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Experimental study on microstructural evolution, mechanical property, and corrosion behaviour of laser additive manufactured (LAM) titanium alloy grade 5

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Abstract

Additive manufacturing technique has become one of the more prominent manufacturing techniques over the years. The applications of this manufacturing technique are boundless as new process parameters of the operation affect the new structure of the components and give extended applications. The study experimentally investigates the effects of Ytterbium Laser System process parameters on the resultant microstructure of Ti-6Al-4V grade 5 alloy and reinforcement powders. The deposition process was conducted employing a 3 kW (CW) Ytterbium Laser System (YLS-2000-TR) machine, co-axial to the reinforcement powder. The laser scanning speed and power were varied between the intervals of 0.8–1.0 m/min and 900–1000 W. All other parameters kept constant were the rate of gas flow, the spot diameter, and the rate of powder flow. The composites (Ti-6Al-4V/Ti-Al-Si-Cu) produced by the DLMD technique were analysed using investigative techniques, namely, optical microscopy (OPM), scanning electron microscopy (SEM) aided with energy dispersive microscopy (EDS), X-ray diffraction analysis (XRD), microhardness testing, and corrosion rate analysis. From the analysis of the physical properties, the findings show that the geometric properties such as heat affected zone (HAZ) and dilution ratio of the composite samples were greatly impacted by the increase of the laser power of the DLMD technique, showing an increase in these attributes brought about by the interaction between the laser and the material. The addition of the copper (Cu) element enabled the movement of the copper (Cu) into the titanium (Ti) lattice structure resulting in the formation of beta titanium (β-Ti) microstructure. Increment 54.94% is associated with sample 5A which has the most enhanced microhardness of 770 HV1.0. Sample 6A had shown the most corrosion resistance improvement with 0.00062 mm/year equivalent to 31%.

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References

  1. Mahamood RM, Akinlabi ET, Shukla M, Pityana S (2013) Laser metal deposition of Ti6Al4V: a study on the effect of laser power on microstructure and microhardness. Proceedings Of The International MultiConference Of Engineers And Computer Scientists

  2. Sibisi PN, Popoola API, Kanyane LR, Fatoba OS, Adesina OS, Arthur NKK, Pityana SL (2019) Microstructure and microhardness characterization of Cp-Ti/SiAlON composite coatings on Ti-6Al-4V by laser cladding. Procedia Manuf 35:272–277. https://doi.org/10.1016/j.promfg.2019.05.039

    Article  Google Scholar 

  3. Fatoba OS, Akinlabi ET, Johnson O, Naidoo LC, Akinlabi SA, Erinosho MF (2020) Numerical modelling and microstructural evolution of hybrid Ti-6Al-4V/Ti-Al-Si-Cu composite coating. Int J Adv Manuf Technol 110:967–975. https://doi.org/10.1007/s00170-020-05863-0

    Article  Google Scholar 

  4. Huang SH, Liu P, Mokasdar A, Hou L (2013) Additive manufacturing and its societal impact: a literature review. Int J Adv Manuf Technol 67(5-8):1191–1203

    Article  Google Scholar 

  5. Zhai Y, Galarraga H, Lados D (2016) Microstructure, static properties, and fatigue crack-growth mechanisms in Ti-6Al-4V fabricated by additive manufacturing: LENS and EBM. Eng Fail Anal 69:3–14

    Article  Google Scholar 

  6. Konecna R, Kunz L, Baca A, Nicoletto G Resistance of direct metal laser sintered ti-6al-4v alloy against growth of fatigue cracks. Eng Fract Mech

  7. Fatoba OS, Du Y (2019) Additive manufacturing of advanced solid oxide fuel cells: a review. 16th International Symposium on Solid Oxide Fuel Cells, Kyoto, Japan, Sep. 8-13, 2019. ECS Trans 91(1):277–283 http://ecst.ecsdl.org/content/91/1/277

    Article  Google Scholar 

  8. Oyesola M, Mathe N, Mpofu K, Fatoba OS (2018) Sustainability of additive manufacturing for the South African aerospace industry: a business model for laser technology production, commercialization and market prospects. The 51th CIRP Conference on Manufacturing Systems. Procedia CIRP 72:1530–1535. https://doi.org/10.1016/j.procir.2018.03.072

    Article  Google Scholar 

  9. Viswanathan V, Laha TK, Balani K, Agarwal A, Seal S (2006) Challenges and advances in nanocomposite processing techniques. Mater Sci Eng 54:121–285

    Article  Google Scholar 

  10. Akinlabi ET, Soliu GA, Mahamood RM, Akinlabi SA, Hassan S, Shatalov MY, Murashkin E, Fatoba OS (2020) Laser metal deposition of titanium composites: a review. In: Emamian S, Awang M, Yusof F (eds) Advances in manufacturing engineering. Lecture Notes in Mechanical Engineering. Springer, Singapore, pp 555–564. https://doi.org/10.1007/978-981-15-5753-8_51

    Chapter  Google Scholar 

  11. Lasisi AM, Fatoba OS, Akinlabi SA, Mahamood RM, Shatalov MY, Murashkin EV, Hassan S, Akinlabi ET (2020) Effect of process parameters on the hardness property of laser metal deposited Al–Cu–Ti coatings on Ti–6Al–4V Alloy. In: Emamian S, Awang M, Yusof F (eds) Advances in manufacturing engineering. Lecture Notes in Mechanical Engineering. Springer, Singapore, pp 523–529. https://doi.org/10.1007/978-981-15-5753-8_48

    Chapter  Google Scholar 

  12. Salonitis K, Zeng B, Mehrabi HA, Jolly M (2016) The challenges for energy efficient casting processes. Procedia CIRP 40:24–29

    Article  Google Scholar 

  13. Naidoo LC, Fatoba OS, Akinlabi SA, Mahamood RM, Shatalov MY, Murashkin EV, Hassan S, Akinlabi ET (2020) Study of additive manufactured ti–al–si–cu/ti–6al–4v composite coating by direct laser metal deposition (DLMD) technique. In: Emamian S, Awang M, Yusof F (eds) Advances in manufacturing engineering. Lecture Notes in Mechanical Engineering. Springer, Singapore, pp 503–513. https://doi.org/10.1007/978-981-15-5753-8_46

    Chapter  Google Scholar 

  14. Wang T, Zhu Y, Zhang S, Tang H, Wang H (2015) Grain morphology evolution behavior of titanium alloy components during laser melting deposition additive manufacturing. J Alloys Compd 632:505–513

    Article  Google Scholar 

  15. Arcam (2019) “Ti6Al4V titanium alloy,” Arcam AB, Krokslätts Fabriker 27A, SE 431 37 Mölndal, Sweden

  16. Williams J, Lutjering G (2003) Chapter 5: Alpha+Beta Alloys. Titanium:178–232

  17. Zhao D, Wang R, Wang J, Wenbang Q, Shen N, Gui J (2003) The role of the A phase in the solidification process of Al–Cu–Fe icosahedral quasicrystal. Mater Lett 57:4493–4500

    Article  Google Scholar 

  18. Gharehbaghi R, Fatoba OS, Akinlabi ET (2018) Experimental investigation of laser metal deposited icosahedral Al-Cu-Fe coatings on grade five titanium alloy. In: 2018 IEEE 9th International Conference on Mechanical and Intelligent Manufacturing Technologies (ICMIMT 2018), Cape Town, South Africa, pp 31–36. https://doi.org/10.1109/ICMIMT.2018.8340416

    Chapter  Google Scholar 

  19. O.S. Fatoba; E.T. Akinlabi; M.E. Makhatha (2017). Influence of rapid solidification on the thermo-physical and fatigue properties of laser additive manufactured Ti-6Al-4V alloy, Fiber Laser, Dr. Subbarayan Sivasankaran (Ed.), InTech https://doi.org/10.5772/intechopen.71697, 2017

  20. Zhang K, Hu R, Li J, Yang J, Gao Z (2020) Grain refinement of 1 at.% Ta-containing cast TiAl-based alloy by cyclic air-cooling heat treatment. Mater Lett 274:127940

    Article  Google Scholar 

  21. Udomphol T (2007) Lecture 5: titanium and its alloys. Suranaree University of Technology, Suranaree

    Google Scholar 

  22. Baumer M, Dickens P, Tuck C, Hague R (2016) The cost of additive manufacturing: machine productivity, economics of scales and technology-push. Technol Forecast Soc Chang 102:193–201

    Article  Google Scholar 

  23. Fatoba OS, Adesina OS, Popoola API (2018) Evaluation of microstructure, microhardness, and electrochemical properties of laser-deposited Ti-Co coatings on Ti-6Al-4V alloy. Int J Adv Manuf Technol 97(5):2341–2350. https://doi.org/10.1007/s00170-018-2106-7

    Article  Google Scholar 

  24. Fatoba OS, Akinlabi ET, Makhatha ME (2018) Effects of cooling rate and silicon content on microstructure and mechanical properties of laser deposited Ti-6Al-4V alloy. Mater Today Proc 5(9) part 3:18368–18375. https://doi.org/10.1016/j.matpr.2018.06.176

    Article  Google Scholar 

  25. Obiegbu MC, Fatoba OS, Akinlabi ET, Akinlabi SA (2019) Experimental study on characteristics of laser metal deposited Al-Si-Sn-Cu/Ti-6Al-4V composite coatings. Mater Express Res 6(4):1–11. https://doi.org/10.1088/2053-1591/aafe4d

    Article  Google Scholar 

  26. Pityana S, Akinlabi ET, Shukla M, Mahamood RM (2013) Effect of powder flow rate and gas flow rate on properties of laser metal deposited Ti-6Al-4V. IMECS:847–852

  27. Hentschel O, Siegel L, Scheitler C, Huber F, Junker D, Gorunow A, Schmidt M (2018) Processing of AISI H11 tool steel powder modified with carbon black nanoparticles for the additive manufacturing of forging tools with tailored mechanical properties by means of laser metal deposition (LMD). Metals 8(9):659

    Article  Google Scholar 

  28. Xu C, Yu J, Zhang Z (2013) In situ joining of titanium To SiC/Al composites by low-pressure infiltration. Mater Des 47:267–273

    Article  Google Scholar 

  29. Jiangwei R, Yajiang L, Tao F (2002) Microstructure Characteristics In The Interface Zone Of Ti/Al Diffusion Bonding. Mater Lett 56:647–652

    Article  Google Scholar 

  30. Hawk JA, Alman DE (1997) Abrasive wear of intermetallic-based alloys and composites. J Mater Sci Eng A 899–906:239–240

    Google Scholar 

  31. Dey SR, Hazotte A, Bouzy E (2009) Crystallography and phase transformation mechanisms in tial-based alloys – a synthesis. Intermetallics 17:1052–1064

    Article  Google Scholar 

  32. Dai J, Zhang F, Wang A, Yu H, Chen C (2017) Microstructure and properties of Ti-Al coating and Ti-Al-Si System coatings on TI-6Al-4V. Surf Coat Technol

  33. Fatoba OS, Akinlabi SA, Akinlabi ET (2018) Numerical Modelling and Performance effects of laser deposited Ti-Al-Sn coating on ASTM A29 steel. International Conference on Mechanical Stress Evaluation by Neutron and Synchrotron (MECASENS 2017), Kruger Park, South Africa. Mater Res Proc 4:135–140. https://doi.org/10.21741/9781945291678-21

    Article  Google Scholar 

  34. Lutjering G, Williams JC, Gysler A (2003) Microstructure and mechanical properties of titanium alloys. Technical University Hamburg-Harburg And General Electric Aircraft Engines, Hamburg

    Google Scholar 

  35. M. F. Erinosho, E. T. Akinlabi, O. Johnson and G. Owolabi, Effect of scanning speed on the material characterisation of laser-deposited titanium alloy and copper, 2015.

    Google Scholar 

  36. Mahamood RM, Akinlabi ET, Shukla M, Pityana S (2014) Characterizing the effect of processing parameters on the porosity of laser-deposited titanium alloy powder, vol 2014. Proceedings Of The International MultiConference Of Engineers And Computer Scientists: IMECS

  37. Sun Z, Guo W, Li L (2020) In-process measurement of melt pool cross-sectional geometry and grain orientation in a laser directed energy deposition additive manufacturing process. Opt Laser Technol 129

  38. Mahamood RM, Akinlabi ET, Shukla M, Pityana S (2012) Effect of laser power on material efficiency, layer height and width of laser metal deposited on Ti-6Al-4V. Int J Mech Ind Sci Eng 2:18–23

    Google Scholar 

  39. Gharehbaghi R, Fatoba OS, Akinlabi ET (2018) Influence of scanning speed on the microstructure of deposited Al-Cu-Fe coatings on a titanium alloy substrate by laser metal deposition process. In: 2018 IEEE 9th International Conference on Mechanical and Intelligent Manufacturing Technologies (ICMIMT 2018), Cape Town, South Africa, pp 44–49. https://doi.org/10.1109/ICMIMT.2018.8340418

    Chapter  Google Scholar 

  40. Fatoba OS, Akinlabi ET, Akinlabi SA (2018) Numerical investigation of laser deposited al-based coatings on Ti-6Al-4V alloy. In: 2018 IEEE 9th International Conference on Mechanical and Intelligent Manufacturing Technologies (ICMIMT 2018), Cape town, South Africa, pp 85–90. https://doi.org/10.1109/ICMIMT.2018.8340426

    Chapter  Google Scholar 

  41. Rahman MJ, Sen SR, Moniruzzaman M, Shorowordi KM (2009) Morphology and properties of electrodeposited Zn-Ni alloy coatings ON MILD STEEL. J Mech Eng 40:9–12

    Article  Google Scholar 

  42. Ashiru OA, Shirokoff J (1996) Electrodeposition and characterization of tin-zinc alloy coatings. Appl Surf Sci 103:159–169

    Article  Google Scholar 

  43. Makhatha ME, Fatoba OS, Akinlabi ET (2018) Effects of rapid solidification on the microstructure and surface analyses of laser-deposited Al-Sn coatings on AISI 1015 steel. Int J Adv Manuf Technol 94(1-4):773–787. https://doi.org/10.1007/s00170-017-0876-y

    Article  Google Scholar 

  44. Fatoba OS, Akinlabi ET, Akinlabi SA, Erinosho MF (2019) Numerical modelling, microstructural evolution and characterization of laser cladded Al-Sn-Si coatings on Ti-6Al-4V alloy: 16th Australasian Conference, AusDM 2018, Bahrurst, NSW, Australia, November 28–30, 2018. https://doi.org/10.1007/978-3-030-05864-7_39.

  45. Ahmed T, Rack HJ (1998) Phase transformation during cooling of α+β titanium alloys. Mater Sci Eng A 243:206–211

    Article  Google Scholar 

  46. Liu X, Warren AP, Nuhfer NT, Rollett AD, Coffey KR, Barmak K (2014) Comparison of crystal orientation mapping-based on the image measurement of grain size distribution in a thin aluminium film. Acta Mater 79:138–145

    Article  Google Scholar 

  47. Kalhapure M, Dighe P (2015) Impact of silicon content on mechanical properties of aluminum alloys. Int J Sci Res 4:38–40

    Google Scholar 

  48. Cai L, Tateishi T (2009) Quasicrystalline phase formation in the conventionally solidified Al-Cu-Fe system. Mater Trans JIM 32(11):1001–1121

    Google Scholar 

  49. Pinkerton AJ, Li L, Wang W (2008) Component repair using laser-direct metal deposition. Proc Inst Mech Eng B J Eng Manuf 223:826–837

    Google Scholar 

  50. Akinlabi ET, Fatoba OS, Akinlabi SA (2019) Numerical modelling and influence of cu addition on the microstructure and mechanical properties of additive manufactured Ti–Al–Cu/Ti–6Al–4V composite: 10th International Symposium, ISICA 2018, Jiujiang, China, October 13–14, 2018. https://doi.org/10.1007/978-3-030-05728-2_13

  51. Lan X, Hong W, Liu Y, Zhang W, Li R, Chen S, Zai X, Hu T (2016) Microstructures and tribological properties of laser-cladded ti-based metallic glass composite coatings. Mater Charact 120:82–89

    Article  Google Scholar 

  52. Yuan G, Li Z, Lou Y, Zhang X (2000) Study on crystallization and microstructure for new series Of Al-Sn-Si. Mater Sci Eng A 280:108–115

    Article  Google Scholar 

  53. Fatoba OS, Akinlabi ET, Akinlabi SA, Obiegbu MC (2019) Effects of silicon carbide (SiC) reinforcement on the microstructure and mechanical properties of laser deposited Al-Sn-SiC/Ti-6Al-4V composite coatings. Key Eng Mater 796:53–61. https://doi.org/10.4028/www.scientific.net/KEM.796.53

    Article  Google Scholar 

  54. Leyens C, Peters M (2003) Titanium and titanium alloys, fundamentals and applications. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, ISBN: 3-527-30534-3

    Book  Google Scholar 

  55. Obiegbu MC, Akinlabi ET, Akinlabi FOS, S.A. (2019) The effects of silicon and copper on the microstructure and wear resistance performance of Al-Si-Sn-Cu/Ti-6Al-4V composite coatings. In: 2019 IEEE 10th International Conference on Mechanical and Intelligent Manufacturing Technologies (ICMIMT 2019), Cape town, South Africa, pp 20–25. https://doi.org/10.1109/ICMIMT.2019.8712023

    Chapter  Google Scholar 

  56. Azarniya A, Colera X, Mirzaali M, Sovizi S, Bartolomeu F, Wits W, Yap C, Ahn J, Miranda G, Silva F, Madaah Hosseini H, Ramakrishna S, Zadpoor A (2019) Additive manufacturing of Ti–6Al–4V parts through laser metal deposition (LMD): process, microstructure, and mechanical properties. J Alloys Compd

  57. Mok S, Bi G, Folkes J, Pashby I (2008) Deposition of Ti–6Al–4V using a high power diode laser and wire, Part I: Investigation on the process characteristics. Surf Coat Technol 202:3933–3939

    Article  Google Scholar 

  58. Zhai Y, Lados DA, Brown EJ, Vigilante GN (2016) Fatigue crack-growth behavior and microstructural mechanisms in Ti-6Al-4V manufactured by laser engineered net shaping. Int J Fatigue 93:51–63

    Article  Google Scholar 

  59. Fatoba OS, Akinlabi SA, Akinlabi ET (2019) Numerical modelling and effects of reinforcement addition on the microstructural evolution of additive manufactured Ti-6Al-4V alloy. Mater Today Proc 18, part 7:2832–2839. https://doi.org/10.1016/j.matpr.2019.07.150

    Article  Google Scholar 

  60. Fatoba OS, Akinlabi SA, Akinlabi ET, Mwema FM (2019) Characterization of laser additive manufactured Al-Si coating on titanium alloy. Mater Today Proc 18, part 7:4675–4682. https://doi.org/10.1016/j.matpr.2019.07.452

    Article  Google Scholar 

  61. Fatoba OS, Akinlabi SA, Akinlabi ET, Krishna S (2019) Influence of rapid solidification and optimized laser parameters relationship on the geometrical and hardness properties of Ti-Al-Cu coatings. Mater Today Proc 18, part 7:2859–2867. https://doi.org/10.1016/j.matpr.2019.07.153

    Article  Google Scholar 

  62. Erinosho MF, Akinlabi ET (2015) Effect of laser power on the microstructural behaviour and strength of modified laser-deposited Ti6Al4V+Cu alloy for medical application. Department Of Mechanical Engineering Science, University Of Johannesburg, Johannesburg

    Google Scholar 

  63. Yang Y, Liu Y, Chen J, Wang H, Zhang Z, Lu Y, Wu S, Lin J (2017) Crystallographic features of α variants and β phase for Ti-6Al-4V alloy fabricated by selective laser melting. Mater Sci Eng A 707:548–558

    Article  Google Scholar 

  64. Hua N, Hong X, Lin L, Liao Z, Zhang L (2020) Mechanical, corrosion, and wear performances of a biocompatible Ti-based glassy alloy. J Non-Cryst Solids 543

  65. Song DS, Kim JH, Fleury E, Kim WT, Kim DH (2005) Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe-Nb-B-Y system. J Alloys Compd 398:159–164

    Article  Google Scholar 

  66. Watkins KG, Mcmahon MA, Steen WM (1997) Microstructure and corrosion properties of laser surface processed aluminium alloys: a review. J Mater Sci Eng 231:55–61

    Article  Google Scholar 

  67. Garcia I, De Damborenea JJ (1998) Corrosion properties of tin prepared by laser gas alloying of ti and ti6al4v. Corros Sci 40:1411–1419

    Article  Google Scholar 

  68. Shao H, Zhao Y, Ge P, Zeng W (2013) Crack initiation and mechanical properties of TC21 titanium alloy with equiaxed microstructure. Mater Sci Eng A 586:215–222

    Article  Google Scholar 

  69. Aigbodion VS, Popoola API, Fatoba OS (2016) Evaluation of hardness values and corrosion behaviour of laser alloyed 20Al-20Sn-60Ti coatings of UNS G10150 mild steel. Int J Adv Manuf Technol 86(1-4):291–301 1-11. https://doi.org/10.1007/s00170-015-8111-1

    Article  Google Scholar 

  70. Fatoba OS, Popoola API, Aigbodion VS (2016) Experimental study of hardness values and corrosion behaviour of laser alloyed Zn-Sn-Ti coatings of UNS G10150 mild steel. J Alloys Compd 658:248–254

    Article  Google Scholar 

  71. Fatoba OS, Popoola API, Fedotova T, Pityana SL (2015) Electrochemical studies on the corrosion behaviour of laser alloyed Zn-Sn coatings on UNS G10150 steel in 1M HCl solution. Silicon. 7(4):357–369

    Article  Google Scholar 

  72. Praveen BM, Venkatesha TV (2008) Electrodeposition and properties of Zn-nanosized TiO2 composite coatings. Appl Surf Sci 254:2418–2424

    Article  Google Scholar 

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Acknowledgements

The authors wish to acknowledge National Laser Center, CSIR, South Africa, for the laser equipment.

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National Research Foundation (NRF) South Africa is appreciated for the research funding.

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OSF: research conception, writing of original manuscript, literature review, experimental work, and data analysis. TCJ: proofreading of manuscript and review. ETA: proofreading of manuscript, literature review, data analysis, and materials.

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Correspondence to Olawale Samuel Fatoba.

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Fatoba, O.S., Jen, TC. & Akinlabi, E.T. Experimental study on microstructural evolution, mechanical property, and corrosion behaviour of laser additive manufactured (LAM) titanium alloy grade 5. Int J Adv Manuf Technol 114, 655–669 (2021). https://doi.org/10.1007/s00170-021-06872-3

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