Abstract
The increased demands for eggs for consumption have large increases in the deposition of eggshells as environmental pollution worldwide and increase high management costs. To reduce the management costs of eggshells, this work attempt was made to utilize eggshells as a source of CaCO3 for improving the hardness values and wear behavior of composite coating on mild steel. The composite coating was produced using 0, 5, 10, 15, and 20 g CaCO3-derived eggshell particles. The response surface method was used to determine the influences of applied load, sliding speed, and weight of CaCO3-derived eggshell particles on the wear behavior. The results have shown that Zn- CaCO3-derived eggshell particles composite coatings were successfully formed on mild steel. A 90.17% improvement of hardness values was obtained at Zn-20 g CaCO3-derived eggshell particles. The Zn-20 g CaCO3-derived eggshell particles sample has a lower friction coefficient. Wear rate increase with the increase in applied load and sliding speed. The optimum condition was obtained at CaCO3-derived eggshell particles (+ 1), applied load (− 0.35), and speed (− 0.58) with the lowest wear rate of 0.99 mm3/Nm. It has been recommended that the Zn-20 g CaCO3-derived eggshell particles composite coating of mild steel can be used in areas where wear and roller body are paramount.
Similar content being viewed by others
Data availability
The authors confirm that the data supporting the findings of this study are available within the article.
References
Morris JP, Thierry B, Gauthier C (2019) Shells from aquaculture: a valuable biomaterial, not a nuisance waste product. Rev Aquac 11:42–57
Nath D, Jangid K, Susaniya A, Kumar R, Vaish R (2021) Eggshell derived CaO-Portland cement antibacterial composites. Composites Part C: Open Access 5:100123
Jovic M, Mandic M, Sljivic-Ivanovic M, Smiciklas I (2019) Recent trends in application of shell waste from mariculture. Stud Mar 32:47–62
Hart A (2020) Mini-review of waste shell-derived materials’ applications. Waste Manag Res. 38(5):514–527. https://doi.org/10.1177/0734242X19897812.
Hecht J (1999) Eggshells break into collagen market. New Sci 161:6
Shellbrane (2012) Project. Co-Funded by the European Commission through the Seventh Framework Programme (FP7) through the Funding Scheme, "Research for the Benefit of SME-s" under Grant Agreement No. 286910
Tripathi AD, Mishra R, Maurya KK, Singh RB, Wilson DW (2019) Estimates for world population and global food availability for global health. In The Role of Functional Food Security in Global Health; Academic Press: Cambridge, MA, USA, 3–24. [CrossRef]
Sonenklar C (1999) Famous for egg waste. In Research/Penn State News; Penn State University: State College, PA, USA, 20, 1–2. https://news.psu.edu/story/140891/1999/09/01/research/famous-egg-waste
Hseih J (2007) Researchers develop process to recover eggshell waste for alternative uses. Poult Tech 19:1
Morris JP, Wang Y, Backeljau T, Chapelle G (2016) Biomimetic and bio-inspired uses of mollusc shells. Mar Genom. 27, 85–90. [CrossRef] [PubMed]
Gil-Quintana E, Fenaux M, Nuez ML, Molero A, Aguirre A (2018) Short-term effects of ovomet R, egg-shell membrane. Joint pain: a double-blind and placebo study. J Osteopor Phys Act 6(2)
Murakami FS, Rodrigues PO, De Campos CMT, Silva MAS (2007) Physicochemical study of CaCO3 from egg shells. Cience Tecnol Aliment 27:658–662. https://doi.org/10.1590/S0101-20612007000300035
Supriyanto NSW, Sukarni PP, Permanasari AA (2019) Synthesis and characterization of CaO/CaCO3 from quail eggshell waste by solid state reaction process. AIP Conf Proc 2120. https://doi.org/10.1063/1.5115670
Schaafsma A, Pakan I, Hofstede GJH, Muskiet FA, Van Der Veer JE, De Vries PJF (2000) Mineral, amino acid, and hormonal composition of chicken eggshell powder and the evaluation of its use in human nutrition. Poult Sci 79:1833–1838. https://doi.org/10.1093/ps/79.12.1833
Chen L, Chenli F, Luo Z, Xin Y (2016) Study of nano-alumina impact on the performance of a CaCO3-Epoxy composite coating, Nanomater Nanotechnol 6:39. https://doi.org/10.5772/63786
Tavares LM, da Costa EM, de Oliveira Andrade JJ, Hubler R, Huet B (2015) effect of calcium carbonate on low carbon steel corrosion behavior in saline CO2 high pressure environments. Appl Surf Sci 359:143–152
Umoru LE, Oladipo A, Ige OO (2012) Carbonate coatings as protective barriers for pipe borne water transport material. J Miner Mater Character Eng 11(6):609–617. https://doi.org/10.4236/jmmce.2012.116044
Panagopoulos CN, Georgarakis KG, Petroutzakou S (2005) Sliding wear behaviour of zinc–cobalt alloy electrodeposits. J of Mater Proc Techn 160(2):234–244. https://doi.org/10.1016/j.jmatprotec.2004.0
Shourgeshty M, Aliofkhazraei M, Karimzadeh A, Poursalehi R (2017) Corrosion and wear properties of Zn–Ni and Zn–Ni–Al2O3 multilayer electrodeposited coatings. Mater Rese Exp 4(9):096406. https://doi.org/10.1088/2053-1591/aa87d5
Mousavi R, Esmailzadeh M, Bahrololoom ME, Deflorian F (2019) Optimization of Ni-Mo/Al composite coating parameters using Taguchi method. Mater Rese Exp. https://doi.org/10.1088/2053-1591/ab050a
Ghosh S, Sahoo P, Sutradhar G (2012) Wear behaviour of Al-SiCp metal matrix composites and optimization using Taguchi method and grey relational analysis, J. of Miner. & Mater. Character Eng 11:1085–1094
Narayanasamy P, Selvakumar N (2017) Effect of hybridizing and optimization of TiC on the tribological behavior of Mg–MoS2 composites. J of Tribo 139(5):051301. https://doi.org/10.1115/1.4035383
Selvakumar N, Narayanasamy P (2016) Optimization and effect of weight fraction of MoS2 on the tribological behavior of Mg-TiC-MoS2 hybrid composites. Tribo Trans 59(4):733–747. https://doi.org/10.1080/10402004.2015.11108
Hincke MT, Nys Y, Gautron J, Mann K, Rodriguez-Navarro AB, McKee MD (2012) The eggshell: structure, composition and mineralization. Front Biosci 17(1):1266. https://doi.org/10.2741/3985
Aigbodion VS, Akinlabi ET (2019) Explicit microstructural evolution and electrochemical performance of zinc eggshell particles composite coating on mild steel. Surf and Interf 17:100387. https://doi.org/10.1016/j.surfin.2019.100387
Hassan SB, Aigbodion VS (2015) Effects of eggshell on the microstructures and properties of Al–Cu–Mg/eggshell particulate composites, J. of King Saud Univer. – Eng. Sci 27:49–56. https://doi.org/10.1016/J.JKSUES.2013.03.001
Paul SGA, K, Martin W., Gao W, (2015) Electrochem studies of sol-enhanced Zn-Ni-Al2O3 composite and Zn-Ni alloy coatings. J of Electro Chem 755:63–70. https://doi.org/10.1016/j.jelechem.2015.07.041
Eliaz N, Venkatakrishna KA, Hegde C (2010) Electroplating and characterization of Zn-Ni, Zn-Co, and Zn-Ni-Co alloy. J surf and Coating Tech 205:1969–1978. https://doi.org/10.1016/j.surfcoat.2010.08.077
Aigbodion VS, Neife SI, Suleiman IY (2019) Surface modification of mild steel by co-deposition using Zn-ZnO-Ant hill particulate composite coating in simulated seawater. Proceed of the Instit of Mech Eng Part M: J of Eng for the Marit Envir. https://doi.org/10.1177/1475090218792382
Kannan R, Sankar K, Venkatesh K, Sathyabalan PA (2019) Research on Ni alloy coatings on mild steel through electrodeposition method. Inter J of Inno Techno and Expl Eng. 8 Issue-9S
Ghaziof S, Gao W (2015) Mechanical and chemical properties of Zn-Ni-Al2O3 nanocomposite coatings, Inter J of Chem Molecu Nucle Mater Metallur Eng 9 No:8:945-49. https://doi.org/10.5281/zenodo.1107748
El Fazazi A, Ouakki M, Cherkaoui M (2018) Electrochemical deposition of Zinc on mild steel. Medi J of Chem 8(1):30–41
Aigbodion VS (2020) Explicit simultaneous enhancement of adhesion strength and wear resistance of functional value-added epoxy-functionalized rice husk ash nanoparticle composite coating, Inter. J. of Adva. Manuf Techno 109:2205–2214. https://doi.org/10.1007/s00170-020-05758-0
Acknowledgements
The authors hereby appreciate and acknowledge the Africa Centre of Excellence for Sustainable Power and Energy Development, ACE-SPED, University of Nigeria, Nsukka, Faculty of Engineering and Built Environment, University of Johannesburg, Auckland Park, South Africa for their support.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Ethics approval
This work does not include humans and animals and hence does not require ethical approval from any committee.
Consent to participate
This work does not include humans and animals and hence does not require consent to participate in the research.
Consent for publication
The authors give the publisher the consent to publish the work.
Competing interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Adams, S.M., Atikpo, E., Aigbodion, V.S. et al. CaCO3 derived from eggshell waste for improving the hardness values and wear behavior of composite coating on mild steel via co-deposition. Int J Adv Manuf Technol 119, 5483–5496 (2022). https://doi.org/10.1007/s00170-021-08492-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00170-021-08492-3