-tricalcium phosphate/hydroxyapatite heterostructures in relation to the bilayer number. Thin Solid Films 752:139256. https://doi.org/10.1016/j.tsf.2022.139256
Ortiz CH, Aperador W, Caicedo JC (2022) Electrochemical response of (β-TCP and HA) individual coatings and [β-TCP/HA] multilayers coatings exposed to biocompatible environments. Surf Coat Technol 435:128266. https://doi.org/10.1016/j.surfcoat.2022.128266
Ortiz CO, Colorado HD, Aperador W, Jurado A (2019) Influence of the number of bilayers on the mechanical and tribological properties in [TiN/TiCrN]n multilayer coatings deposited by magnetron sputtering. Tribol Ind 41:330–343. https://doi.org/10.24874/ti.2019.41.03.03
Greczynski G, Hultman L (2017) C1s peak of adventitious carbon aligns to the vacuum level: dire consequences for material’s bonding assignment by photoelectron spectroscopy. ChemPhysChem. 18:1507–1512
Greczynski G, Hultman L (2020) Compromising science by ignorant instrument calibration—need to revisit half a century of published XPS data. Angew Chem 132:5034–5038
Anju VG, Austeria MP, Sampath S (2017) Work function tunable titanium carbonitride nanostructures for high-efficiency, rechargeable Li–iodine batteries. Adv Mater Interfaces 4:1700151
Greczynski G, Hultman L (2018) Reliable determination of chemical state in x-ray photoelectron spectroscopy based on sample-work-function referencing to adventitious carbon: resolving the myth of apparent constant binding energy of the C 1s peak. Appl Surf Sci 451:99–103
Li J, Wang Y, Yao Y, Wang Y, Wang L (2017) Structure and tribological properties of TiSiCN coating on Ti6Al4V by arc ion plating. Thin Solid Films 644:115–119. https://doi.org/10.1016/j.tsf.2017.09.053
Lin J, Wei R (2018) A comparative study of thick TiSiCN nanocomposite coatings deposited by dcMS and HiPIMS with and without PEMS assistance. Surf Coat Technol 338:84–95. https://doi.org/10.1016/j.surfcoat.2018.01.082
Wang Y, Li J, Dang C, Wang Y, Zhu Y (2017) Influence of carbon contents on the structure and tribocorrosion properties of TiSiCN coatings on Ti6Al4V. Tribol Int 109:285–296. https://doi.org/10.1016/j.triboint.2017.01.002
Ma Y, Yang J, Tian X, Gong C, Zheng W, He Y, Li H, Gao Z, Zhang K, Wei L, Chu PK (2020) Enhanced discharge and surface properties of TiSiCN coatings deposited by pulse-enhanced vacuum arc evaporation. Surf Coat Technol 403:126413. https://doi.org/10.1016/j.surfcoat.2020.126413
Wang R, Yang C, Hao J, Shi J, Yan F, Zhang N, Jiang B, Shao W (2022) Influence of target current on structure and performance of Cu films deposited by oscillating pulse magnetron sputtering. Coatings 12:394. https://doi.org/10.3390/coatings12030394
Matsutani T, Tai Y, Kawasaki T (2020) Nitrogen ion beam thinning of a-SiCN diaphragm for environmental cell prepared by low-energy ion beam enhanced chemical vapor deposition. Vacuum. 182:109770
Ma X, Mao Z, Xu D, Ding Y, Xu C (2020) High-rate synthesis of SiCN films using single-source silicon precursor with high-density helicon plasma. Vacuum. 177:109397
Hernandez-Rengifo E, Ortiz CH, Hidalgo CH, Ballesteros JA, Caicedo JC (2021) Comparative study of tribological and mechanical properties between single layers of Al2O3 and Si3N4 deposited on AISI 316 stainless steel. Tribol Ind 43:259–273. https://doi.org/10.24874/ti.956.09.20.01
Ortiz CH, Hernandez-Rengifo E, Guerrero A, Aperador W, Caicedo JC (2021) Mechanical and tribological properties evolution of [Si3N4/Al2O3]n multilayer coatings. Tribol Ind 43:23–39. https://doi.org/10.24874/ti.952.08.20.01
Endler I, Höhn M, Schmidt J, Scholz S, Herrmann M, Knaut M (2013) Ternary and quarternary TiSiN and TiSiCN nanocomposite coatings obtained by chemical vapor deposition. Surf Coat Technol 215:133–140. https://doi.org/10.1016/j.surfcoat.2012.10.067
Zheng Y-j, Yong-xiang Leng X, Xin Z-y X, Fan-qingJiang R, Wei NH (2013) Evaluation of mechanical properties of Ti(Cr)SiC(O)N coated cemented carbide tools. Vacuum. 90:50–58
Piedrahita WF, Aperador W, Caicedo JC, Prieto P (2017) Evolution of physical properties in hafnium carbonitride thin films. J Alloys Compd 690:485–496
Archard JF (1953) Contact and rubbing of flat surfaces. J Appl Phys 24:981–988. https://doi.org/10.1063/1.1721448
Pierson HO (1996) Carbides of group IV. In: Handbook of Refractory Carbides and Nitrides. Elsevier, pp 55–80. https://doi.org/10.1016/B978-081551392-6.50005-2
Ortiz Ortiz C, Hernandez-Rengifo E, Cesar Caicedo J (2021) Analysis of the tribological evolution of nitride-based coatings. In: Tribol. [Working Title. IntechOpen. https://doi.org/10.5772/intechopen.100629
Fernandes L, Silva FJG, Paiva OC, Baptista A, Pinto G (2018) Minimizing the adhesion effects in food packages forming by the use of advanced coatings. Procedia Manuf 17:886–894. https://doi.org/10.1016/j.promfg.2018.10.141
Falsafein M, Ashrafizadeh F, Kheirandish A (2018) Influence of thickness on adhesion of nanostructured multilayer CrN/CrAlN coatings to stainless steel substrate. Surf Interfaces 13:178–185. https://doi.org/10.1016/j.surfin.2018.09.009
Sunil J, Godwin J, Selvam CM (2020) Roles of nanomaterials at the rubbing interface of mechanical systems. Mater Today Proc 21:184–188. https://doi.org/10.1016/j.matpr.2019.04.218
Li Q, Jiang F, Leng Y, Wei R, Huang N (2013) Microstructure and tribological properties of Ti(Cr)SiCN coating deposited by plasma enhanced magnetron sputtering. Vacuum. 89:168–173
Panda A (2012) Analysis of cutting tools durability compared with standard ISO 3685. Int J Adv Comput Theory Eng 4(4):621–624
Coelho RT, Ng E-G, Elbestawi MA (2007) Tool wear when turning hardened AISI 4340 with coated PCBN tools using finishing cutting conditions. Int J Mach Tools Manuf 47(2):263–272
Acknowledgements
In this research, we are grateful to the Universidad del Valle, CDT-ASTIN SENA regional Valle, Cali, Colombia, the Universidad Militar Nueva Granada, and the Excellence Center de Novel Materials CENM.
Funding
This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No. 823717 – ESTEEM3.
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Erick Hernandez-Rengifo and Christian Ortíz: deposition of TiSiCN coatings and morphological characterization
Julio Cesar Caicedo: chemical characterization, mechanical characterization, and machining tests
Luis Alfredo Rodríguez and Cesar Magén: structural and crystalline characterization by TEM
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Hernandez-Renjifo, E., Ortíz, C., Caicedo, J.C. et al. Tribomechanical analysis and machining development for TiSiCN material deposited on industrial steel. Int J Adv Manuf Technol 128, 5437–5461 (2023). https://doi.org/10.1007/s00170-023-11966-1
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DOI: https://doi.org/10.1007/s00170-023-11966-1