Abstract
This study investigated heavy metal(HM) soil pollution and evaluated the risk and sources at a legacy tailings pond’s area in Meizhou, China. Result shows that HM accumulation in soil, particularly Cd, Pb, and Zn, were serious. Zn and Cd in tailing soil and all studied elements in field soil had a significant release potential. Four HM sources were identified by positive matrix factorization (PMF) model: cinder and vehicle emissions (11.3%), natural sources (16.3%), tailings pond and human activities (32.8%), tailings pond (39.7%). The soil was severely polluted with Cd, Pb, and Zn, which posed a high potential environmental risk near surrounding area. Column leaching tests showed that large quantities of HMs were released from the tailings soil during simulated rainfall with different pH. This study indicates that the study area has been severely polluted and continues to have a great risk of HM pollution under natural conditions.
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References
Alam R, Ahmed Z, Howladar MF (2020) Groundwater for Sustainable Development Evaluation of heavy metal contamination in water, soil and plant around the open landfill site Mogla Bazar in Sylhet, Bangladesh. Groundw Sustain Dev 10:100311. https://doi.org/10.1016/j.gsd.2019.100311
Barbieri E, Fontúrbel FE, Herbas C, Barbieri FL, Gardon J (2014) Indoor metallic pollution and children exposure in a mining city. Sci Total Environ 487:13–19. https://doi.org/10.1016/j.scitotenv.2014.03.136
Cai LM, Wang QS, Wen HH, Luo J, Wang S (2019) Heavy metals in agricultural soils from a typical township in Guangdong Province, China: Occurrences and spatial distribution. Ecotoxicol Environ Saf 168:184–191. https://doi.org/10.1016/j.ecoenv.2018.10.092
Chen H (2009) Analysis on the distribution and genesis of acid rain in Qujiang. Guangdong Meteonology(Chinese) 31(2):53–55
Chen M, Lu G, Wu J, Sun J, Yang C, Xie Y, Wang K, Deng F, Yi X, Dang Z (2020) Acidity and metallic elements release from AMD-affected river sediments: Effect of AMD standstill and dilution. Environ Res 186:109490. https://doi.org/10.1016/j.envres.2020.109490
Cui H, Zhang S, Li R, Yi Q, Zheng X, Hu Y, Zhou J (2017) Leaching of Cu, Cd, Pb, and phosphorus and their availability in the phosphate-amended contaminated soils under simulated acid rain. Environ Sci Pollut Res 24:21128–21137. https://doi.org/10.1007/s11356-017-9696-8
Dijkstra JJ, Meeussen JCL, Comans RNJ (2004) Leaching of heavy metals from contaminated soils: An experimental and modeling study. Environ Sci Technol 38:4390–4395. https://doi.org/10.1021/es049885v
Ding Q, Cheng G, Wang Y, Zhuang D (2017) Effects of natural factors on the spatial distribution of heavy metals in soils surrounding mining regions. Sci Total Environ 578:577–585. https://doi.org/10.1016/j.scitotenv.2016.11.001
Dube A, Kowalkowski RZT, Cukrowska E, Buszewski B (2001) Adsorption and Migration of heavy metals in Soil. Pol J Environ Stud 10:1–10
Feng H (2010) Acid rain pollution in Meizhou City and Its Control Counter measures. J Jialing Univ (Natural science) (Chinese) 28(8):51–54
Feng S, Liao R, Ali A, Mahar A, Guo D, Li R, Xining S, Awasthi MK, Wang Q, Zhang Z (2017) Spatial distribution and risk assessment of heavy metals in soil near a Pb/Zn smelter in Feng County, China. Ecotoxicol Environ Saf 139:254–262. https://doi.org/10.1016/j.ecoenv.2017.01.044
Hakanson L (1980) An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14:975–1001. https://doi.org/10.1016/0043-1354(80)90143-8
Hou D, He J, Lü C, Ren L, Fan Q, Wang J, Xie Z (2013) Distribution characteristics and potential ecological risk assessment of heavy metals (Cu, Pb, Zn, Cd) in water and sediments from Lake Dalinouer. China Ecotoxicol Environ Saf 93:135–144. https://doi.org/10.1016/j.ecoenv.2013.03.012
Hu Y, Cheng H (2016) A method for apportionment of natural and anthropogenic contributions to heavy metal loadings in the surface soils across. Environ Pollut 214:400–409. https://doi.org/10.1016/j.envpol.2016.04.028
Huang J, Peng S, Mao X, Li F, Guo S, Shi L, Shi Y, Yu H, Zeng G-M (2019) Source apportionment and spatial and quantitative ecological risk assessment of heavy metals in soils from a typical Chinese agricultural county. Process Saf Environ Prot 126:339–347. https://doi.org/10.1016/j.psep.2019.04.023
Jin G, Fang W, Shafi M, Wu D, Li Y, Zhong B, Ma J, Liu D (2019) Source apportionment of heavy metals in farmland soil with application of APCS-MLR model: A pilot study for restoration of farmland in Shaoxing City Zhejiang, China. Ecotoxicol Environ Saf 184. https://doi.org/10.1016/j.ecoenv.2019.109495
Lu A, Wang J, Qin X, Wang K, Han P, Zhang S (2012) Multivariate and geostatistical analyses of the spatial distribution and origin of heavy metals in the agricultural soils in Shunyi. Beijing China Sci Total Environ 425:66–74. https://doi.org/10.1016/j.scitotenv.2012.03.003
Li H, Ji H, Shi C, Gao Y, Zhang Y, Xu X, Ding H, Tang L, Xing Y (2017) Distribution of heavy metals and metalloids in bulk and particle size fractions of soils from coal-mine brownfield and implications on human health. Chemosphere 172:505–515. https://doi.org/10.1016/j.chemosphere.2017.01.021
Li W, Gu K, Yu Q, Sun Y, Wang Y, Xin M, Bian R, Wang H, Wang Ya-nan, Zhang D (2021) Leaching behavior and environmental risk assessment of toxic metals in municipal solid waste incineration fly ash exposed to mature landfill leachate environment. Waste Manag 120:68–75. https://doi.org/10.1016/j.wasman.2020.11.020
Liu K, Li C, Tang S, Shang G, Yu F, Li Y (2020) Heavy metal concentration, potential ecological risk assessment and enzyme activity in soils affected by a lead-zinc tailing spill in Guangxi, China. Chemosphere 251. https://doi.org/10.1016/j.chemosphere.2020.126415
Ogunlaja A, Ogunlaja OO, Okewole DM, Morenikeji OA (2019) Risk assessment and source identification of heavy metal contamination by multivariate and hazard index analyses of a pipeline vandalised area in Lagos State. Nigeria Sci Total Environ 651:2943–2952. https://doi.org/10.1016/j.scitotenv.2018.09.386
Ran J, Wang D, Wang C, Zhang G, Zhang H (2016) Heavy metal contents, distribution, and prediction in a regional soil–wheat system. Sci Total Environ 544:422–431. https://doi.org/10.1016/j.scitotenv.2015.11.105
Rauret G, López-Sánchez JF, Sahuquillo A, Rubio R, Davidson C, Ure A, Quevauviller P (1999) Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials. J Environ Monit 1:57–61. https://doi.org/10.1039/a807854h
Schaider LA, Senn DB, Estes ER, Brabander DJ, Shine JP (2014) Sources and fates of heavy metals in a mining-impacted stream: Temporal variability and the role of iron oxides. Sci Total Environ 490:456–466. https://doi.org/10.1016/j.scitotenv.2014.04.126
Shu XH, Zhang Q, Lu GN, Yi XY, Dang Z (2018) Pollution characteristics and assessment of sulfide tailings from the Dabaoshan Mine, China. Int Biodeterior Biodegrad 128:122–128. https://doi.org/10.1016/j.ibiod.2017.01.012
Wang F, Guan Q, Tian J, Lin J, Yang Y, Yang L, Pan N (2020a) Contamination characteristics, source apportionment, and health risk assessment of heavy metals in agricultural soil in the Hexi Corridor. CATENA 191:104573. https://doi.org/10.1016/j.catena.2020a.104573
Wang G, Zhao W, Yuan Y, Morel JL, Chi H, Feng W, Wang S, Zhang J, Feng Z, Tan H, Chen D, Ding W, Liu C, Qiu R (2020b) Mobility of metal(loid)s in Pb/Zn tailings under different revegetation strategies. J Environ Manage 263:110323. https://doi.org/10.1016/j.jenvman.2020b.110323
Wang S, Cai L, Wen H, Luo J, Wang Q, Liu X (2019) China Sci Total Environ 655:92–101. https://doi.org/10.1016/j.scitotenv.2018.11.244. Spatial distribution and source apportionment of heavy metals in soil from a typical county-level city of Guangdong Province
Wang Z, Hong C, Xing Y, Wang K, Li Y, Feng L, Ma S (2018) Spatial distribution and sources of heavy metals in natural pasture soil around copper-molybdenum mine in Northeast China. Ecotoxicol Environ Saf 154:329–336. https://doi.org/10.1016/j.ecoenv.2018.02.048
Wu W, Guo Q, Lin T, Chinese (2017) 40(S1),33–37
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This work was supported by the National Natural Science Foundation of China (No. 41673090) and Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control (No. 2017B030301012).
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Hao, X., Yi, X., Dang, Z. et al. Heavy Metal Sources, Contamination and Risk Assessment in Legacy Pb/Zn Mining Tailings Area: Field Soil and Simulated Rainfall. Bull Environ Contam Toxicol 109, 636–642 (2022). https://doi.org/10.1007/s00128-022-03555-x
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DOI: https://doi.org/10.1007/s00128-022-03555-x