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Study on the potential of chemo-mechanical-grinding (CMG) process of sapphire wafer

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Abstract

Chemo-mechanical-grinding (CMG) is a hybrid process which integrates chemical reaction and mechanical grinding between abrasives and workpiece into one process. It has been successfully applied into manufacturing process of silicon wafers where both geometric accuracy and surface quality are required. This paper aims to study the potential of CMG process in manufacturing process of single crystal sapphire wafers. The basic material removal mechanism in terms of chemical effect and mechanical effect in CMG process has been analysed based on experiment results of two different kinds of CMG wheels. The experiment results suggest that chromium oxide (Cr2O3) performs better than silica (SiO2) in both material removal rate (MRR) and surface quality. It also reveals that, no matter under dry condition or wet condition, CMG is with potential to achieve excellent surface quality and impressive geometric accuracy of sapphire wafer. Meanwhile, test result by Raman spectrum shows that, by using Cr2O3 as abrasive, the sub-surface damage of sapphire wafer is hardly to be detected. Transmission electron microscopy (TEM) tells that the sub-surface damage, about less than 50 nm, might remain on the top surface if chemical effect is not sufficient enough to meet the balance with mechanical effect in CMG process.

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References

  1. Li ZC, Pei ZJ, Funkenbusch, PD (2011) Machining processes for sapphire wafers: a literature review. Proceedings of the Institution of Mechanical Engineers, Part B: Journal of Engineering Manufacture 225(7):975–989

  2. Lin YS, Lin KH, Chang YM, Yeh JA (2012) Epitaxy of m-plane GaN on nanoscale patterned c-plane sapphire substrates. Surf Sci 606(1–2):L1–L4

    Article  Google Scholar 

  3. Wang G, Zuo H, Zhang H, Wu Q et al (2010) Preparation, quality characterization, service performance evaluation and its modification of sapphire crystal for optical window and dome application. Mater Design 31(2):706–711

    Article  Google Scholar 

  4. Gutsche HW, Moody JW (1978) Polishing of sapphire with colloidal silica. J Electrochem Soc 125(1):136–138

    Article  Google Scholar 

  5. Eda H, Zhou L, Nakano H, Kondo R et al (2001) Development of single step grinding system for large scale Φ300 Si wafer. CIRP Ann-Manuf Techn 50(1):225–228

    Article  Google Scholar 

  6. Zhou L, Kawai S, Honda M et al (2002) Research on chemo-mechanical-grinding (CMG) of Si wafer: 1st report: development of CMG wheel. J Jpn Soc Precis Eng 68(12):1559–1563

    Article  Google Scholar 

  7. Zhu H, Tessaroto LA, Sabia R et al (2004) Chemical mechanical polishing (CMP) anisotropy in sapphire. Appl Surf Sci 236(1):120–130

    Article  Google Scholar 

  8. Zhu H, Niesz DE, Greenhut VA et al (2005) The effect of abrasive hardness on the chemical-assisted polishing of (0001) plane sapphire. J Mater Res 20(02):504–520

    Article  Google Scholar 

  9. Aida H, Doi T, Takeda H et al (2012) Ultraprecision CMP for sapphire, GaN, and SiC for advanced optoelectronics materials. Curr Appl Phys 12:S41–S46

    Article  Google Scholar 

  10. Lee H, Kasuga H, Ohmori H et al (2011) Application of electrolytic in-process dressing (ELID) grinding and chemical mechanical polishing (CMP) process for emerging hard–brittle materials used in light-emitting diodes. J Cryst Growth 326(1):140–146

    Article  Google Scholar 

  11. Zhou L, Shimizu J, Eda H, Kimura S (2005) Research on chemo-mechanical-grinding (CMG) of Si wafer (2nd report). J Jpn Soc Precis Eng 71(4):466–470

    Google Scholar 

  12. Zhou L, Eda H, Shimizu J, Kamiya S, Iwase H, Kimura S (2006) Defect-free fabrication for single crystal silicon substrate by chemo-mechanical grinding. CIRP Ann-Manuf Techn 55(1):313–316

    Article  Google Scholar 

  13. Wu K, Yamazaki N, Ebina Y, et al. (2016) Study on sapphire wafer grinding by chromium oxide (Cr2O3) wheel. Adv mat res Trans Tech Publications 806:311–316

  14. Yasunuga N (1978) Effect of solid state reaction on wear of sapphire sliding on steel. J Jpn Soc Precis Eng 44:65

    Google Scholar 

  15. Suzuki K, Uematsu T, Ohashi H et al (1992) Development of a new mechanochemical polishing method with a polishing film for ceramic round bars. CIRP Ann-Manuf Techn 41(1):339–342

    Article  Google Scholar 

  16. Kikuchi M, Takahashi Y, Suga T et al (1992) Mechanochemical polishing of silicon carbide single crystal with chromium (III) oxide abrasive. J Am Ceram Soc 75(1):189–194

    Article  Google Scholar 

  17. Xu L, Zou C, Shi X et al (2015) Fe-N x/C assisted chemical–mechanical polishing for improving the removal rate of sapphire. Appl Surf Sci 343:115–120

    Article  Google Scholar 

  18. Shi X, Pan G, Zhou Y et al (2015) A study of chemical products formed on sapphire (0001) during chemical–mechanical polishing. Sur Coat Tech 270:206–220

    Article  Google Scholar 

  19. Lei H, Tong K (2015) Preparation of La-doped colloidal SiO2 composite abrasives and their chemical mechanical polishing behavior on sapphire substrates. Precis Eng 44:124–130

    Article  Google Scholar 

  20. Zhou Y, Pan G, Shi X et al (2015) Effects of ultra-smooth surface atomic step morphology on chemical mechanical polishing (CMP) performances of sapphire and SiC wafers. Tribol Int 87:145–150

    Article  Google Scholar 

  21. Rogov VV, Rublev ND, Krotenko TL et al (2008) A study of intensity of tribochemical contact interaction between a polishing compound and sapphire in machining. J Superhard Mater 30(4):273–275

    Article  Google Scholar 

  22. Vovk EA, Budnikov AT, Dobrotvorskaya MV et al (2012) Mechanism of the interaction between Al2O3 and SiO2 during the chemical-mechanical polishing of sapphire with silicon dioxide. J Surf Investig-X-Ra 6(1):115–121

    Article  Google Scholar 

  23. Fujita M, Inukai K, Sakida S et al (2007) Sintering of Al2O3-Cr2O3 powder prepared by sol-gel process. Journal of the Society of Materials Science, Japan 56(6):526–530

    Article  Google Scholar 

  24. Parada FE (2006) Characterization of stress in GaN-on-sapphire microelectromechanical systems (MEMS) structures using micro-raman spectroscopy. Air Force Inst of Tech Wright-Patterson AFB OH School of Engineering and Management

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Wu, K., Zhou, L., Shimizu, J. et al. Study on the potential of chemo-mechanical-grinding (CMG) process of sapphire wafer. Int J Adv Manuf Technol 91, 1539–1546 (2017). https://doi.org/10.1007/s00170-016-9836-1

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  • DOI: https://doi.org/10.1007/s00170-016-9836-1

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