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Assessment of 20 Organochlorine Pesticides (OCPs) Pollution in Suburban Soil in Tianjin, China

Abstract

Soil contamination with organochlorine pesticides has aroused worldwide concerns considering their high toxicities and long-term persistence. In this study, 87 representative soil samples from suburban areas (Xiqing, Dongli, Jinnan, Beichen) of Tianjin, the third biggest city in China, were collected to evaluate the pollution of 20 organochlorine pesticides. Surface soil samples were air-dried and sieved. Ultrasonic extraction was used for organochlorine pesticides preparation prior to analysis with gas chromatography–mass spectrometry. It was revealed that p,p′-DDE, p,p′-DDD, o,p′-DDT, o,p′-DDD, hexachlorobenzene, dicofol and β-HCH were seven pesticides detected most frequently. DDTs, HCHs and hexachlorobenzene were the predominant pesticide pollutants in soil. Spatial variation of these organochlorine pesticides in soil was illustrated; Pollution levels, characteristics and possible sources were also investigated. Most of other 13 kinds of pesticides were detected and the frequencies of detection were calculated to reveal the pollution status, which ranged from 0.0% (aldrin, dieldrin and endrin) to 34.5% (p,p′-DDT). These data were helpful to figure out the pollution of organochlorine pesticides and could be further used to evaluate the health risk associated with soil pollution.

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References

  • Fu S, Cheng HX, Liu YH, Xu XB (2009) Levels and distribution of organochlorine pesticides in various media in a mega-city, China. Chemosphere 75:588–594

    Article  CAS  Google Scholar 

  • Gong ZM, Cao J, Zhu XM, Cui YH, Guo LQ, Tao S, Shen WR, Zhao XM, Han LX (2002) Organochlorine pesticide residues in agricultural soils from Tianjin. Agro-Environ Protect 21:459–461 in Chinese

    Google Scholar 

  • Harris ML, Wilson LK, Elliott JE, Bishop CA, Tomlin AD, Henning KV (2000) Transfer of DDT and metabolites from fruit orchard soils to American Robins (Turdus migratorius) twenty years after agricultural use of DDT in Canada. Arch Environ Contam Toxicol 39:205–220

    Article  CAS  Google Scholar 

  • Jiang YF, Wang XT, Jia Y, Wang F, Wu MH, Sheng GY, Fu JM (2009) Occurrence, distribution and possible sources of organochlorine pesticides in agricultural soil of Shanghai, China. J Hazard Mater 170:989–997

    Article  CAS  Google Scholar 

  • NY/T 761-2004 Determination of organophosphorus pesticides, organochlorine pesticides, pyrethroids, carbamates residues in vegetable and fruit (in Chinese)

  • Qiu XH, Zhu T, Yao B (2005) Contribution of dicofol to the current DDT pollution in China. Environ Sci Technol 39:4385–4390

    Article  CAS  Google Scholar 

  • Wang XJ, Piao XY, Chen J, Hu JD, Xu FL, Tao S (2006) Organochlorine pesticides in soil profiles from Tianjin, China. Chemosphere 64:1514–1520

    Article  CAS  Google Scholar 

  • Willett KL, Ulrich EM, Hites RA (1998) Differential toxicity and environmental fates of hexachlorocyclohexane isomers. Environ Sci Technol 32:2197–2207

    Article  CAS  Google Scholar 

  • Yang RQ, Lv AH, Shi JB, Jiang GB (2005) The levels and distribution of organochlorine pesticides (OCPs) in sediments from the Haihe River, China. Chemosphere 61:347–354

    Article  CAS  Google Scholar 

  • Zhang HB, Luo YM, Zhao QG, Zhang GL, Huang MH (2006) Soil research in Hongkong-IV content and component of organochlorine compounds in soil. Acta Pedol Sin 43:220–225 (in Chinese)

    CAS  Google Scholar 

  • Zheng XY, Liu XD, Liu WJ, Jiang GB, Yang RQ (2009) Levels and source analysis of organochlorine pesticides in Wolong natural reserve soils. Chin Sci Bull 54:33–40

    Google Scholar 

  • Zheng XY, Chen DZ, Liu XD, Zhou QF, Liu Y, Yang W, Jiang GB (2010) Spatial and seasonal variations of organochlorine compounds in air on an urban–rural transect across Tianjin, China. Chemosphere 78:92–98

    Article  CAS  Google Scholar 

  • Zhu YF, Liu H, Xi ZQ, Cheng HX, Xu XB (2005) Organochlorine pesticides (DDTs and HCHs) in soils from the outskirts of Beijing, China. Chemosphere 60:770–778

    Article  CAS  Google Scholar 

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Correspondence to Jungang Lv.

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Lv, J., Shi, R., Cai, Y. et al. Assessment of 20 Organochlorine Pesticides (OCPs) Pollution in Suburban Soil in Tianjin, China. Bull Environ Contam Toxicol 85, 137–141 (2010). https://doi.org/10.1007/s00128-010-0048-3

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  • DOI: https://doi.org/10.1007/s00128-010-0048-3

Keywords

  • Organochlorine pesticides (OCPs)
  • Soil
  • Suburban
  • Tianjin