Abstract
The Nimbus Ag–Zn(–Au) deposit is a hybrid VHMS deposit with epithermal characteristics formed in the Eastern Goldfields Superterrane, Yilgarn Craton, under shallow water (~ 700 mbsl), low-temperature conditions. Intersections of some ore lenses are high-grade and polymetallic, making similar styles of mineralization attractive Yilgarn exploration targets. The mineralization at Nimbus is hosted by a bimodal felsic–mafic succession of volcanic rocks, which are overlain by a succession of least-altered polymict conglomerates with a carbonaceous to dacitic matrix. A new Re–Os age (2680 ± 34 Ma; nodular pyrite and black shale) suggests that the overlying polymict conglomerate is coeval to ~ 2.70 Ga volcanism and mineralization at Nimbus. The pyrite within the high-grade polymetallic sulfide assemblages has a consistently lower Sb/Ag ratio (1–30) than pyrite from other sulfide phases (e.g., 30 to 1000 in colloform and barren pyrite). Trace elements (TEs) in sedimentary nodular pyrite from multiple intervals along a single drillhole (NBDH010), indicate the existence of an enriched sedimentary interval with higher total TE content, Ag/Au and Sb/Au, lower S/Se, and polymetallic-like signature of Sb/Ag. Within this enriched interval, the black shale matrix of the polymict conglomerate shows higher total organic carbon (TOC), Mo content, and Co/Ni ratios and suggest increased bio-activity at that time, interpreted to be associated with the Ag–Zn(–Au) mineralization. The TE characteristics in sedimentary pyrite, reflecting increased metal content in seawater inferred from in situ pyrite trace element analysis has the potential to be developed into an exploration tool for successions, adjacent and coeval to similar ore deposits.
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References
Barrote V, Tessalina S, McNaughton N, Jourdan F, Hollis SP, Ware B, Zi J-W (2020) 4D history of the Nimbus VHMS ore deposit in the Yilgarn Craton, Western Australia. Precambrian Res 337:105536. https://doi.org/10.1016/j.precamres.2019.105536
Bekker A, Slack JF, Planavsky N, Krapez B, Hofmann A, Konhauser KO, Rouxel OJ (2010) Iron formation: the sedimentary product of a complex interplay among mantle, tectonic, oceanic, and biospheric processes. Econ Geol 105:467–508. https://doi.org/10.2113/gsecongeo.105.3.467
Belousov I, Large RR, Meffre S, Danyushevsky LV, Steadman J, Beardsmore T (2016) Pyrite compositions from VHMS and orogenic Au deposits in the Yilgarn Craton, Western Australia: Implications for gold and copper exploration. Ore Geol Rev 79:474–499. https://doi.org/10.1016/j.oregeorev.2016.04.020
Berge J (2013) Likely “mantle plume” activity in the Skellefte district, Northern Sweden. A reexamination of mafic/ultramafic magmatic activity: its possible association with VMS and gold mineralization. Ore Geol Rev 55:64–79. https://doi.org/10.1016/j.oregeorev.2013.04.008
Birck JL, Barman MR, Capmas F (1997) Re-Os isotopic measurements at the femtomole level in natural samples. Geostand Geoanal Res 21:19–27. https://doi.org/10.1111/j.1751-908X.1997.tb00528.x
Bolhar R, Kamber BS, Moorbath S, Fedo CM, Whitehouse MJ (2004) Characterisation of early Archaean chemical sediments by trace element signatures. Earth Planet Sci Lett 222:43–60. https://doi.org/10.1016/j.epsl.2004.02.016
Bragagni A, Fonseca ROC, van Acken D, Speelmanns IM, Heuser A, Luguet A (2015) Highly siderophile elements and 187Os/188Os in individual sulfides by isotope dilution. In: Goldschmidt2015 Abstracts. Prague, p 374
Canfield DE (2005) The early history of atmospheric oxygen: homage to Robert M. Garrels. Annu Rev Earth Planet Sci 33:1–36. https://doi.org/10.1146/annurev.earth.33.092203.122711
Caruso S, Fiorentini ML, Hollis SP, LaFlamme C, Baumgartner RJ, Steadman JA, Savard D (2018) The fluid evolution of the Nimbus Ag-Zn-(Au) deposit: an interplay between mantle plume and microbial activity. Precambrian Res 317:211–229. https://doi.org/10.1016/j.precamres.2018.08.012
Creaser RA, Sannigrahi P, Chacko T, Selby D (2002) Further evaluation of the Re-Os geochronometer in organic-rich sedimentary rocks: a test of hydrocarbon maturation effects in the Exshaw Formation, Western Canada Sedimentary Basin. Geochim Cosmochim Acta 66:3441–3452. https://doi.org/10.1016/S0016-7037(02)00939-0
Czarnota K, Champion DC, Goscombe B, Blewett RS, Cassidy KF, Henson PA, Groenewald PB (2010) Geodynamics of the eastern Yilgarn Craton. Precambrian Res 183:175–202. https://doi.org/10.1016/j.precamres.2010.08.004
Deditius AP, Utsunomiya S, Renock D, Ewing RC, Ramana CV, Becker U, Kesler SE (2008) A proposed new type of arsenian pyrite: composition, nanostructure and geological significance. Geochim Cosmochim Acta 72:2919–2933. https://doi.org/10.1016/j.gca.2008.03.014
Derry LA, Jacobsen SB (1990) The chemical evolution of Precambrian seawater: evidence from REEs in banded iron formations. Geochim Cosmochim Acta 54:2965–2977. https://doi.org/10.1016/0016-7037(90)90114-Z
Ding L, Yang G, Xia F, Lenehan CE, Qian G, McFadden A, Brugger J, Zhang X, Chen G, Pring A (2011) A LA-ICP-MS sulphide calibration standard based on a chalcogenide glass. Mineral Mag 75:279–287. https://doi.org/10.1180/minmag.2011.075.2.279
Gregory DD, Large RR, Halpin JA, Baturina EL, Lyons TW, Wu S, Danyushevsky L, Sack PJ, Chappaz A, Maslennikov VV, Bull SW (2015) Trace element content of sedimentary pyrite in black shales. Econ Geol 110:1389–1410. https://doi.org/10.2113/econgeo.110.6.1389
Gregory DD, Lyons TW, Large RR, Jiang G, Stepanov AS, Diamond CW, Figueroa MC, Olin P (2017) Whole rock and discrete pyrite geochemistry as complementary tracers of ancient ocean chemistry: an example from the Neoproterozoic Doushantuo Formation, China. Geochim Cosmochim Acta 216:201–220. https://doi.org/10.1016/j.gca.2017.05.042
Gregory D, Mukherjee I, Olson SL, Large RR, Danyushevsky LV, Stepanov AS, Avila JN, Cliff J, Ireland TR, Raiswell R, Olin PH, Maslennikov VV, Lyons TW (2019a) The formation mechanisms of sedimentary pyrite nodules determined by trace element and sulfur isotope microanalysis. Geochim Cosmochim Acta 259:53–68. https://doi.org/10.1016/j.gca.2019.05.035
Gregory DD, Liu C, Morrison SM, Hazen RM, Cracknell MJ, Large RR, McGoldrick PJ, Kuhn S, Baker MJ, Fox N, Belousov I, Steadman JA, Fabris A, Maslennikov V, Lyons TW, Figueroa MC (2019b) A comparison of random forests and cluster analysis to identify ore deposits type using LA-ICPMS analysis of pyrite. In: Life with ore deposits on earth. Glasgow, Scotland, pp 1274–1277
Hannah JL, Bekker A, Stein HJ, Markey RJ, Holland HD (2004) Primitive Os and 2316 Ma age for marine shale: implications for Paleoproterozoic glacial events and the rise of atmospheric oxygen. Earth Planet Sci Lett 225:43–52. https://doi.org/10.1016/j.epsl.2004.06.013
Hannah JL, Stein HJ, Zimmerman A, Bingen B (2006) Precise 2004±9 Ma Re–Os age for Pechenga black shale: comparison of sulfides and organic material. Geochim Cosmochim Acta 70:A228. https://doi.org/10.1016/j.gca.2006.06.461
Hannah JL, Stein HJ, Yang G, Markey RJ, Melezhik VA (2008) Re-Os dating of black shales timing and duration of sedimentary processes. In: AAPG Annual Convention, San Antonio
Hildrew C (2015) Understanding the nature of the host rock succession to the Archean Nimbus Ag-Zn-Pb-Au deposit, WA. B.Sc with honours thesis, University of Tasmania, UTAS
Hollis SP, Mole DR, Gillespie P, Barnes SJ, Tessalina S, Cas RAF, Hildrew C, Pumphrey A, Goodz MD, Caruso S, Yeats CJ, Verbeeten A, Belford SM, Wyche S, Martin LAJ (2017) 2.7 Ga plume associated VHMS mineralization in the eastern goldfields Superterrane, Yilgarn Craton: insights from the low temperature and shallow water, Ag-Zn-(Au) Nimbus deposit. Precambrian Res 291:119–142. https://doi.org/10.1016/j.precamres.2017.01.002
Jochum KP, Wilson SA, Abouchami W, Amini M, Chmeleff J, Eisenhauer A, Hegner E, Iaccheri LM, Kieffer B, Krause J, McDonough WF, Mertz-Kraus R, Raczek I, Rudnick RL, Scholz D, Steinhoefel G, Stoll B, Stracke A, Tonarini S, Weis D, Weis U, Woodhead JD (2011) GSD-1G and MPI-DING Reference glasses for in situ and bulk isotopic determination. Geostand Geoanal Res 35:193–226. https://doi.org/10.1111/j.1751-908X.2010.00114.x
Lan C, Yang AY, Wang C, Zhao T (2019) Geochemistry, U-Pb zircon geochronology and Sm-Nd isotopes of the Xincai banded iron formation in the southern margin of the North China Craton: implications on Neoarchean seawater compositions and solute sources. Precambrian Res 326:240–257. https://doi.org/10.1016/j.precamres.2017.10.024
Large RR, Halpin JA, Danyushevsky LV, Maslennikov VV, Bull SW, Long JA, Gregory DD, Lounejeva E, Lyons TW, Sack PJ, McGoldrick PJ, Calver CR (2014) Trace element content of sedimentary pyrite as a new proxy for deep-time ocean–atmosphere evolution. Earth Planet Sci Lett 389:209–220. https://doi.org/10.1016/j.epsl.2013.12.020
Large RR, Gregory DD, Steadman JA, Tomkins AG, Lounejeva E, Danyushevsky LV, Halpin JA, Maslennikov V, Sack PJ, Mukherjee I, Berry R, Hickman A (2015) Gold in the oceans through time. Earth Planet Sci Lett 428:139–150. https://doi.org/10.1016/j.epsl.2015.07.026
Large RR, Mukherjee I, Gregory DD, Steadman JA, Maslennikov VV, Meffre S (2017) Ocean and atmosphere geochemical proxies derived from trace elements in marine pyrite: implications for ore genesis in sedimentary basins. Econ Geol 112:423–450. https://doi.org/10.2113/econgeo.112.2.423
Ludwig KR (2011) User’s manual for Isoplot 4.15: a geochronological toolkit for Microsoft Excel
Lyons TW, Anbar AD, Severmann S, Scott C, Gill BC (2009) Tracking euxinia in the ancient ocean: a multiproxy perspective and Proterozoic case study. Annu Rev Earth Planet Sci 37:507–534. https://doi.org/10.1146/annurev.earth.36.031207.124233
MacPhersons Resources (2015) Nimbus increases resources. ASX – Nimbus JORC Resource Update
Moore EK, Hao J, Prabhu A, Zhong H, Jelen BI, Meyer M, Hazen RM, Falkowski PG (2018) Geological and chemical factors that impacted the biological utilization of cobalt in the Archean eon. J Geophys Res Biogeosci 123:743–759. https://doi.org/10.1002/2017JG004067
Mukherjee I, Large R (2017) Application of pyrite trace element chemistry to exploration for SEDEX style Zn-Pb deposits: McArthur Basin, Northern Territory, Australia. Ore Geol Rev 81:1249–1270. https://doi.org/10.1016/j.oregeorev.2016.08.004
Philippot P, Ávila JN, Killingsworth BA, Tessalina S, Baton F, Caquineau T, Muller E, Pecoits E, Cartigny P, Lalonde SV, Ireland TR, Thomazo C, van Kranendonk MJ, Busigny V (2018) Globally asynchronous sulphur isotope signals require re-definition of the Great Oxidation Event. Nat Commun 9. https://doi.org/10.1038/s41467-018-04621-x
Poulton SW, Fralick PW, Canfield DE (2004) The transition to a sulphidic ocean ∼ 1.84 billion years ago. Nature 431:173–177. https://doi.org/10.1038/nature02912
Pumphrey A, Weeber L, Gillespie P (2014) Nimbus project final report – EIS Ag Grant DAG2013/00171295. Macphersons Resources Limited
Reinhard CT, Raiswell R, Scott C, Anbar AD, Lyons TW (2009) A late Archean sulfidic sea stimulated by early oxidative weathering of the continents. Science 326:713–716. https://doi.org/10.1126/science.1176711
Reinhard CT, Planavsky NJ, Robbins LJ, Partin CA, Gill BC, Lalonde SV, Bekker A, Konhauser KO, Lyons TW (2013) Proterozoic ocean redox and biogeochemical stasis. Proc Natl Acad Sci 110:5357–5362. https://doi.org/10.1073/pnas.1208622110
Selby D, Creaser RA (2003) Re–Os geochronology of organic rich sediments: an evaluation of organic matter analysis methods. Chem Geol 200:225–240. https://doi.org/10.1016/S0009-2541(03)00199-2
Smoliar MI, Walker RJ, Morgan JW (1996) Re-Os ages of group IIA, IIIA, IVA, and IVB iron meteorites. Science 271:1099–1102. https://doi.org/10.1126/science.271.5252.1099
Steadman JA, Large RR (2016) Synsedimentary, Diagenetic, and metamorphic pyrite, pyrrhotite, and marcasite at the Homestake BIF-hosted gold deposit, South Dakota, USA: insights on Au-As ore genesis from textural and LA-ICP-MS trace element studies. Econ Geol 111:1731–1752. https://doi.org/10.2113/econgeo.111.7.1731
Steadman JA, Large RR, Meffre S, Olin PH, Danyushevsky LV, Gregory DD, Belousov I, Lounejeva E, Ireland TR, Holden P (2015) Synsedimentary to early diagenetic gold in black shale-hosted pyrite nodules at the Golden Mile deposit, Kalgoorlie, Western Australia. Econ Geol 110:1157–1191. https://doi.org/10.2113/econgeo.110.5.1157
Swanner ED, Planavsky NJ, Lalonde SV, Robbins LJ, Bekker A, Rouxel OJ, Saito MA, Kappler A, Mojzsis SJ, Konhauser KO (2014) Cobalt and marine redox evolution. Earth Planet Sci Lett 390:253–263. https://doi.org/10.1016/j.epsl.2014.01.001
Tardani D, Reich M, Deditius AP, Chryssoulis S, Sánchez-Alfaro P, Wrage J, Roberts MP (2017) Copper–arsenic decoupling in an active geothermal system: a link between pyrite and fluid composition. Geochim Cosmochim Acta 204:179–204. https://doi.org/10.1016/j.gca.2017.01.044
Thomson J, Higgs NC, Wilson TRS, Croudace IW, De Lange GJ, Van Santvoort PJM (1995) Redistribution and geochemical behaviour of redox-sensitive elements around S1, the most recent eastern Mediterranean sapropel. Geochim Cosmochim Acta 59:3487–3501. https://doi.org/10.1016/0016-7037(95)00232-O
van Acken D, Thomson D, Rainbird RH, Creaser RA (2013) Constraining the depositional history of the Neoproterozoic Shaler Supergroup, Amundsen Basin, NW Canada: rhenium-osmium dating of black shales from the Wynniatt and Boot Inlet Formations. Precambrian Res 236:124–131. https://doi.org/10.1016/j.precamres.2013.07.012
Whitney DL, Evans BW (2010) Abbreviations for names of rock-forming minerals. Am Mineral 95:185–187. https://doi.org/10.2138/am.2010.3371
Wille M, Nebel O, Van Kranendonk MJ, Schoenberg R, Kleinhanns IC, Ellwood MJ (2013) Mo–Cr isotope evidence for a reducing Archean atmosphere in 3.46–2.76Ga black shales from the Pilbara, Western Australia. Chem Geol 340:68–76. https://doi.org/10.1016/j.chemgeo.2012.12.018
Acknowledgments
The authors acknowledge Mark Rigby and Andrew Pumphrey from MacPhersons Resources Ltd. for access to samples, drill core, and internal data; GSWA core library for access to drill core; Dr. Jeffrey Steadman and Dr. Stefano Caruso for access to samples and scientific assistance; Thermo Fisher, GSWA, and MRIWA for financial support; and the John de Laeter Centre, Curtin University and UWA for the facilities, scientific, and technical assistance. We thank Dr. George Hudak, Dr. Bernd Lehmann, Dr. Thomas Monecke, and an anonymous reviewer whose comments helped improve and clarify this manuscript.
Funding
JdLC facilities are supported by a university-government consortium, ARC and AuScope via NCRIS. GeoHistory Facility instruments in the John de Laeter Centre, Curtin University were funded via an Australian Geophysical Observing System grant provided to AuScope Pty Ltd. by the AQ44 Australian Education Investment Fund program. The NPII multi-collector was obtained via funding from the Australian Research Council LIEF program (LE150100013).
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Barrote, V.R., Tessalina, S.G., McNaughton, N.J. et al. Surge of ore metals in seawater and increased bio-activity: a tracer of VHMS mineralization in Archaean successions, Yilgarn Craton, Western Australia. Miner Deposita 56, 643–664 (2021). https://doi.org/10.1007/s00126-020-00986-6
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DOI: https://doi.org/10.1007/s00126-020-00986-6