Abstract
Water safety concerning Barium (Ba) has become a public issue worldwide. As the “Asian water tower”, Tibetan Plateau is the birthplace of many rivers. However, the distribution, source, and output flux of Ba are largely unknown. In this study, surface water samples were collected from different catchments in the Sanjiangyuan Region (SJY) and the Qilian Mountain Region (QLM) in Tibetan Plateau. The concentration of Ba was determined by inductively coupled plasma optical emission spectroscopy, the source of Ba was discussed by a Gibbs diagram, and the output flux of Ba was estimated using the observation data from different hydrological stations. The results showed that the Ba concentrations were less than 160 µg/L, which is much lower than the guideline value of 700 µg/L for surface waters. The main sources of Ba were rock weathering and evaporation concentration. The total Ba output flux from SJY and QLM to downstream waters was 1,240 t/yr, which accounts for about 0.01% of the global freshwater Ba output flux to the ocean. The Ba production rate in Tibetan Plateau was comparable with that in the Arctic rivers. Under the scenario of global warming, water safety issues concerning Ba will be more serious since the output flux of Ba to downstream waters will be increased by intensified rock weathering, evaporation concentration, glacial retreat, and permafrost thawing. This study reveals the Ba flux and production rate in Tibetan Plateau, which will provide important information for evaluating the environmental impact of global warming on public health.
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References
Alexander RB, Smith RA, Schwarz GE et al (2008) Differences in phosphorus and nitrogen delivery to the gulf of Mexico from the Mississippi river basin. Environ Sci Technol 42(3):822–830
Chen JS, Wang FY, Xia XH et al (2002) Major element chemistry of the Changjiang (Yangtze River). Chem Geol 187(3–4):231–255
Cuoco E, Tedesco D, Poreda RJ et al (2013) Impact of volcanic plume emissions on rain water chemistry during the January 2010 Nyamuragira eruptive event: implications for essential potable water resources. J Hazard Mater 244–245:570–581
Dalai TK, Krishnaswami S, Sarin MM (2002) Barium in the Yamuna River System in the Himalaya: sources, fluxes, and its behavior during weathering and transport. Geochem Geophy Geosy. 3https://doi.org/10.1029/2002gc000381
Das A, Krishnaswami S (2006) Barium in Deccan basalt rivers: its abundance, relative mobility and flux. Aquat Geochem 12(3):221–238
Emsley J (2011) Nature’s building blocks: an AZ guide to the elements. Oxford University Press
Franciskovic-Bilinski S (2006) Barium anomaly in Kupa River drainage basin. J Geochem Explor 88(1–3):106–109
Gaillardet J, Dupre B, Louvat P et al (1999) Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers. Chem Geol 159(1–4):3–30
Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170(3962):1088–1090
He B, Zhang Y, Zhu J, Wei S et al (2011) Analysis of the features of the mountainous runoff in three inland river basins of Qilian mountain during recent 50 years. J Water Res Plan Man 22(5):11–15
Hu MH, Stallard RF, Edmond JM (1982) Major ion chemistry of some large chinese rivers. Nature 298(5874):550–553
Jia WX, He YQ, Wang XF et al (2009) Temporal and spatial change of the potential evaporation over Qilian mountains and Hexi corridor from 1960 to 2006. Adv Water Resour 20(2):159–167
Jiao X, Dong Z, Kang S et al (2021) New insights into heavy metal elements deposition in the snowpacks of mountain glaciers in the eastern tibetan Plateau. Ecotox Environ Safe, 207
Kravchenko J, Darrah TH, Miller RK et al (2014) A review of the health impacts of barium from natural and anthropogenic exposure. Environ Geochem Health 36(4):797–814
Lu Q, Xu X, Xu Z et al (2018) Barium concentrations and speciation in surface waters collected from an active barium mining area in Guizhou Province, southwestern China. Environ Sci Pollut R 25(8):7608–7617
Ministry of Environmental Protection of China (2002) Environmental quality standards for surface water (GB 3838 – 2002)
Paudyal R, Kang S, Sharma CM et al (2016) Major ions and trace elements of two selected rivers near Everest region, southern Himalayas, Nepal. Environ Earth Sci, 75(1)
Qi D, Li X, Xiao H et al (2015) Study on changing characteristics and impact factor of evaporation over three-river source area in recent 50 years. Resour and Environ in the Yangtze Basin 24(9):1613–1620
Qu B, Zhang Y, Kang S et al (2019) Water quality in the Tibetan Plateau: major ions and trace elements in rivers of the “Water Tower of Asia. Sci Total Environ 649:571–581
Quiriny M, Dekeyser C, Moreau M et al (2017) Benign tumors of the parotid gland: a retrospective study of 339 patients. Acta Chir Belg 117(4):227–231
Rahman S, Shiller AM, Anderson RF et al (2022) Dissolved and particulate barium distributions along the US GEOTRACES North Atlantic and East Pacific zonal transects (GA03 and GP16): global implications for the marine barium cycle. Global Biogeochem Cy, 36(6)
Samanta S, Dalai TK (2016) Dissolved and particulate barium in the Ganga (Hooghly) River estuary, India: Solute-particle interactions and the enhanced dissolved flux to the oceans. Geochim Cosmochim Ac 195:1–28. https://doi.org/10.1016/j.gca.2016.09.005
Sebesta F, Benes P, Sedlacek J et al (1981) Behavior of radium and barium in a system including uranium-mine waste-waters and adjacent surface waters. Environ Sci Technol 15(1):71–75
St Pierre KA, Zolkos S, Shakil S et al (2018) Unprecedented increases in total and methyl mercury concentrations downstream of retrogressive thaw slumps in the western canadian Arctic. Environ Sci Technol 52(24):14099–14109
Taylor SR, McLennan SM, McCulloch MT (1983) Geochemistry of loess, continental crustal composition and crustal model ages. Geochim Cosmochim Ac 47(11):1897–1905
World Health Organization (2004) Guidelines for drinking-water quality, vol 1. World Health Organization
Wu W, Yang J, Xu S et al (2008) Geochemistry of the headwaters of the Yangtze River, Tongtian he and Jinsha Jiang: Silicate weathering and CO2 consumption. Appl Geochem 23(12):3712–3727
Xu M, Kang S, Chen X et al (2018) Detection of hydrological variations and their impacts on vegetation from multiple satellite observations in the three-river source region of the Tibetan Plateau. Sci Total Environ 639:1220–1232
Zhang X, Chen H, Yao Q et al (2013) The seasonal changes and flux of trace elements in the lower reaches of Yellow River. Periodical of Ocean University of China 43(8):69–75
Acknowledgements
This study was supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No.: XDB40020400), the Strategic Priority Research Program of the Chinese Academy of Sciences, Pan-Third Pole Environment Study for a Green Silk Road (Pan-TPE) (Grant No.: XDA20040502), and National Natural Science Foundation of China (Grant No.: 41877405).
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Zuxiu Yao and Guangyi Sun contributed equally to this work.
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Yao, Z., Sun, G., Lin, L. et al. Distribution, Source Identification, and Output flux of Barium in Surface Waters in the Sanjiangyuan Region and Qilian Mountain Region of Tibetan Plateau. Bull Environ Contam Toxicol 111, 7 (2023). https://doi.org/10.1007/s00128-023-03747-z
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DOI: https://doi.org/10.1007/s00128-023-03747-z