Abstract
The persistence and dissipation of a new readymix formulation of halauxifen-methyl + pyroxsulam was investigated in three soils viz. red lateritic (Soil A), coastal saline (Soil B) and black soil (Soil C) under three incubation temperatures (20, 30 and 40° C). Soil samples were fortified at 1.0 (T1) and 2.0 (T2) mg kg− 1 doses separately for both compounds. The analytical methods showed satisfactory mean recovery, precision and linearity and therefore accepted for analysis. Both molecules followed single first-order kinetics. A significant influence of soil type on the persistence of both herbicides was observed. The order of stability of halauxifen-methyl was Soil A > B > C and for pyroxsulam was Soil B > C > A. Besides, a faster rate of dissipation of halauxifen-methyl and pyroxsulam was recorded at elevated temperatures, regardless of soil type. This research will help to understand the effect of temperature on the fate of the herbicide mixture in soils of diverse agro-climatic regions.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ali S, Ullah MI, Sajjad A, Shakeel Q, Hussain A (2021) Environmental and Health Effects of Pesticide Residues. In: Inamuddin, Ahamed MI, Lichtfouse E (eds) Sustainable Agriculture Reviews. Springer, Cham, pp 311–336. https://doi.org/10.1007/978-3-030-54719-6_8
Das S, Singha D, Kundu A, Saha S, Bhattacharyya A, Roy S (2020) Effect of pH on the hydrolytic transformation of a new mixture formulation of fomesafen and quizalofop-ethyl in water. Bull Environ Contam Toxicol 104:471–476. https://doi.org/10.1007/s00128-020-02808-x
Das S, Singha D, Kundu A, Kundu A, Bhattacharyya A, Nanda MK, Roy S (2021) Effect of Soil Type and Temperature on Persistence and Dissipation Kinetics of a New Readymix Formulation of Fomesafen + Quizalofop-ethyl. Bull Environ Contam Toxicol 107:1–6. https://doi.org/10.1007/s00128-021-03375-5
Doumandji L, Moussiden A, Ihdene Z, Hamada B (2018) Hydrolytic decontamination of methyl parathion in the presence of 2-aminoethanol: kinetics study. J Pestic Sci 43:41–46
EFSA (2013) Conclusion on the peer review of the pesticide risk assessment of the active substance pyroxsulam. https://efsa.onlinelibrary.wiley.com/doi/pdf/10.2903/j.efsa.2013.3182. Accessed 13 Nov 2021
Health Canada Pest Management Regulatory Agency (2014) Halauxifen-Methyl. Proposed Registration Document: PRD2014-12. https://publications.gc.ca/collections/collection_2014/sc-hc/H113-9-2014-12-eng.pdf. Accessed 10 November 2021
Helling CS, Kearney PC, Alexander M(1971) Behavior of Pesticides in Soils. In: Brady NC (ed) Advances in Agronomy. Academic Press, pp 147–240
Hui TJ, Ariffin MM, Tahir NM (2010) Hydrolysis of chlorpyrifos in aqueous solutions at different temperatures and pH. Malaysian J Anal Sci 14:50–55
Jabusch TW, Tjeerdema RS (2005) Partitioning of penoxsulam, a new sulfonamide herbicide. J Agric Food Chem 53:7179–7183. https://doi.org/10.1021/jf050767g
Jackson R, Ghosh D, Paterson G (2000) The soil degradation of the herbicide florasulam. Pest Manag Sci 56:1065–1072
Kaur H, Kaur P (2018) Effect of soil type, moisture and temperature on the dissipation of penoxsulam in soil under laboratory conditions. Bull Environ Contam Toxicol 101:803–809. https://doi.org/10.1007/s00128-018-2452-z
Kaur P, Kaur H, Bhullar MS (2020) Influence of organic amendments on dissipation and leaching potential of penoxsulam under laboratory conditions. Int J Environ Anal Chem. https://doi.org/10.1080/03067319.2020.1748611
Meng X, Chen L, Zhang Y, Hu D, Song B (2018) Hydrolysis and photolysis kinetics, and identification of degradation products of the novel bactericide 2-(4-fluorobenzyl)-5-(methylsulfonyl)-1,3,4-oxadiazole in water. Int J Environ Res Public Health 15:2741. https://doi.org/10.3390/ijerph15122741
Saha S, Majumder S, Das S, Das TK, Bhattacharyya A, Roy S (2018) Effect of pH on the transformation of a new readymix formulation of the herbicides bispyribac sodium and metamifop in water. Bull Environ Contam Toxicol 100:548–552
SANTE (2019) Analytical quality control and method validation procedures for pesticide residues analysis in food and feed. Document No. SANTE/12682/2019. https://www.eurl-pesticides.eu/userfiles/file/EurlALL/AqcGuidance_SANTE_2019_12682.pdf. Accessed 02 Nov 2021
Steinweg JM, Dukes JS, Paul EA, Wallenstein MD (2013) Microbial responses to multi-factor climate change: effects on soil enzymes. Front Microbiol 4:1–11. https://doi.org/10.3389/fmicb.2013.00146
Su W, Xu H, Hao H, Wu R, Wang H, Lu C (2017) Effect of environmental conditions on the degradation of florasulam in typical soils of northern China. J Environ Qual 46:553–558. https://doi.org/10.2134/jeq2016.11.0449
USEPA (2007) Pyroxsulam (Sect. 3: Wheat Use). https://www3.epa.gov/pesticides/chem_search/cleared_reviews/csr_PC-108702_30-Aug-07_a.pdf. Accessed 10 November 2021
USEPA (2016) Halauxifen-methyl - New Active Ingredient Human Health Risk Assessment for Proposed Uses on Cereal Grains (Barley, Wheat, and Triticale). https://www.regulations.gov/document/EPA-HQ-OPP-2012-0919-0005. Accessed 13 Nov 2021
Acknowledgements
The authors are thankful to the Export Testing Laboratory (NABL accredited ISO/IEC 17025: 2005 certified), Bidhan Chandra Krishi Viswavidyalaya for extending the infrastructure facilities. The authors are also thankful to the Dow AgroSciences India Pvt. Ltd. for providing reference materials of the active ingredients and the formulation.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Singha, D., Das, S., Bhowmick, N. et al. Impact of soil type and temperature on dissipation dynamics of a new readymix formulation of halauxifen-methyl + pyroxsulam. Bull Environ Contam Toxicol 109, 373–378 (2022). https://doi.org/10.1007/s00128-022-03542-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00128-022-03542-2