Abstract
The paper describes disseminated tabular, podiform massive, and transitional chromitite deposits from a mantle section of the Kraka ophiolite massif, South Urals, Russia. The chromitite is hosted by dunite with no correlation between their size and quality and the size of the dunite bodies. Thick dunite bodies mostly host disseminated fine-grained banded chromitite; massive ores are composed of coarse-grained chromitite typically with a thin dunite envelope. The chromitite and host ultramafic rocks exhibit plastic deformation of silicates and chromite, which is expressed in microstructural features, preferred orientation of rock-forming olivine, and folding of the chromitite bodies. The ultramafic rocks are also characterized by deformation-induced textures leading to the formation of the small-size chromite grains on structural defects of plastically deformed rock-forming olivine and orthopyroxene. The formation of dunite bodies and associated chromitite is related to the localization of deformation of rising mantle flows under decompression conditions. Dunite was the most rheologically weak zone exhibiting a focused solid state flow and effective separation of mineral phases (olivine and chromite). The higher amount of the latter in dunite is a result of deformation-induced breakdown of enstatite and removal of trace elements from olivine. The structural features of massive chromitite aggregates indicate that they are a product of concentration and aggregation of grains under the influence of tectonic stresses at high temperatures and pressures, similar to pressure sintering.
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References
Ahmed Z (1984) Stratigraphic and textural variations in the chromite composition of the ophiolitic Sakhakot-Qila complex, Pakistan. Econ Geol 79:1334–1359
Anderson DL (1989) Theory of the Earth. Blackwell scientific publication, Boston, Oxford, London, Edinburgh, Melburn
Arai S, Akizawa N (2014) Precipitation and dissolution of chromite by hydrothermal solutions in the Oman ophiolite: new behavior of Cr and chromite. Am Mineral 99:28–34
Arai S, Miura M (2016) Formation and modification of chromitites in the mantle. Lithos 264:277–295
Ballhaus C (1998) Origin of the podiform chromite deposits by magma mingling. Earth Planet Sci Lett 156:185–193
Barnes S, Roeder P (2001) The range of spinel compositions in terrestrial mafic and ultramafic rocks. J Petrol 42:2279–2302. https://doi.org/10.1093/petrology/42.12.2279
Borisova AY, Ceuleneer G, Kamenetsky VS, Arai S, Béjina F, Abily B, Bindeman IN, Polvé M, De Parseval P, Aigouy T, Pokrovski GS (2012) A new view on the petrogenesis of the Oman ophiolite chromitites from microanalyses of chromite-hosted inclusions. J Petrol 53:2411–2440
Bunin KP, Baranov AA (1970) Metallography. Metallurgiya, Moscow (in Russian)
Carter NL (1976) Steady state flow of rocks. Rev Geophys Space Phys 14:301–360
Cassard D, Nicolas A, Rabinowitch M, Moutte J, Leblanc M, Prinzhoffer A (1981) Structural classification of chromite pods in Southern New Caledonia. Econ Geol 76:805–831
Chernyshov AI (2001) Ultramafic rocks (plastic flow, structural and petrostructural heterogeneity). Charodey, Tomsk (in Russian)
Coccomazi G, Grieco G, Tartarotti P, Bussolesi M, Zaccarini F, Crispini L, Oman Drilling Project Science Team (2020) The formation of dunite channels within harzburgite in the Wadi Tayin Massif, Oman Ophiolite: insights from compositional variability of Cr-Spinel and olivine in Holes BA1B and BA3A, Oman Drilling Project. Minerals 10:167. https://doi.org/10.3390/min10020167
Dickey JS (1975) A hypothesis of origin for podiform chromite deposits. Geochim Cosmochim Acta 39:1061–1075
Dodd RT (1973) Minor element abundances in olivines of the Sharps (H3) chondrite. Contrib Mineral Petrol 42:156–167
El Dien HG, Arai S, Doucet L-S, Li Z-X, Kil Y, Fougerouse D, Reddy SM, Saxey DW, Hamdy M (2019) Cr-spinel records metasomatism not petrogenesis of mantle rocks. Nat Commun 10:5103. https://doi.org/10.1038/s41467-019-13117-1
Fedoseev VB (2016) Stratification of two-phase monodisperse system in a laminar planar flow. J Exp Theor Phys 149(4):1057–1067. https://doi.org/10.1134/S1063776116040142
Franz L, Wirth R (2000) Spinel inclusions in olivine of peridotite xenoliths from TUBAF seamount (Bismarck Archipelago/Papua New Guinea): evidence for the thermal and tectonic evolution of the oceanic lithosphere. Contrib Mineral Petrol 140:283–295
Ghosh B, Ray J, Morishita T (2014) Grain-scale plastic deformation of chromite from podiform chromitite of the Naga-Manipur ophiolite belt, India: implication to mantle dynamics. Ore Geol Rev 56:199–208. https://doi.org/10.1016/j.oregeorev.2013.09.001
Ghosh B, Misra S, Morishita T (2017) Plastic deformation and post-deformation annealing in chromite: Mechanisms and implications. Am Mineral 102:216–226
Goncharenko AI (1989) Deformation and petrostructural evolution of Alpine-type ultramafic rocks. Tomsk University Publishing, Tomsk (in Russian)
Gonzalez-Jimenez JM, Proenza JA, Gervilla F, Melgarejo JC, Blanco-Moreno JA, Ruiz-Sanchez R, Griffin WL (2011) High-Cr and high-Al chromitites from the Sagua de Tanamo district, Mayari-Cristal ophiolitic massif (eastern Cuba): constrains on their origin from mineralogy and geochemistry of chromian spinel and platinum-group-elements. Lithos 125:101–121. https://doi.org/10.1016/j.lithos.2011.01.016
Gonzalez-Jimenez JM, Griffin WL, Proenza A, Gervilla F, O'Reilly SY, Akbulut M, Pearson NJ, Arai S (2014) Chromitites in ophiolites: how, where, when, why? Part II The crystallisation of chromitites. Lithos 189:148–158. https://doi.org/10.1016/j.lithos.2013.09.008
Gorelik SS (1978) Recrystallization of metals and alloys. Metallurgiya, Moscow (in Russian)
Greenbaum D (1977) The chromitiferous rocks of the Troodos ophiolite complex, Cyprus. Econ Geol 72:1175–1194
Hock M, Friedrich G (1985) Structural features of ophiolitic chromitites in the Zambales Range, Luzon, Philippines. Mineral Deposita 20:290–301
Hock M, Friedrich G, Plueger WL, Wichowski A (1986) Refractory- and metallurgical-type chromite ores, Zambales Ophiolite, Luzon, Philippines. Mineral Deposita 21:190–199
Jochum KP, Willbold M, Raczek I, Stoll B, Herwig K (2005) Chemical characterisation of the USGS Reference Glasses GSA-1G, GSC-1G, GSD-1G, GSE-1G, BCR-2G, BHVO-2G and BIR-1G using EPMA, ID-TIMS, ID-ICP-MS and LA-ICP-MS. Geostand Geoanal Res 29(3):285–302. https://doi.org/10.1111/j.1751-908X.2005.tb00901.x
Jochum KP, Weis U, Stoll B, Kuzmin D, Yang Q, Raczek I, Jacob DE, Stracke A, Birbaum K, Frick DA (2011) Determination of reference values for NIST SRM 610–617 glasses following ISO guidelines. Geostand Geoanal Res 35(4):397–429. https://doi.org/10.1111/j.1751-908X.2011.00120.x
Johan Z, Martin RF, Ettler V (2017) Fluids are bound to be involved in the formation of ophiolitic chromite deposits. Eur J Mineral 29:543–555
Johnson C (2012) Podiform chromite at Voskhod, Kazakhstan. Cardiff University, Dissertation
Jung H (2017) Crystal preferred orientations of olivine, orthopyroxene, serpentine, chlorite, and amphibole, and implications for seismic anisotropy in subduction zones: a review. Geosci J 21(6):985–1011. https://doi.org/10.1007/s12303-017-0045-1
Kapsiotis A, Rassios AE, Uysal I, Grieco G, Akmaz RM, Saka S, Bussolesi M (2018) Compositional fingerprints of chromian spinel from the refractory chrome ores of Metalleion, Othris (Greece): implications for metallogeny and deformation of chromitites within a “hot” oceanic fault zone. J Geochem Explor 185:14–32. https://doi.org/10.1016/j.gexplo.2017.11.003
Karato S-I (2008) Deformation of Earth materials. Cambridge University Press, An introduction to the rheology of solid Earth, 463 p
Kazantseva TT (1987) Allochthonous structures and an origin of the Uralian crust. Nauka, Moscow (in Russian)
Kelemen PB, Dick HJB, Quick JE (1992) Formation of harzburgite by pervasive melt/rock reaction in the upper mantle. Nature 358:635–641
Kelemen PВ, Shimizu N, Salters VJM (1995) Extraction of mid-ocean-ridge basalt from the upwelling mantle by focused flow of melt in dunite channels. Nature 375:747–753
Kelemen PВ, Hirth G, Shimizu N, Spiegelman M, Dick HJB (1997) A review of melt migration processes in the adiabatically upwelling mantle beneath oceanic spreading ridges. Philos Trans R Soc Lond Ser A 355:283–318
Kiseleva ON, Airiyants EV, Belyanin DK, Zhmodik SM (2020) Podiform chromitites and PGE mineralization in the Ulan-Sar’dag ophiolite (East Sayan, Russia). Minerals 10:141. https://doi.org/10.3390/min10020141
Kohlstedt DL, Goetze C, Durham WB, van der Sande JB (1976) A new technique for decorating dislocations in olivine. Science 191:1045–1046
Lago BL, Rabinowicz M, Nicolas A (1982) Podiform chromite ore bodies: a genetic model. J Petrol 23:103–125
Leblanc M, Ceuleneer G (1992) Chromite crystallization in a multicellular magma flow: evidence from a chromitite dike in the Oman ophiolite. Lithos 27:231–257
Leblanc M, Violette J-F (1983) Distribution of aluminium-rich and chromium-rich chromite pods in ophiolite peridotites. Econ Geol 78:293–301
Matveev S, Ballhaus C (2002) Role of water in the origin of podiform chromitite deposits. Earth Planet Sci Lett 203:235–243. https://doi.org/10.1016/S0012-821X(02)00860-9
McLaren AC, Etheridge MA (1976) A transmission electron microscope study of naturally deformed orthopyroxene. I. Slip mechanisms. Contrib Mineral Petrol 57:163–177
Melcher F, Grum W, Simon G, Thalhammer TV, Stumpfl EF (1997) Petrogenesis of the ophiolitic giant chromite deposits of Kempirsai, Kazakhstan: a study of solid and fluid inclusions in chromite. J Petrol 38:1419–1458
Morishita T, Andal ES, Arai S, Ishida Y (2006) Podiform chromitites in the lherzolite-dominant mantle section of the Isabela ophiolite, the Philippines. Island Arc 15:84–101. https://doi.org/10.1111/j.1440-1738.2006.00511.x
Nicolas A, Bouchez JL, Boudier F, Mercier JC (1971) Textures, structures and fabrics due to solid state flow in some European lherzolites. Tectonophysics 12:55–86
Novikov II (1986) Theory of thermal processing of metals. Metallurgiya, Moskow (in Russian)
Ozawa K (1989) Stress-induced Al–Cr zoning of spinel in deformed peridotites. Nature 338:141–144
Poirier J-P (1985) Creep of crystals. High-temperature deformation processes in metals, ceramics and minerals. Cambridge University Press. London
Puchkov VN (1997) Structure and geodynamics of the Uralian orogen. In Orogeny Through Time. Published by The Geological Society London. Ed. J.-P. Burg and M. Ford. P.201–236.
Puchkov VN (2002) Paleozoic evolution of the East European continental margin involved into the Urals. Mountain Building in the Uralides: Pangea to the Present. AGU Geophysics. Monogr. Ser. 132:9–32.
Pushkarev EV, Kamenetsky VS, Morozova AV, Khiller VV, Glavatskykh SP, Rodemann T (2015) Ontogeny of ore Cr-spinel and composition of inclusions as indicators of the pneumatolytic–hydrothermal origin of PGM-bearing chromitites from Kondyor massif, the Aldan Shield. Geol Ore Depos 57:352–380
Ringwood AE (1975) Composition and structure of the Earth’s mantle. McGraw-Hill, New York
Rost F (1959) Probleme ultrabasischer Gesteine und ihrer Lagerstatten. Freiberger Forschungshefte, Berlin
Satsukawa T, Piazolo S, González-Jiménez J-M, Colás V, Griffin WL, O'Reilly SY, Gervilla F, Fanlo I, Kerestedjian TN (2015) Fluid-present deformation aids chemical modification of chromite: Insights from chromites from Golyamo Kamenyane, SE Bulgaria. Lithos 228–229:78–89. https://doi.org/10.1016/j.lithos.2015.04.020
Saveliev DE, Artemyev DA (2021) Geochemical features of plastically deformed olivine from ophiolite peridotites and dunites of Kraka massifs (the Southern Urals). Zapiski RMO 150(1) (in press) (in Russian)
Saveliev DE, Blinov IA (2015) Syndeformation chrome spinel exsolutions in plastically deformed olivine aggregates (Kraka ophiolite, South Urals). Vestnik Permskogo Universiteta. Geologiya 4(29):45–69 (in Russian). doi: 10.17072/psu.geol.29.44
Saveliev DE, Blinov IA (2017) Compositional variations of chrome spinels in ore-bearing zones of the Kraka ophiolite and origin of chromitite. Vestnik Permskogo universiteta. Geologiya 16(2):130–156. DOI: 10.17072/psu.geol.16.2.130
Saveliev DE, Fedoseev VB (2011) Segregation mechanism of formation of chromitites in ultramafic rocks of fold belts. Rudy Metally 5:35–42 (in Russian)
Saveliev DE, Fedoseev VB (2014) Plastic flow and rheomorphic differentiation of mantle ultramaflc rocks. Vestnik Permskogo Universiteta. Geologiya 4(25):22-41 (in Russian) doi: 10.17072/psu.geol.25.22
Saveliev DE, Fedoseev VB (2019) Solid-state redistribution of mineral particles in the upwelling mantle flow as a mechanism of chromite concentration in the ophiolite ultramafic rocks (by the example of Kraka ophiolite, the Southern Urals). Georesources 21(1):31–46. https://doi.org/10.18599/grs.2019.1.2-10
Saveliev DE, Snachev VI, Savelieva EN, Bazhin EA (2008) Geology, petrogeochemistry, and chromite content of gabbro-ultramafic massifs of the South Urals. DizaynPoligrafServis, Ufa (in Russian)
Saveliev DE, Puchkov VN, Sergeev SN, Musabirov II (2017) Deformation-induced decomposition of enstatite in mantle peridotite and its role in partial melting and chromite ore formation. Dokl Earth Sci 476:1058–1061
Savelieva GN (1987) Gabbro-ultramafic complexes of the Uralian ophiolites and their analogs in the present-day oceanic crust. Nauka, Moscow (in Russian)
Senchenko GS (1976) Fold structures of the South Urals. Nauka, Moscow (in Russian)
Shcherbakov SA (1990) Plastic deformations of ultramafic rock of the Uralian ophiolite association. Nauka, Moscow (in Russian)
Shiryaev PB, Vakhrusheva NV (2017) Chemical zoning of spinels and olivines from chromitites and the enclosing ultramafites of the Rai-Iz massif, Tsentralnoe deposit (the Polar Urals). News of the Ural State Mining University, 4:29–35. DOI 10.21440/2307-2091-2017-4-29-35
Shiryaev PB, Vakhrusheva NV (2018) The redox state of chromitites from the Yambotyvissky area (Voikar-Syninsky massif, Polar Urals). News Ural State Min Univ 4(52):33–40. https://doi.org/10.21440/2307-2091-2018-4-33-40
Skrotzki W (1994) Defect structure and deformation mechanisms in naturally deformed augite and enstatite. Tectonophysics 229:43–68
Spiegelman M, Kelemen PB, Aharonov E (2001) Causes and consequences of flox organization during melt transport: the reaction infiltration instability in compactible media. J Geophys Res 106:2061–2077. https://doi.org/10.1029/2000JB900240
Spray JG (1988) Generation and crystallization of an amphibolite shear melt: an investigation using radial friction welding apparatus. Contrib Mineral Petrol 99:464–475
Spray JG (1992) A physical basis for the frictional melting of some rock-forming minerals. Tectonophysics 204:205–221
Stoll WC (1958) Geology and petrology of the Masinloc chromite deposit, Zambales, Luzon, Philippine islands. Bull Geol Soc Am 89:410–448
Stünitz H (1998) Syndeformational recrystallization ± dynamic or compositionally induced? Contrib Mineral Petrol 131:219–236
Suzuki AM, Yasuda A, Ozawa K (2008) Cr and Al diffusion in chromite spinel: experimental determination and its implication for diffusion creep. Phys Chem Miner 35:433–445
Thayer TP (1964) Principal features and origin of podiform chromite deposits, and some observations on the Guleman-Soridag District, Turkey. Econ Geol 59:1497–1524
Van Duysen JC, Doukhan N, Doukhan JC (1985) Transmission electron micro-scope study of dislocations in orthopyroxene (Mg, Fe)2 Si2O6. Phys Chem Miner 12:39–44
White JC, White SH (1981) The structure of grain boundaries in tectonites. Tectonophysics 78:613–628
Yamamoto J, Kagi H, Kaneoka I, Lai Y, Prikhod'ko VS, Arai S (2002) Fossil pressures of fluid inclusions in mantle xenoliths exhibiting rheology of mantle minerals: implications for the geobarometry of mantle minerals using micro Raman spectroscopy. Earth Planet Sci Lett 198:511–519. https://doi.org/10.1016/S0012-821X(02)00528-9
Yamamoto J, Ando J, Kagi H, Inoue T, Yamada A, Yamazaki D, Irifune T (2008) In situ strength measurements on natural upper-mantle minerals. Phys Chem Miner 35:249–257. https://doi.org/10.1007/s00269-008-0218-6
Zagrtdenov NR, Ceuleneer G, Rospabe M, Borisova AY, Toplis M, Benoit M, Abily B (2018) Anatomy of a chromitite dyke in the mantle/crust transition zone of the Oman ophiolite. Lithos 312–313:343–357. https://doi.org/10.1016/j.lithos.2018.05.012
Zhang RY, Shu JF, Mao HK, Liou JG (1999) Magnetite lamellae in olivine and clinohumite from Dabie UHP ultramafic rocks, central China. Am Mineral 84:564–569
Zhou MF, Robinson PT, Bai WJ (1994) Formation of podiform chromites by melt/rock interaction in the upper mantle. Mineral Deposita 29:98–101
Zhou M-F, Robinson PT, Malpas J, Li Z (1996) Podiform chromitites in the Luobusa Ophiolite (Southern Tibet): implications for melt-rock interaction and chromite segregation in the upper mantle. J Petrol 37:3–21
Zhou M-F, Robinson PT, Malpas J, Aitchison J, Sun M, Bai WJ, Hu XF, Yang JS (2001) Melt/rock interaction and melt evolution in the Sartohay high-Al chromite deposit of the Dalabute ophiolite (NW China). J Asian Earth Sci 19:519–536
Acknowledgements
The author is grateful to Z. Vukmanovich, M. Fiorentini, W. Maier, and two anonymous reviewers and Editor-in-Chief Georges Beaudoin for their useful comments; I.A. Blinov (Institute of Mineralogy, SU FRC MB UB RAS, Miass), S.N. Sergeev, and I.I. Musabirov (Institute for Superplasticity of Metals, Ufa) for SEM studies; V.V. Shilovskikh (St. Petersburg State University, St. Petersburg) for EBSD analysis; and D.A. Artemyev (Institute of Mineralogy, SU FRC MB UB RAS, Miass) for LA-ICP-MS studies.
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This work was supported by the Government of the Russian Federation (projects nos. 0252–2017–0014 and 0246–2019–0078).
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Saveliev, D.E. Chromitites of the Kraka ophiolite (South Urals, Russia): geological, mineralogical and structural features. Miner Deposita 56, 1111–1132 (2021). https://doi.org/10.1007/s00126-021-01044-5
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DOI: https://doi.org/10.1007/s00126-021-01044-5