Abstract
A gold-bearing quartz vein system has been identified in Archaean basement rocks at Sortekap in the Kangerlussuaq region of east Greenland, 35 km north–northeast of the Skaergaard Intrusion. This constitutes the first recorded occurrence of Au mineralisation in the metamorphic basement rocks of east Greenland. The mineralisation can be classified as orogenic style, quartz vein-hosted Au mineralisation. Two vein types have been identified based on their alteration styles and the presence of Au mineralisation. Mineralised type 1 veins occur within sheared supracrustal units and are hosted by garnet-bearing amphibolites, with associated felsic and ultramafic intrusions. Gold is present as native Au and Au-rich electrum together with arsenopyrite and minor pyrite and chalcopyrite in thin alteration selvages in the immediate wall rocks. The alteration assemblage of actinolite-clinozoisite-muscovite-titanite-scheelite-arsenopyrite-pyrite is considered to be a greenschist facies assemblage. The timing of mineralisation is therefore interpreted as being later and separate event to the peak amphibolite facies metamorphism of the host rocks. Type 2 quartz veins are barren of mineralisation, lack significant alteration of the wall rocks and are considered to be later stage. Fluid inclusion microthermometry of the quartz reveals three separate fluids, including a high temperature (T h = 300–350 °C), H2O–CO2–CH4 fluid present only in type 1 veins that in interpreted to be responsible for the main stage of Au deposition and sulphidic wall rock alteration. It is likely that the carbonic fluids were actually trapped at temperatures closer to 400 °C. Two other fluids were identified within both vein types, which comprise low temperature (100–200 °C) brines, with salinities of 13–25 wt% eq. NaCl and at least one generation of low salinity aqueous fluids. The sources and timings of the secondary fluids are currently equivocal but they may be related to the emplacement of Paleogene mafic intrusions. The identification of this occurrence of orogenic-style Au mineralisation has implications for exploration in the underexplored area of east Greenland between 62 and 69° N, where other, similar supracrustal units are known to be present.
Similar content being viewed by others
References
Andersen JCØ, Rasmussen H, Nielsen TFD, Ronsbo JC (1998) The Triple Group and the Platinova gold and palladium reefs in the Skaergaard Intrusion: stratigraphic and petrographic relations. Econ Geol 93:488–509
Andrews JR, Bridgwater D, Gormsen K, Gulson B, Keto L, Watterson J (1973) The Precambrian of southeast Greenland. In: Park RG, Tarney J (eds) The Early Precambrian of Scotland and Related Rocks of Greenland. Univ Keele, pp 143–156
Appel PWU, Bliss IC, Coller DW, Grahl-Madsen L, Petersen JS (2000) Recent gold discoveries in Archaean rocks of central west Greenland. Appl Earth Sci (Trans Inst Min Metall B) 109:34–41
Àrnason JG, Bird DK (2000) A gold- and platinum-mineralised layer in gabbros of The Kap Edvard Holm Complex: field, petrologic, and geochemical relations. Econ Geol 95:945–970
Bird DK, Àrnason JG, Brandriss ME, Nevle RJ, Radford G, Bernstein S, Gannicott RA, Kelemen PB (1995) A gold- and platinum-mineralised layer in gabbros of The Kap Edvard Holm Complex: field, petrologic, and geochemical relations. Econ Geol 90:1288–1300
Blichert-Toft J, Lesher CE, Rosing MT (1992) Selectively contaminated magmas of the Tertiary East Greenland macrodike complex. Contrib Mineral Petrol 110:154–172
Bridgewater D, Watson J, Windley BF (1973) The Archaean craton of the North Atlantic region. Phil Trans R Soc London A273:493–512
Brooks CK, Nielsen TFD (1978) Early stages in the differentiation of the Skaergaard magma as revealed by a closely related suite of dike rocks. Lithos 11:1–14
Carpenter AB (1978) Origin and chemical evolution of brines in sedimentary basins. Okla Geol Surv Circ 79:60–77
Diamond LW (1994) Salinity of multivolatile fluid inclusions determined by clathrate hydrate stability. Geochim Cosmochim Acta 58:19–41
Geist DJ, White CM (1994) Assimilation and fractionation in adjacent parts of the same magma chamber: Vandfaldsdalen macrodike, East Greenland. Contrib Mineral Petrol 116:92–107
Geyti A, Thomassen B (1984) Molybdenum and precious metal mineralisation at Flammefjeld, Southeast Greenland. Econ Geol 79:1921–1929
Gisselø P (2000) Sorgenfri Gletscher Sill Complex, East Greenland. Solidification mechanisms of sheet-like bodies and the role of sill complexes in large igneous provinces. Unpublished PhD thesis, Aarhus Geoscience, Denmark
Goldfarb RJ, Baker T, Dubé B, Groves DI, Hart CJR, Gosselin P (2005) Distribution, character and genesis of gold deposits in metamorphic terranes. Econ Geol 100th Anniv Vol, Soc Econ Geol, Colorado, pp 407–450
Grassineau NV, Appel PWU, Fowler CMR, Nisbet EG (2005) Distinguishing biological from hydrothermal signatures via sulphur and carbon isotopes in Archaean mineralisations at 3.8 and 2.7 Ga. In: McDonald I, Boyce AJ, Butler IB, Herrington RJ, Polya DA (eds) Mineral Deposits and Earth Evolution, Geol Soc London, Special Publication 248, pp 195–212
Groves DI, Goldfarb RJ, Robert F, Hart CJR (2003) Gold deposits in metamorphic belts: overview of current understanding, outstanding problems, future research, and exploration significance. Econ Geol 96:1–29
Heyen G, Ramboz C, Dubessy A (1982) Simulation des équilibres de phases dans le système CO2-CH4 en dessous de 50 °C et de 100 bar. Application aux inclusions fluids. C R Acad Sci Paris 294:203–206
Holwell DA, Boyce AJ, McDonald I (2007) Sulfur isotope variations within the Platreef: genetic implications for the origin of sulfide mineralization. Econ Geol 102:1091–1110
Holwell DA, Abraham-James T, Keays RR, Boyce AJ (2012a) The nature and genesis of marginal Cu-PGE-Au sulphide mineralisation in Paleogene Macrodykes of the Kangerlussuaq region, east Greenland. Mineral Deposits 47:3–21
Holwell DA, Selby D, Boyce AJ, Gilbertson JA, Abraham-James T (2012b) A Re-Os date for molybdenite-bearing quartz vein mineralization within the Kangerlussuaq Alkaline Complex, east Greenland: implications for the timing of regional metallogenesis. Econ Geol 107:713–722
Kaltoft K, Schlatter DM, Kludt L (2000) Geology and genesis of Nalunaq Palaeoproterozoic shear zone hosted gold deposit, south Greenland. App Earth Sci (Trans Inst Min Metall B) 109:23–33
Kays MA, Goles GG, Grover TW (1989) Precambrian sequence bordering the Skaergaard Intrusion. J Petrol 30:321–361
Larsen M, Bjerager M, Nedkvitne T, Olaussen S, Preuss T (2001) Pre-basaltic sediments (Aptian–Paleocene) of the Kangerlussuaq Basin, southern East Greenland. Geol Surv Denmark Greenland Bull 189:99–106
Leeman WP, Dasch EJ, Kays MA (1976) 207Pb/206Pb whole-rock age of gneisses from the Kandgerdlugssuaq area, eastern Greenland. Nature 263:469–471
McBirney AR (1989) The Skaergaard layered series: I; structure and average composition. J Petrol 30:363–397
Mikucki EJ, Ridley JR (1993) The hydrothermal fluid of Archaean lode-gold deposits at different metamorphic grades: compositional constraints from ore and wallrock alteration assemblages. Mineral Deposita 28:469–481
Momme P, Tegner C, Brooks CK, Keays RR (2002) The behaviour of platinum-group elements in basalts from the East Greenland rifted margin. Contrib Mineral Petrol 143:133–153
Myers JS, Dawes PR, Nielsen TFD (1988) Map sheet no. 13, Kangerdlugssuaq. Geol Surv Denmark Greenland
Nielsen TFD (1978) The Tertiary dike swarms of the Kangerdlugssuaq area, east Greenland. Contrib Mineral Petrol 67:63–78
Nielsen TFD (2002) Palaeogene intrusions and magmatic complexes an East Greenland, 66 to 75°N. Danmarks og Grønlands Geologiske Undersøgelse Rapport 2002/113, pp 249
Ohmoto H, Rye RO (1979) Isotopes of sulfur and carbon. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 2nd edn. Wiley, London, pp 509–567
Platina Resources Limited (2009, 30 October) Strong polymetallic assays confirm potential of key regional Greenland prospect: ASX/Media Release, pp 5
Ridley JR, Diamond LW (2000) Fluid chemistry of orogenic lode gold deposits and implications for genetic models. Rev Econ Geol 13:141–162
Ridley JR, Groves DI, Knight JT (2000) Gold deposits in amphibolites and granulite facies terranes of the Archaean Yilgarn craton. Western Australia: evidence and implications for synmetamorphic mineralisation. Rev Econ Geol 11:265–290
Riishuus MS, Peate DW, Tegner C, Wilson R (2006) Temporal evolution of a long-lived syenitic centre: the Kangerlussuaq Alkaline Complex, East Greenland. Lithos 92:276–299
Robert F, Poulsen KH, Cassidy KF, Hodgson CJ (2005) Gold metallogeny of the Superior and Yilgarn Cratons. Econ Geol 100th Anniv Vol, Soc Econ Geol, Colorado, pp 1001–1033
Robinson BW, Kusakabe M (1975) Quantitative preparation of sulphur dioxide for 34S/32S analyses from sulfides by combustion with cuprous oxide. Anal Chem 47:1179–1181
Saunders AD, Fitton JG, Kerr AC, Norry MJ, Kent RW (1997) The North Atlantic Igneous province. In: Mahoney JJ, Coffin MF (eds) Large igneous provinces: continental, oceanic and planetary flood volcanism. Geophys Monograph 100, Am Geophys Union, Washington DC, pp 45–93
Soper NJ, Higgins AC, Downie C, Matthews DW, Brown PE (1976) Late Cretaceous-early Tertiary stratigraphy of the Kangerdlugssuaq area, east Greenland, and the age of opening of the north-east Atlantic. J Geol Soc Lond 132:85–104
Spangler R, Wagner W (1996) A new equation of state for carbon dioxide covering the fluid region from the triple–point temperature to 1,100 K at pressures up to 800 MPa. J Phys Chem Ref Data 25:1509–1596
Steele-MacInnis M, Bodnar RJ, Naden J (2011) Numerical model to determine the composition of H2O-NaCl-CaCl2 fluid inclusions based on microthermometric and microanalytical data. Geochim Cosmochim Acta 75:21–41
Steenfelt A (2000) Geochemical signatures of gold provinces in south Greenland. App Earth Sci (Trans Inst Min Metall B) 109:14–22
Stendal H, Frei R (2000) Gold occurrences and lead isotopes in Ketilidian Mobile Belt, south Greenland. App Earth Sci (Trans Inst Min Metall B) 109:6–13
Sterner, Bodnar (1991) Synthetic fluid inclusions. X. Experimental determination of P-V-T-X properties in the CO2-H2O system to 6 kb and 700 °C. Am J Sci 291:1–54
Wager LR (1934) Geological investigations in east Greenland, pt. I. General geology from Angmagssalik to Kap Dalton. Medd Grønland 105:1–46
Wager LR, Deer WA (1939) Geological investigations in east Greenland, pt. HI. The petrology of the Skaergaard intrusion, Kangerlugssuaq, east Greenland. Medd Grønland 105:1–352
Acknowledgments
This work is part of a collaborative project between Platina Resources Limited and the University of Leicester and has been funded by a research grant from Platina. Platina is also acknowledged for logistical arrangements during fieldwork in Greenland and the provision of assay data. Sulphur isotope analysis was funded by the Natural Environment Research Council Isotope Geoscience Facilities Steering Committee (Grant IP-1200-1110). The quality of the manuscript benefitted from extremely helpful and constructive reviews by Frank Bierlein and John Ridley and the associate editor, Dave Craw. In addition to the authors, other members of the field team that were part of the discovery of this occurrence, Sveinborg Hlíf Gunnarsdóttir, Freyr Ingi, Brodie Sutherland and Toby Roscoe, are also thanked for their involvement in the fieldwork. DAH acknowledges logistical support from SRK Exploration Services Ltd.
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial handling: D. Craw
Rights and permissions
About this article
Cite this article
Holwell, D.A., Jenkin, G.R.T., Butterworth, K.G. et al. Orogenic gold mineralisation hosted by Archaean basement rocks at Sortekap, Kangerlussuaq area, East Greenland. Miner Deposita 48, 453–466 (2013). https://doi.org/10.1007/s00126-012-0434-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00126-012-0434-3