Abstract
The Permian Huangshanxi Cu–Ni deposit is the second largest magmatic sulfide deposit discovered to date in a major Ni–Cu province related to protracted basaltic magmatism in eastern Xinjiang, China. It is hosted by a small mafic–ultramafic intrusion comprised predominantly of lherzolites, olivine websterites, gabbronorites, and gabbros. The Huangshanxi intrusion is coeval with Permian basalts of tholeiitic and alkaline affinities in the Tuha and Tarim basins, respectively. To evaluate a possible genetic relationship between the Huangshanxi intrusion and a specific type of coeval basalt in the region, as well as ore genesis in the intrusion, we have carried out an integrated mineralogical, petrological, and geochemical study. Our data reveal that the Huangshanxi intrusive rocks are characterized by relatively flat chondrite-normalized REE patterns, depletion in Nb and Ta, and elevated εNd values varying between 6 and 10. These features are similar to those of coeval tholeiitic basalts in the nearby Tuha basin, but are significantly different from those of coeval alkaline basalts in the relatively remote Tarim basin. The geochemical similarities and differences suggest that the Huangshanxi intrusion is genetically related to the tholeiitic basalts in the Tuha basin, not to the alkaline basalts in the Tarim basin, as suggested previously by some researchers. This implies that regional exploration for the Huangshanxi-type Cu–Ni deposits should be centered in the Tuha basin instead of the Tarim basin. More specifically, the uplifted areas around the Tuha basin where similar intrusions may have been brought close to the surface should be carefully examined for mineralization potential. Intrusive relations and mass balance constraints from incompatible trace elements and sulfide abundances suggest that the Huangshanxi intrusion represents a dynamic magma conduit through which multiple pulses of magma ascended to higher levels or to the surface. Numerical simulation of magma evolution and mixing calculations using Sr–Nd isotopes indicate that selective assimilation of S-bearing crustal materials is important for sulfide saturation during the early stages of magma evolution when lherzolites formed. Fractional crystallization may have also played a role in the attainment of sulfide saturation during the later stages of magma evolution when olivine websterites and gabbronorites formed. In both cases, immiscible sulfide droplets were retained in the conduit to form disseminated sulfide lenses while the fractionated silicate liquids and buoyant phases such as plagioclase continued to ascend. Extremely low PGE tenors in the sulfide ores of the Huangshanxi deposit suggest that the parental magma was highly depleted in chalcophile elements possibly due to previous sulfide segregation at depth.
Similar content being viewed by others
References
Anders E, Grevesse N (1989) Abundances of the elements: meteoritic and solar. Geochim Cosmochim Acta 53:197–214
Asimow PD, Ghiorso MS (1998) Algorithmic modifications extending MELTS to calculate subsolidus phase relations. Am Mineralog 83:1127–1132
Barnes SB, Roeder PL (2001) The range of spinel compositions in terrestrial mafic and ultramafic rocks. J Petrol 42:2279–2302
Barnes S-J, Maier WD (1999) The fractionation of Ni, Cu, and the noble metals in silicate and sulphide liquids. Geol Assoc Can Short Course Notes 13:69–106
Barnes S-J, Lightfoot PC (2005) Formation of magmatic nickel sulfide ore deposits and processes affecting their copper and platinum group element contents. In: Hedenquist JW, Thompson JFH, Goldfarb RJ, Richards JP (eds) Economic geology 100th anniversary volume., pp 179–213
Campbell IH, Naldrett AJ (1979) The influence of silicate:sulfide ratios on the geochemistry of magmatic sulfides. Econ Geol 74:1503–1505
Chen HL, Yang SF, Dong CW (1997) The discovery of early Permian basic rock belt in the Tarim basin and its tectonic meaning. Geochemica 26:77–87 (in Chinese)
Chung SL, Jahn BM (1995) Plume-lithosphere interaction in generation of the Emeishan flood basalts at the Permian–Triassic boundary. Geology 23:889–892
Fan W, Zhang C, Wang Y, Guo F, Peng T (2008) Geochronology and geochemistry of Permian basalts in western Guangxi Province, Southwest China: evidence for plume–lithosphere interaction. Lithos 102:218–236
Ghiorso MS, Sack RO (1995) Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid–solid equilibria in magmatic systems at elevated temperatures and pressures. Contrib Mineralog Petrol 119:197–212
Han BF, Ji JQ, Song B, Chen LH, Li ZH (2004) SHRIMP zircon U–Pb ages of Karatongke No. 1 and Huangshandong Cu–Ni-bearing mafic–ultramafic complexes, North Xinjiang, and geological implications. Chin Sci Bull 49:2424–2429
Jahn B-M (2004) The Central Asia Orogenic Belt and growth of the continental crust in the Phanerozoic. In: Malpas J, Fletcher CJN, Ali JR, Aitchison JC (eds) Aspects of the tectonic evolution of China. Geol Soc Lond Spec Publ 226:73–100
Jiang CY, Cheng SL, Ye SF, Xia MZ, Jiang HB, Dai YC (2006) Lithogeochemistry and petrogenesis of Zhongposhanbei mafic rock body at Beishan region. Xinjiang Acta Petrologica Sin 22:115–126 (in Chinese)
Kamo SL, Czamanske GK, Amelin Y, Fedorenko VA, Davis DW, Trofimov VR (2003) Rapid eruption of Siberian flood-volcanic rocks and evidence for coincidence with the Permian–Triassic boundary and mass extinction at 251 Ma. Earth Planet Sci Lett 214:75–91
Kushiro K (2001) Partial melting experiments on peridotite and origin of mid-ocean ridge basalt. Annu Rev Earth Planet Sci 29:71–107
Li C, Ripley EM (2009) Sulfur contents at sulfide-liquid or anhydrite saturation in silicate melts: empirical equations and example applications. Econ Geol 104:405–412
Li C, Ripley EM (2010) The relative effects of composition and temperature on olivine-liquid Ni partitioning: statistical deconvolution and implications for petrologic modeling. Chem Geol 275:99–104
Li C, Ripley EM, Naldrett AJ (2009) A new genetic model for the giant Ni–Cu–PGE sulfide deposits associated with the Siberian flood basalts. Econ Geol 104:291–301
Li CD, Mou J, Lan G, Sun Y, Yang ZX, Tang J, Chen J, Miao F, Xiao Y (1996) Origin and ore-forming principals of the Huangshan Cu–Ni metallogenic belt, Hami, Xinjiang. Chengdu University of Technology, Chengdu, p 204 (in Chinese)
Li DH, Bao X, Zhang B, Han Z, Lan G, Zheng Z et al (1989) Investigation of geology, geophysics and geochemistry of the Huangshan Cu –Ni metallogenic belt for mineral exploration. Unpublished report to the office of the National 305 Project of China, p 418 (in Chinese)
Li HQ, Chen FW, Mei YP, Wu H, Cheng SL, Yang JQ, Dai YC (2006) Dating of the No. 1 intrusion of Pobei basic–ultrabasic rocks belt, Xinjiang, and its geological significance. Miner Depos 25:463–469 (in Chinese)
Lightfoot PC, Keays RR (2005) Siderophile and chalcophile metal variations in flood blasts from the Siberian trap, Noril’sk region: implications for the origin of the Ni–Cu–PGE sulfide ores. Econ Geol 100:439–462
Mao J-W, Pirajno F, Zhang Z-H, Chai F-M, Wu H, Chen S-P, Cheng L-S, Yang J-M, Zhang C-Q (2008) A review of Cu–Ni sulphide deposits in the Chinese Tainshan and Altay orogens (Xinjiang Autonomous Region, NW China): principal characteristics and ore-forming processes. Asian J Earth Sci 32:184–203
Naldrett AJ (2010) Secular variation of magmatic sulfide deposits and their source magmas. Econ Geol 105:669–688
Naldrett AJ, Li C (2009) Ore deposits related to flood basalts, Siberia. In: Li C, Ripley EM (eds) New developments in magmatic Ni–Cu and PGE deposits. Geological Publishing House, Beijing, pp 141–179
Pirajno F, Mao J-W, Zhang Z-C, Zhang Z-H, Chai F-M (2008) The association of mafic–ultramafic intrusions and A-type magmatism in the Tian Shan and Altay orogens, NW China: implications for gedodynamic evolution and potential for the discovery of new ore deposits. Asian J Earth Sci 32:165–183
Pirajno F, Ernst RE, Borisenko AS, Fedoseev G, Naumov EA (2009) Intraplate magmatism in central Asia and China and associated metallogeny. Ore Geol Rev 35:114–136
Qi L, Zhou M-F (2008) Platinum-group elemental and Sr–Nd–Os isotopic geochemistry of Permian Emeishan flood basalts in Guizhou Province, SW China. Chem Geol 248:83–103
Reichow MK, Saunders AD, White RV, Pringle MS, Al’Mukhamedev AI, Medvedev AI, Kirda NP (2002) 40Ar/39Ar dates from the West Siberian basin: Siberian flood basalt province doubled. Science 296:1846–1849
Ripley EM, Li C (2007) Applications of stable and radiogenic isotopes to magmatic Cu–Ni–PGE deposits: examples and cautions. Earth Sci Front 14:124–132
Roeder PL, Emslie RF (1970) Olivine-liquid equilibrium. Contrib Mineralog Petrol 29:275–289
Rudnick RL, Gao S (2003) Composition of the continental crust. In: Rudnick RL (ed) Treatise on geochemistry Volume 3: The Crust. Elsevier, pp 1–64
Saal AE, Hauri EH, Langmuir CH, Perfit MR (2002) Vapour undersaturation in primitive mid-ocean-ridge basalt and the volatile content of earth's upper mantle. Nature 419:451–455
San JZ, Qin KZ, Tang DM, Su BX, Sun H, Xiao QH, Liu PP, Cao MJ (2010) Precise zircon U-Pb ages of Tulargen large Cu-Ni-ore bearing mafic-ultramafic complex and their geological implications. Acta Petrologica Sinica 26:3027–3035
Sun SS, McDonough WF (1989) Chemical and isotopic systematics in ocean basalt: implication for mantle composition and processes. In: Saunders AD, Norry MJ (eds) Magmatism in the Ocean Basins. Geological Society of London Special Publications 42:313–345
Tang DM, Qin KZ, Sun H, Su BX, Xiao QH, Cheng SL, Li J (2009) Lithological, geochronological and geochemical characteristics of Tianyu Cu–Ni deposit: constraints on source and genesis of mafic-ultramafic intrusions in eastern Xinjiang. Acta Petrologica Sin 25:817–831 (in Chinese)
Tao Y, Li C, Song X, Ripley EM (2008) Mineralogical, petrological and geochemical studies of the Limahe mafic–ultramatic intrusion and the associated Ni–Cu sulfide ores, SW China. Miner Deposita 43:849–872
Tian W, Campbell IH, Allen CM, Guan P, Pan W, Chen M, Yu H, Zhu W (2010) The Tarim picrite–basalt–rhyolite suite, a Permian flood basalt from northwest China with contrasting rhyolites produced by fractional crystallization and anatexis. Contrib Mineral Petrol. doi:10.1007/s00410-009-0485-3
Wang B, Faure M, Shu L, de Jong K, Charvet J, Cluzel D, Jahn B-M, Chen Y, Ruffet G (2010) Structural and geochronological study of high-pressure metamorphic rocks in the Kekesu section (northwestern China): implications for the late Paleozoic tectonics of the southern Tianshan. J Geol 118:59–77
Wang R-M, Liu D-Q, Ying D-T et al (1987) Cu–Ni sulfide deposits in the Tudun–Huangshan region, Hami, X Xinjiang: Genet controls exploration implications. Miner Rocks 7:1–152 (in Chinese)
Wu H, Li HQ, Mo XH, Chen FW, Lu YF, Mei YP, Deng G (2005) Age of the Baishiquan mafic–ultramafic complex, Hami, Xinjiang and its geological significance. Acta Geol Sin 79:498–502
Xiao QH, Qin KZ, Tang DM, Sun BX, Sun H, San JZ, Cao MJ, Hui WD (2010) Xiangshanxi composite Cu–Ni–Ti–Fe deposit belongs to comagmatic evolution product: evidence from ore microscopy, zircon U-Pb chronology and petrological geochemistry, Hami, Xinjiang, NW China. Acta Petrologica Sin 26:503–522
Xiao WJ, Windley F, Huang BC, Han CM, Yuan C, Chen HL, Sun M, Sun S, Li JL (2009) End-Permian to mid-Triassic termination of the accretionary processes of the southern Altaids: implications for the geodynamic evolution, Phanerozoic continental growth, and metallogeny of Central Asia. Int J Earth Sci 98:1189–1217
Yang SF, Li Z, Chen H, Santosh M, Dong CW, Yu X (2007) Permian bimodal dyke of Tarim Basin, NW China: geochemical characteristics and tectonic implications. Gondwana Res 12:113–120
Yang SH, Zhou M-F (2009) Geochemistry of the 430-Ma Jingbulake mafic–ultramafic intrusion in Western Xinjiang, NW China: implications for subduction related magmatism in the South Tianshan orogenic belt. Lithos 113:259–273
Zhang CL, Li XH, Li ZX, Ye HM, Li CN (2008a) A Permian layered intrusive complex in the Western Tarim Block, Northwestern China: product of a Ca. 275-Ma mantle plume? J Geol 116:269–287
Zhang LF, Ai YL, Li XP, Rubatto D, Song B, Williams S, Song SG, Ellis DJ, Liou JG (2007) Triassic collision of western Tianshan orogenic belt, China: evidence from SHRIMP U-Pb dating of zircon from HP/UHP eclogitic rocks. Lithos 96:266–280
Zhang XH, Zhang H, Tang Y, Wilde SA, Hu Z (2008b) Geochemistry of Permian bimodal volcanic rocks from central Inner Mongolia, North China: implication for tectonic setting and Phanerozoic continental growth in Central Asian Orogenic Belt. Chem Geol 249:262–281
Zhou DW, Liu YQ, Xin XJ, Hao JR, Dong YP, Ouyang ZJ (2006) Formation of the Permian basalts and implications of geochemical tracing for paleo-tectonic setting and regional tectonic background in the Turpan-Hami and Santanghu basins, Xinjiang. Sci China D 49:584–596 (in Chinese)
Zhou M-F, Lesher CM, Yang ZX, Li JW, Sun M (2004) Geochemistry and petrogenesis of 270 Ma Ni–Cu–(PGE) sulfide-bearing mafic intrusions in the Huangshan district, Eastern Xinjiang, Northwestern China: implication for the tectonic evolution of the Central Asian orogenic belt. Chem Geol 209:233–257
Zhou M-F, Arndt NT, Malpas J, Wang CY, Kennedy AK (2008) Two magma series and associated ore deposit types in the Permian Emeishan large igneous province, SW China. Lithos 103:352–368
Zhou M-F, Zhao J-H, Jiang C-Y, Gao J-F, Wang W, Yang S-H (2009) OIB-like, heterogeneous mantle sources of Permian basaltic magmatism in the western Tarim Basin, NW China: implications for a possible Permian large igneous province. Lithos 113:583–594
Zindler A, Hart S (1986) Chemical geodynamics. Annu Rev Earth Planet Sci 14:493–571
Acknowledgements
We thank John Guo for facilitating drill-core sampling, and Mei-Fu Zhou and Bernd Lehmann for constructive reviews. This study was supported by grants from NSF of China (40534020, 40772058, and 40873005), the Ministry of Education of China (NCET-04-0980 and Project 111-B07011), and the State Key Laboratory of Ore Deposit Geochemistry of China (200905).
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial handling: B. Lehmann
Rights and permissions
About this article
Cite this article
Zhang, M., Li, C., Fu, P. et al. The Permian Huangshanxi Cu–Ni deposit in western China: intrusive–extrusive association, ore genesis, and exploration implications. Miner Deposita 46, 153–170 (2011). https://doi.org/10.1007/s00126-010-0318-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00126-010-0318-3