Abstract
The hydraulic conductivity of Na-montmorillonite in dual-cation solutions of Na+ and Mn+ (Mn+ = K+, Ca2+, Zn2+ and Al3+) with a constant ionic strength of 0.1 mol/L was determined. The focus of this study was on the influence of Mn+ on the grain-size distribution of montmorillonite and hence its hydraulic conductivity. All the tested cations showed a high affinity towards montmorillonite, and the high valency favored the exchange between Mn+ and Na+. The hydraulic conductivity of montmorillonite increased to the maxima and then decreased in a left-skewed log-normal shape as the cation exchange progressed. The grain size of montmorillonite concurrently decreased monotonically with the cation exchange. The XRD patterns of montmorillonite confirmed the occurrence of demixing of Na+ and K+ in the interlayers. It is proposed that the rearrangement and reaggregation of grains during cation exchange occurred, leading to variations in the hydraulic conductivity of montmorillonite.
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Al-Bazali T (2021) Insight on the inhibitive property of potassium ion on the stability of shale: a diffuse double-layer thickness (κ – 1) perspective. J Petroleum Explor Prod Technol 11:2709–2723
Arya LM, Leij FJ, Shouse PJ, Van Genuchten MT (1999) Relationship between the hydraulic conductivity function and the particle-size distribution. Soil Sci Soc Am J 67:1063–1070
Bergaya F, Theng BKG, Lagaly G (2006) Handbook of clay science. Elsevier, p 1224
Brooks RH (1964) Hydraulic properties of porous media. McGill-Queen’s University Press, pp 352–366
Castellanos E, Villar MV, Romero E, Lloret A, Gens A (2008) Chemical impact on the hydro-mechanical behaviour of high-density FEBEX bentonite. Phys Chem Earth 33:516–526
Chen YG, Zhu CM, Ye WM, Cui YJ, Wang Q (2015) Swelling pressure and hydraulic conductivity of compacted GMZ01 bentonite under salinization-desalinization cycle conditions. Appl Clay Sci 114:454–460
Chapman DL (1913) A Contribution to the Theory of Electrocapillarity. Phil Mag 25:475–481
Cronican AE, Gribb MM (2004) Hydraulic conductivity prediction for sandy soils. Ground Water 42:459
Derjaguin B (1954) A theory of the heterocoagulation, interaction and adhesion of dissimilar particles in solutions of electrolytes. Discuss Faraday Soc 18:85–98
Dixon JB, Schulze DG (2002) Soil mineralogy with environmental applications. SSSA Inc., Madison, WI, USA, p 864
Durner W (1994) Hydraulic conductivity estimation for soils with heterogeneous pore structure. Water Resour Res 30:211–223
Farthing MW, Ogden FL (2017) Numerical solution of Richards’ equation: a review of advances and challenges. Soil Sci Soc Am J 81(6):1257–1269
Felhendler R, Shainberg I, Frenkel H (1974) Dispersion and the hydraulic conductivity of soils in mixed solutions. Proceedings of the Transition of the 10th International Congress of Soil Science pp 103–112
Feng J, Yu Q, He A, Sheng GD (2021a) Accelerating Cu and Cd removal in soil flushing assisted by regulating permeability with electrolytes. Chemosphere 281:130883
Feng J, Yu Q, He A, Sheng GD (2021b) A theoretical model for the hydraulic conductivity of montmorillonite in relation to the concentration and valence of electrolyte cations in solution. J Hydrol 600:126567
Frenkel H, Rhoades JD (1978) Effects of dispersion and swelling on soil hydraulic conductivity. J Test Eval 6:60–65
Ghanbarian-Alavijeh B, Liaghat AM, Sohrabi S (2010) Estimating saturated hydraulic conductivity from soil physical properties using neural networks model. World Academy of Science Engineering & Technology, pp 108–113
Gouy M (1910) Sur la constitution de la charge électrique à la surface d’un électrolyte, 457–468
Hernández A, Arcos J, Martínez-Trinidad J, Bautistab O, Sánchezc S, Méndezd F (2022) Thermodiffusive effect on the local Debye-length in an electroosmotic flow of a viscoelastic fluid in a slit microchannel. Int J Heat Mass Transf 187:122522
Hogg R, Healy TW, Fuerstenau DW (1966) Mutual coagulation of colloidal dispersions. Trans Faraday Soc 62:1638–1651
Hwang SI, Powers SE (2003) Using Particle-Size Distribution Models to Estimate Soil Hydraulic Properties. Soil Sci Soc Am J 67:1103–1112
Jo HY, Katsumi T, Benson CH, Edil TB (2001) Hydraulic conductivity and swelling of nonprehydrated GCLs permeated with single-species salt solutions. J Geotech GeoEnviron Eng 127:557–567
Kolstad DC, Benson CH, Edil TB (2004) Hydraulic conductivity and swell of nonprehydrated geosynthetic clay liners permeated with multispecies inorganic solutions. J Geotech GeoEnviron Eng 130:1236–1249
Kunze RJ, Uehara G, Graham K (1968) Factors Important in the Calculation of Hydraulic Conductivity. Soil Sci Soc Am J 32:760–765
Laird DA (2006) Influence of layer charge on swelling of smectites. Appl Clay Sci 34:74–87
Li H, Teppen BJ, Laird DA, Johnston CT, Boyd SA (2004) Geochemical modulation of pesticide sorption on smectite clay. Environ Sci Technol 38(20):5393–5399
McBride MB (1994) Environmental chemistry of soils, 256 edn. Oxford University Press
Rawls WJ, Brakensiek DL, Logsdon SD (1993) Predicting Saturated Hydraulic Conductivity Utilizing Fractal Principles. Soil Sci Soc Am J 57:1193
Saary J, Qureshi R, Palda V, DeKoven J, Pratt M, Skotnicki-Grant S, Holness L (2005) A systematic review of contact dermatitis treatment and prevention. J Am Acad Dermatol 53:845
Shainberg I, Otoh H (1968) Size and shape of montmorillonite particles saturated with Na/Ca ions (inferred from viscosity and optical measurements). Isr J Chem 6:251–259
Sposito G (2008) The chemistry of soils, 329 edn. Oxford university press
Stern O (1924) The theory of the electrolytic double-layer. Z Elektrochem 30:1014–1020
Suzuki S, Noble AD, Ruaysoongnern S, Chinabut N (2007) Improvement in water-holding capacity and structural stability of a sandy soil in Northeast Thailand. Arid land research and management 21:37–49
Vereecken H, Maes J, Feyen J (1990) Estimating unsaturated hydraulic conductivity from easily measured soil properties. Soil Sci 149:1–12
Vogel HJ, Roth K (1998) A new approach for determining effective soil hydraulic functions. Eur J Soil Sci 49:547–556
Von Helmholtz H (1879) Studies of electric boundary layers. Wied Ann 7:337–382
Wosten JHM (1988) Using texture and other soil properties to predict the unsaturated soil hydraulic functions. Soil Sci Soc Am J 52:1762–1770
Zhang F, Ye WM, Wang Q, Chen YG, Chen B (2019) An insight into the swelling pressure of GMZ01 bentonite with consideration of salt solution effects. Eng Geol 251:190–196
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Funding for this project was provided by the Entrepreneurship and Innovation Program of Jiangsu Province (Project No. 2018 − 2017).
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Feng, J., Yu, Q., He, A. et al. Variations in Hydraulic Conductivity of Montmorillonite in Dual-Cation Electrolyte Solutions. Bull Environ Contam Toxicol 109, 358–363 (2022). https://doi.org/10.1007/s00128-022-03484-9
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DOI: https://doi.org/10.1007/s00128-022-03484-9