Abstract
Mean concentrations of selected USEPA priority polycyclic aromatic hydrocarbons (PAHs) in surface sediments and water samples from Car Wash and Kisat areas of Winam Gulf, Lake Victoria in Kenya have been determined using GC-FID and GC-MS. Sampling was done during the rainy season in April 2006. The PAH concentrations in sediment and water ranged from 0.04 to 31.95 μg/g dry weight and 3.32 to 55.8 μg/L, respectively, depending upon the sampling location. The total concentration levels of PAHs in both the sediment and water phase in this study were found to be much higher compared with those reported from other regions worldwide, revealing significant PAH pollution of Car Wash and Kisat areas of Kisumu city bay as a consequent of anthropogenic activities as described in the text. The GC-detected PAHs were confirmed by GC-MS.
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References
ATSDR (1995) Agency for toxic substances and disease registry (ATSDR) toxicological profile for polycyclic aroatic hydrocarbons (PAHs). U.S. Department of Health and Human Services, Atlanta
Baumard P, Budzinski H, Michon Q, Garrigues P, Burgeot T, Bellocq J (1998) Origin and bioavailability of PAHs in the mediterranean sea from mussel and sediment records. Estuar Coast Shelf S 47:77–90
Christopher DS, William RC, Kristine B, Quinlan K, Reimer R (1995) Methodology for the determination of priority pollutant polycyclic aromatic hydrocarbons in marine sediments. Chemosphere 9:4143–4155
David N, Nancy L (1995) Identification of pollution sources in the Kenyan part of the Lake Victoria catchment area. A Kenya-Belgiam joint project in fresh water ecology. National Environmental Management Agency, Nairobi
Gogou A, Stratigakis N, Kanakidou M, Stephanou EG (1996) Organic aerosols in Eastern Mediterranean: components source reconciliation by using molecular markers and atmospheric back trajectories. Org Geochem 25:79–96
Hallet DJ, Brecher RW (1984) Toxic contaminants in the Great Lakes. Willey, New York
Heidelberger C (1976) In: Freudenthal R, Jones PW (eds) Carcinogenesis—a comprehensive survey, vol 1. Polynuclear aromatic hydrocarbons: chemistry, metabolism and carcinogenesis. Raven Press, New York
Hostettler FD, Pereira WE, Kvenvolden KA, Van Green A, Luoma SN, Fuller CC, Anima R (1999) A record of hydrocarbon input to San Francisco Bay as traced by biomarker profiles in surface sediment and sediment core. Mar Chem 64:115–127
IARC (1983) International agency for research on cancer, IARC monographs on the evaluation of the carcinogenic risk of chemicals to human. Polynuclear Aromatic Compounds, Part I chemical environmental and experimental data. World Health Organization, Geneva
Ko FC, Baker JE (1995) Partitioning of Hydrophobic organic contaminants to resuspended sediments and planktons in the mesahaline Chesapeake Bay. Mar Chem 49:171–188
Kwach OB (2008) Assessment of cyclic polynuclear aromatic hydrocarbon distribution in Winam Gulf, Lake Victoria, Kenya. M.Sc. thesis, Maseno University
Li G, Xia X, Yang Z, Wang R, Voulvoulis N (2006) Distribution and sources of polycyclic aromatic hydrocarbons in the middle and lower reaches of the Yellow River, China. Environ Pollut 144:985–993
McVeety BD, Hites RA (1988) Atmospheric deposition of polycyclic aromatic hydrocarbons to water surfaces: a mass balance approach. Atmos Environ 22:511–536
Readman JW, Mantoura RFC, Rhead MM (1984) The Physico-chemical specification of polycyclic aromatic hydrocarbons (PAH) in the aquatic system. Anal Chem 319:126–138
SEPA, State Environmental Protection Administration of China (2002) Monitoring and analytical method on water and waste water, 4th edn. China Environmental Science Press, Beijing
UNEP, United Nations Environmental Programme (1992) Determination of petroleum hydrocarbons in sediments. Reference methods for marine pollution studies no. 20. Monaco
Wakeham SG (1996) Aliphatic and polycylic aromatic hydrocarbons in Black Sea sediments. Mar Chem 53:187–195
Wakeham SG, Farrington JW (1980) Hydrocarbons in contemporary aquatic sediments. In: Petrakis C, Weiss FT (eds) Petroleum in the marine environment. ACS advances in chemistry series no. 185. American Chemical Society, Washington DC
WHO (1998) World Health Organization, International programme on chemical safety. Environmental health criteria 202: selected non-heterocyclic polycyclic aromatic hydrocarbons. WHO, Geneva
Witt G (1995) Polycyclic aromatic hydrocarbons in water and sediments of the Baltic Sea. Mar Pollut Bull 31:237–246
Yunker MB, Snowdon LR, Macdoland RW, Smith JN, Fowler MG, Skibo DN, McLaughlin FA, Danyushevskaya AI, Petrova VI, Ivanov GI (1996) Polycyclic aromatic hydrocarbon composition and potential sources for sediment samples from the Beaufort and Barents Seas. Environ Sci Technol 30:1310–1320
Acknowledgments
This work was supported by the Department of Chemistry, Maseno University in Kenya. We acknowledge Prof Dr. K.-W. Schramm, Helmholtz Zentrum, Munich for PAH standards and the Department of Physical Sciences, Masinde Muliro University of Science and Technology-Kenya, for assistance during laboratory analysis.
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Kwach, B.O., Lalah, J.O. High Concentrations of Polycyclic Aromatic Hydrocarbons Found in Water and Sediments of Car Wash and Kisat Areas of Winam Gulf, Lake Victoria-Kenya. Bull Environ Contam Toxicol 83, 727–733 (2009). https://doi.org/10.1007/s00128-009-9859-5
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DOI: https://doi.org/10.1007/s00128-009-9859-5